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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organolithium >Lithium borohydride

Lithium borohydride

Lithium borohydride Structure
  • ₹1558.8 - ₹72722.35
  • Product name: Lithium borohydride
  • CAS: 16949-15-8
  • MF: BH4Li
  • MW: 21.78
  • EINECS:241-021-7
  • MDL Number:MFCD00011088
  • Synonyms:Lithium borohydride2M solution in tetrahydrofuranAcroSeal§3;Lithium boron tetrahydride;Lithium borohydride (LBH);Lithium Borohydride in THF;Lithium borohydride, 4M (10 wt.%) solution in THF, AcroSeal;LithiuM borohydride, 95% 10GR;LithiuM borohydride, 95% 50GR;LithiuM borohydride, 2.0 M solution in THF
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Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 1G
  • 5gm
  • 5G
  • 10G
  • 25G
  • 25gm
  • 50G
  • 100ML
  • 4X25ML
  • 800ML
  • ManufacturerSigma-Aldrich(India)
  • Product number222356
  • Product descriptionLithium borohydride ≥90%
  • Packaging1G
  • Price₹1558.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number62460
  • Product descriptionLithium borohydride ≥95.0%
  • Packaging5G
  • Price₹6007.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number702714
  • Product descriptionLithium borohydride solution 0.5?M in diethyl ether
  • Packaging100ML
  • Price₹7804.83
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number222356
  • Product descriptionLithium borohydride ≥90%
  • Packaging10G
  • Price₹8779.08
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number686026
  • Product descriptionLithium borohydride hydrogen-storage grade, ≥90%
  • Packaging10G
  • Price₹13628.68
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number230200
  • Product descriptionLithium borohydride solution 2.0?M in THF
  • Packaging4X25ML
  • Price₹15122.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number230200
  • Product descriptionLithium borohydride solution 2.0?M in THF
  • Packaging100ML
  • Price₹17493.2
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number222356
  • Product descriptionLithium borohydride ≥90%
  • Packaging50G
  • Price₹30688.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number62460
  • Product descriptionLithium borohydride ≥95.0%
  • Packaging25G
  • Price₹36112.2
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number702714
  • Product descriptionLithium borohydride solution 0.5?M in diethyl ether
  • Packaging800ML
  • Price₹40853.55
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number230200
  • Product descriptionLithium borohydride solution 2.0?M in THF
  • Packaging800ML
  • Price₹72722.35
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number L 1509
  • Product descriptionLithium borohydride, ≥95%
  • Packaging5gm
  • Price₹7389
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number L 1509
  • Product descriptionLithium borohydride, ≥95%
  • Packaging25gm
  • Price₹33093
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 222356 Lithium borohydride ≥90% 1G ₹1558.8 2022-06-14 Buy
Sigma-Aldrich(India) 62460 Lithium borohydride ≥95.0% 5G ₹6007.88 2022-06-14 Buy
Sigma-Aldrich(India) 702714 Lithium borohydride solution 0.5?M in diethyl ether 100ML ₹7804.83 2022-06-14 Buy
Sigma-Aldrich(India) 222356 Lithium borohydride ≥90% 10G ₹8779.08 2022-06-14 Buy
Sigma-Aldrich(India) 686026 Lithium borohydride hydrogen-storage grade, ≥90% 10G ₹13628.68 2022-06-14 Buy
Sigma-Aldrich(India) 230200 Lithium borohydride solution 2.0?M in THF 4X25ML ₹15122.53 2022-06-14 Buy
Sigma-Aldrich(India) 230200 Lithium borohydride solution 2.0?M in THF 100ML ₹17493.2 2022-06-14 Buy
Sigma-Aldrich(India) 222356 Lithium borohydride ≥90% 50G ₹30688.88 2022-06-14 Buy
Sigma-Aldrich(India) 62460 Lithium borohydride ≥95.0% 25G ₹36112.2 2022-06-14 Buy
Sigma-Aldrich(India) 702714 Lithium borohydride solution 0.5?M in diethyl ether 800ML ₹40853.55 2022-06-14 Buy
Sigma-Aldrich(India) 230200 Lithium borohydride solution 2.0?M in THF 800ML ₹72722.35 2022-06-14 Buy
ottokemi L 1509 Lithium borohydride, ≥95% 5gm ₹7389 2022-05-26 Buy
ottokemi L 1509 Lithium borohydride, ≥95% 25gm ₹33093 2022-05-26 Buy

Properties

Melting point :280 °C
Boiling point :66°C/760mmHg
Density :0.896 g/mL at 25 °C
Flash point :−1 °F
storage temp. :water-free area
solubility :Soluble in ether, THF, and aliphatic aminesSoluble in ether, tetrahydrofuran, aliphatic amines and ethanol.
form :Powder
color :White
Specific Gravity :0.66
explosive limit :4.00-75.60%(V)
Water Solubility :soluble H2O above pH 7, ether, tetrahydrofuran, aliphatic amines [MER06]
Sensitive :Air & Moisture Sensitive
Merck :14,5525
CAS DataBase Reference :16949-15-8(CAS DataBase Reference)
NIST Chemistry Reference :Lithium tetrahydroborate(16949-15-8)
EPA Substance Registry System :Borate(1-), tetrahydro-, lithium (16949-15-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Strong reducing agent. Used to reduce compounds containing ketones, aldehydes, ester carbonyls, acid chlorides, lactones, and epoxidesLithium borohydride is a versatile reducing agent for aldehydes, ketones, nitriles, primary amides, acid chlorides, lactones, epoxides, and esters. It is involved in the preparation of intercalation compounds and nanocomposites. It is used as a precursor for other borohydrides and acts as a catalyst in hydroboration reactions. It is known to be good reversible storage compound for anhydrous ammonia and hydrogen.

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