Chromyl chloride
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- ₹7750.7
- Product name: Chromyl chloride
- CAS: 14977-61-8
- MF: Cl2CrO2
- MW: 154.9
- EINECS:239-056-8
- MDL Number:MFCD00010951
- Synonyms:chromiumdioxychloride[qr] ;chromiumdioxydichloride ;chromiumoxychloride(cro2cl2) ;Chromoxychlorid;chromoxychlorid[qr] ;chromyl ;Chromylchlorid;chromylchlorid[qr]
2 prices
Selected condition:
Brand
- Sigma-Aldrich
- Sigma-Aldrich(India)
Package
- 10G
- ManufacturerSigma-Aldrich
- Product number200042
- Product descriptionChromyl chloride ≥99.99% trace metals basis
- Packaging10G
- Price₹7750.7
- Updated2022-06-14
- Buy
- ManufacturerSigma-Aldrich(India)
- Product number200042
- Product descriptionChromyl chloride ≥99.99% trace metals basis
- Packaging10G
- Price₹7750.7
- Updated2022-06-14
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
Sigma-Aldrich | 200042 | Chromyl chloride ≥99.99% trace metals basis | 10G | ₹7750.7 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 200042 | Chromyl chloride ≥99.99% trace metals basis | 10G | ₹7750.7 | 2022-06-14 | Buy |
Properties
Melting point :-96.5 °C (lit.)
Boiling point :117 °C (lit.)
Density :1.911 g/mL at 25 °C (lit.)
Flash point :117°C
solubility :reacts with H2O; soluble in ctc, chloroform,benzene
form :liquid
Specific Gravity :1.911
color :red
Water Solubility :Soluble in carbon tetrachloride, carbon disulfide, benzene, nitrobenzene, chloroform, and POCL3. Insoluble in water(Reacts).
Sensitive :Moisture Sensitive
Merck :14,2248
Dielectric constant :2.6(20℃)
Exposure limits :ACGIH: TWA 0.0001 ppm; STEL 0.00025 ppm (Skin)
NIOSH: TWA 0.0002 mg/m3 CAS DataBase Reference :14977-61-8(CAS DataBase Reference)
EPA Substance Registry System :Chromium(VI) dioxychloride (14977-61-8)
Boiling point :117 °C (lit.)
Density :1.911 g/mL at 25 °C (lit.)
Flash point :117°C
solubility :reacts with H2O; soluble in ctc, chloroform,benzene
form :liquid
Specific Gravity :1.911
color :red
Water Solubility :Soluble in carbon tetrachloride, carbon disulfide, benzene, nitrobenzene, chloroform, and POCL3. Insoluble in water(Reacts).
Sensitive :Moisture Sensitive
Merck :14,2248
Dielectric constant :2.6(20℃)
Exposure limits :ACGIH: TWA 0.0001 ppm; STEL 0.00025 ppm (Skin)
NIOSH: TWA 0.0002 mg/m3 CAS DataBase Reference :14977-61-8(CAS DataBase Reference)
EPA Substance Registry System :Chromium(VI) dioxychloride (14977-61-8)
Safety Information
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Description
Highly spin-polarized chromium dioxide (CrO2) thin films were deposited on 100 TiO2 substrates by chemical vapor deposition using chromyl chloride as a precursor. Chromyl chloride (Cr02C12) reacts with cyclohexane solvent at 75 OC to give a dark precipitate along with chlorocyclohexane and a small amount of cyclohexene (in 10.0 and ca. 0.3% yields based on chromium). Chromyl chloride, CrO2C12, oxidizes cyclooctane, isobutane, and toluene under mild conditions (25-60" C). The reactions give chlorinated products (chlorocyclooctane, tert- butyl chloride, and benzyl chloride) and a dark chromium-containing precipitate. Used for Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins. Chromyl chloride in carbon tetrachloride solution reacts in the cold with cyclohexene, cyclopentene, and 1-hexene to give the various isomeric chlorohydrins as the major products.More related product prices
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