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ChemicalBook > Product Catalogue >Inorganic chemistry >Inorganic salts >Metal halide and Halogen salt >Non-metal halides, sulfides or sulfonated >Phosphorus oxychloride

Phosphorus oxychloride

Phosphorus oxychloride Structure
  • ₹2790 - ₹1057570.01
  • Product name: Phosphorus oxychloride
  • CAS: 10025-87-3
  • MF: Cl3OP
  • MW: 153.33
  • EINECS:233-046-7
  • MDL Number:MFCD00011443
  • Synonyms:Phosphorus oxychlori;phosphollJs oxychloride;Fosforoxychlorid;Oxychlorid fosforecny;Trichlorophosphorus oxide;trichlorophosphorusoxide ;PHOSPHORUS(V) OXIDE CHLORIDE;PHOSPHORUS(V) TRICHLORIDE OXIDE
3 prices
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Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 1L
  • 8223399300
  • 500mL
  • ManufacturerSigma-Aldrich(India)
  • Product number8.22339
  • Product descriptionPhosphoryl chloride for synthesis
  • Packaging1L
  • Price₹16460
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.22339
  • Product descriptionPhosphoryl chloride for synthesis
  • Packaging8223399300
  • Price₹1057570.01
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number P 1755
  • Product descriptionPhosphorous oxychloride 98%
  • Packaging500mL
  • Price₹2790
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 8.22339 Phosphoryl chloride for synthesis 1L ₹16460 2022-06-14 Buy
Sigma-Aldrich(India) 8.22339 Phosphoryl chloride for synthesis 8223399300 ₹1057570.01 2022-06-14 Buy
ottokemi P 1755 Phosphorous oxychloride 98% 500mL ₹2790 2022-05-26 Buy

Properties

Melting point :1.25 °C(lit.)
Boiling point :107 °C
Density :1.645 g/mL at 25 °C(lit.)
vapor density :5.3 (vs air)
vapor pressure :104 mm Hg ( 50 °C)
refractive index :n20/D 1.461
Flash point :105.8°C
storage temp. :Store below +30°C.
solubility :Phosphorus(V) oxychloride is soluble in many organic solvents.
form :Liquid
Specific Gravity :1.692 (15/15℃)
color :Colorless
PH :1.0 (5g/l, H2O, 25℃)
Odor :Pungent odour
Water Solubility :reacts exothermically
Sensitive :Moisture Sensitive
Merck :14,7349
Exposure limits :TLV-TWA0.628 mg/m3 (0.1 ppm)(ACGIH).
Dielectric constant :14.0(22℃)
Stability :Stable. Reacts violently with water. Incompatible with many metals, alcohols, amines, phenol, DMSO, strong bases.
InChIKey :XHXFXVLFKHQFAL-UHFFFAOYSA-N
LogP :0.357 (est)
CAS DataBase Reference :10025-87-3(CAS DataBase Reference)
NIST Chemistry Reference :Phosphoryl chloride(10025-87-3)
EPA Substance Registry System :Phosphorus oxychloride (10025-87-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314 Get medical advice/attention if you feel unwell.

Description

Phosphorus(V) oxychloride is widely used as a dehydrating agent and a chlorinating agent. Useful for the conversion of amide to nitriles, in Bischler-Napieralski reactions, Vilsmeier Haak reaction, and other reactions producing commercially important intermediates. Acts a source of liquid phosphorus in semiconductor industry. Manufacture of trialkyl phosphate esters and triarylphosphate esters, including commercially popular tricresyl phosphate,which is useful as a plasticizer, flame retardant, gasoline additive, hydrolytic fluid, etc...

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