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ChemicalBook > Product Catalogue >Organic Chemistry >Amides >Acyclic polyamines and their derivatives >BREDERECK'S REAGENT

BREDERECK'S REAGENT

BREDERECK'S REAGENT Structure
  • ₹1944 - ₹111118.63
  • Product name: BREDERECK'S REAGENT
  • CAS: 5815-08-7
  • MF: C9H22N2O
  • MW: 174.28
  • EINECS:227-383-9
  • MDL Number:MFCD00042858
  • Synonyms:tert-Butoxy bis(dimethylamino)methane technical;BREDERECKS REAGENT;BREDERECK'S REAGENT;tert-Butoxybis(dimethylamino)methane, 85+%;Bis(dimethylamino)(tert-butoxy)methane;N,N,N',N'-Tetramethyl(tert-butoxy)methanediamine;N,N,N',N'-Tetramethyl-α-tert-butoxymethanediamine;α-(1,1-Dimethylethoxy)-N,N,N',N'-tetramethylmethanediamine
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Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 1gm
  • 1G
  • 5gm
  • 10G
  • 10ML
  • 25gm
  • 50ML
  • ManufacturerSigma-Aldrich(India)
  • Product number384216
  • Product descriptiontert-Butoxy bis(dimethylamino)methane
  • Packaging1G
  • Price₹4708.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number20425
  • Product descriptiontert-Butoxy bis(dimethylamino)methane technical
  • Packaging10ML
  • Price₹23208.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number384216
  • Product descriptiontert-Butoxy bis(dimethylamino)methane
  • Packaging10G
  • Price₹23436.13
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number20425
  • Product descriptiontert-Butoxy bis(dimethylamino)methane technical
  • Packaging50ML
  • Price₹111118.63
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number B 2273
  • Product descriptiontert-Butoxy bis(dimethylamino)methane
  • Packaging1gm
  • Price₹1944
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 2273
  • Product descriptiontert-Butoxy bis(dimethylamino)methane
  • Packaging5gm
  • Price₹5949
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 2273
  • Product descriptiontert-Butoxy bis(dimethylamino)methane
  • Packaging25gm
  • Price₹17991
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 384216 tert-Butoxy bis(dimethylamino)methane 1G ₹4708.88 2022-06-14 Buy
Sigma-Aldrich(India) 20425 tert-Butoxy bis(dimethylamino)methane technical 10ML ₹23208.8 2022-06-14 Buy
Sigma-Aldrich(India) 384216 tert-Butoxy bis(dimethylamino)methane 10G ₹23436.13 2022-06-14 Buy
Sigma-Aldrich(India) 20425 tert-Butoxy bis(dimethylamino)methane technical 50ML ₹111118.63 2022-06-14 Buy
ottokemi B 2273 tert-Butoxy bis(dimethylamino)methane 1gm ₹1944 2022-05-26 Buy
ottokemi B 2273 tert-Butoxy bis(dimethylamino)methane 5gm ₹5949 2022-05-26 Buy
ottokemi B 2273 tert-Butoxy bis(dimethylamino)methane 25gm ₹17991 2022-05-26 Buy

Properties

Boiling point :50-55 °C/15 mmHg (lit.)
Density :0.844 g/mL at 25 °C (lit.)
refractive index :n20/D 1.422(lit.)
Flash point :106 °F
storage temp. :Sealed in dry,Store in freezer, under -20°C
solubility :Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly)
pka :5.46±0.38(Predicted)
form :Liquid
color :Clear pale yellow
Specific Gravity :0.844
BRN :1901973
Stability :Hygroscopic
InChI :InChI=1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3
InChIKey :HXRAMSFGUAOAJR-UHFFFAOYSA-N
SMILES :C(OC(C)(C)C)(N(C)C)N(C)C
CAS DataBase Reference :5815-08-7(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

tert-Butoxy bis(dimethylamino)methane (Bredereck′s reagent) may be used in the following studies:Enamination of active methylene and methyl groups.As condensation reagent in the synthesis of benz[c,d]indoles.Preparation of methyl and ethyl 3-dimethylamino-2-(indol-3-yl)propenoate.Synthesis of the macrolide natural product (-)-gloeosporone.Preparation of new bioactive naphthyridine alkaloids lophocladine A and B.Preparation of (E/Z)-ethyl 6,7-dichloro-3-[1-cyano-2-(dimethylamino)vinyl]-1-methyl-1H-indole-2-carboxylate.Preparation of (E)-ethyl 3-(dimethylamino)-2-(1H-indol-3-yl)acrylate.α-Enamination of ketones and esters.

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