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ChemicalBook > Product Catalogue >Organic Chemistry >Carboxylic acids and derivatives >Carboxylic acid esters and derivatives >METHYL ISOCYANOACETATE

METHYL ISOCYANOACETATE

METHYL ISOCYANOACETATE Structure
  • ₹2800 - ₹18056.1
  • Product name: METHYL ISOCYANOACETATE
  • CAS: 39687-95-1
  • MF: C4H5NO2
  • MW: 99.09
  • EINECS:254-593-8
  • MDL Number:MFCD00000006
  • Synonyms:Methyl isocyanoacetate, technical grade;Methyl isocyanoacetate, 95%, tech.;(2-Oxo-2-methoxyethyl) isocyanide;2-Isocyanoacetic acid methyl ester;2-Oxo-2-methoxyethyl isocyanide;Methyl isocyanoacetate, tech., 95% 5GR;Acetic acid, 2-isocyano-, Methyl ester;METHYL ISOCYANOACETATE
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Brand

  • Sigma-Aldrich(India)
  • ALFA India
  • TCI Chemicals (India)

Package

  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number238880
  • Product descriptionMethyl isocyanoacetate technical grade, 95%
  • Packaging1G
  • Price₹5131.05
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number238880
  • Product descriptionMethyl isocyanoacetate technical grade, 95%
  • Packaging5G
  • Price₹18056.1
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H31069-06
  • Product descriptionMethyl isocyanoacetate, 95%
  • Packaging5g
  • Price₹7772
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H31069-03
  • Product descriptionMethyl isocyanoacetate, 95%
  • Packaging1g
  • Price₹3663
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM2549
  • Product descriptionMethyl Isocyanoacetate min. 97.0 %
  • Packaging5G
  • Price₹6900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM2549
  • Product descriptionMethyl Isocyanoacetate min. 97.0 %
  • Packaging1G
  • Price₹2800
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 238880 Methyl isocyanoacetate technical grade, 95% 1G ₹5131.05 2022-06-14 Buy
Sigma-Aldrich(India) 238880 Methyl isocyanoacetate technical grade, 95% 5G ₹18056.1 2022-06-14 Buy
ALFA India ALF-H31069-06 Methyl isocyanoacetate, 95% 5g ₹7772 2022-05-26 Buy
ALFA India ALF-H31069-03 Methyl isocyanoacetate, 95% 1g ₹3663 2022-05-26 Buy
TCI Chemicals (India) M2549 Methyl Isocyanoacetate min. 97.0 % 5G ₹6900 2022-05-26 Buy
TCI Chemicals (India) M2549 Methyl Isocyanoacetate min. 97.0 % 1G ₹2800 2022-05-26 Buy

Properties

Boiling point :75-76 °C10 mm Hg(lit.)
Density :1.09 g/mL at 25 °C(lit.)
refractive index :n20/D 1.417(lit.)
Flash point :193 °F
storage temp. :2-8°C
solubility :Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form :Liquid
color :Clear yellow to brown
Water Solubility :Miscible with organic solvents. Slightly miscible with water.
BRN :3537963
CAS DataBase Reference :39687-95-1(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.

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