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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic iron >1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene Structure
  • ₹1500 - ₹8720
  • Product name: 1,1'-Bis(diisopropylphosphino)ferrocene
  • CAS: 97239-80-0
  • MF: C22H36FeP210*
  • MW: 418.31
  • EINECS:677-500-6
  • MDL Number:MFCD02684559
  • Synonyms:BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON;1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%;1,1'-Bis(diisopropylphosphino)ferrocene,98%;1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%;1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene;Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]-
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 500MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberB2710
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging100MG
  • Price₹1500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2710
  • Product description1,1'-Bis(diisopropylphosphino)ferrocene
  • Packaging1G
  • Price₹7100
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number578266
  • Product description1,1′-Bis(diisopropylphosphino)ferrocene 97%
  • Packaging500MG
  • Price₹8720
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B2710 1,1'-Bis(diisopropylphosphino)ferrocene 100MG ₹1500 2022-05-26 Buy
TCI Chemicals (India) B2710 1,1'-Bis(diisopropylphosphino)ferrocene 1G ₹7100 2022-05-26 Buy
Sigma-Aldrich(India) 578266 1,1′-Bis(diisopropylphosphino)ferrocene 97% 500MG ₹8720 2022-06-14 Buy

Properties

Melting point :50-52 °C(lit.)
Flash point :>230 °F
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :orange-yellow
Water Solubility :Insoluble in water.
InChI :InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey :LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES :P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference :97239-80-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

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