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ChemicalBook > Product Catalogue >Organic Chemistry >Organosulfur compounds >TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE

TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE

TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE Structure
  • ₹2800 - ₹9807.45
  • Product name: TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE
  • CAS: 80522-42-5
  • MF: C10H21F3O3SSi
  • MW: 306.42
  • EINECS:638-988-6
  • MDL Number:MFCD00009913
  • Synonyms:Triisopropyl(trifluoromethylsulfonyloxy)silane;Triisopropylsilyl-trifluoromethanesulfonate,97%;Triisopropylsilyl Triflate Trifluoromethanesulfonic Acid Triisopropylsilyl Ester;Triisopropylsilyl trifluoromethanesulfonate ,98%;Triisopropylsilyl-trifluoroMethanesulfonate, 97% 10GR;RIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE;1,1,1-TrifluoroMethanesulfonic Acid Tris(1-Methylethyl)silyl Ester;TRIISOPROPYLSILYL TRIFLUOROMETHANESULFOTE
Price4 Properties Safety Information Description
4 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 10G
  • 25G
  • 50G
  • ManufacturerTCI Chemicals (India)
  • Product numberT1588
  • Product descriptionTriisopropylsilyl Trifluoromethanesulfonate
  • Packaging5G
  • Price₹2800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1588
  • Product descriptionTriisopropylsilyl Trifluoromethanesulfonate
  • Packaging25G
  • Price₹7800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number248460
  • Product descriptionTriisopropylsilyl trifluoromethanesulfonate 97%
  • Packaging10G
  • Price₹2857.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number248460
  • Product descriptionTriisopropylsilyl trifluoromethanesulfonate 97%
  • Packaging50G
  • Price₹9807.45
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T1588 Triisopropylsilyl Trifluoromethanesulfonate 5G ₹2800 2022-05-26 Buy
TCI Chemicals (India) T1588 Triisopropylsilyl Trifluoromethanesulfonate 25G ₹7800 2022-05-26 Buy
Sigma-Aldrich(India) 248460 Triisopropylsilyl trifluoromethanesulfonate 97% 10G ₹2857.8 2022-06-14 Buy
Sigma-Aldrich(India) 248460 Triisopropylsilyl trifluoromethanesulfonate 97% 50G ₹9807.45 2022-06-14 Buy

Properties

Boiling point :45-46 °C/0.03 mmHg
Density :1.14 g/mL at 25 °C (lit.)
refractive index :n20/D 1.415(lit.)
Flash point :213 °F
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
solubility :Miscible with chloroform and ethyl acetate.
form :Liquid
Specific Gravity :1.14
color :Clear light brown to orange-brown
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :3591541
InChI :InChI=1S/C10H21F3O3SSi/c1-7(2)18(8(3)4,9(5)6)16-17(14,15)10(11,12)13/h7-9H,1-6H3
InChIKey :LHJCZOXMCGQVDQ-UHFFFAOYSA-N
SMILES :C(F)(F)(F)S(O[Si](C(C)C)(C(C)C)C(C)C)(=O)=O
CAS DataBase Reference :80522-42-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.

Description

Triisopropylsilyl trifluoromethanesulfonate is used as a reagent for the introduction of triisopropylsilyl(TIPS) group in organic synthesis. It is involved in the synthesis of 2-substituted benzothiopyran-4-ones and silyloxy acetylenes. As a protecting group in organic synthesis, it is utilized especially for the protection of primary amines. Furthermore, it plays an important role in Takahashi Taxol total synthesis or for chemical glycosylation reactions.

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Suppliers and manufacturers

ORGANO FINE CHEMICALS SURVIVAL TECHNOLOGIES LIMITED ORGANO FINE CHEMICALS Organo Fine Chemicals CLEARSYNTH LABS LTD. TCI Chemicals (India) Pvt. Ltd. Alfa Aesar Spectrochem Pvt., Ltd. Survival Technologies Pvt., Ltd. (STPL)
Aceschem Inc.