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(R)-H8-BINAP

(R)-H8-BINAP Structure
  • ₹6007.88 - ₹11084.8
  • Product name: (R)-H8-BINAP
  • CAS: 139139-86-9
  • MF: C44H40P2
  • MW: 630.74
  • EINECS:
  • MDL Number:MFCD01630795
  • Synonyms:(R)-H8-BINAP;(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl(R)-H8-BINAP;(R)-(+)-2,2μ-Bis(diphenylphospino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl, [(1R)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-[1,1μ-binaphthalene]-2,2μ-diyl]bis[diphenylphosphine];(R)-(+)-2,2'-Bis(diphenylphospino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl;(R)-(+)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl;(R)-H8-BINAP >=94%;(R)-(+)-2,2-Bis(diphenylphosphino)-5,5,6,6,7,7,8,8-octahydro-[1,1-binaphthalene]-2,2-diyl]bis[diphenylphosphine];(R)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene
Price3 Properties Safety Information Description
3 prices
Selected condition：

Brand

  • Sigma-Aldrich
  • Sigma-Aldrich(India)

Package

  • 50MG
  • 100MG
  • ManufacturerSigma-Aldrich
  • Product number692387
  • Product description(R)-H8-BINAP ≥94%
  • Packaging50MG
  • Price₹6007.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692387
  • Product description(R)-H8-BINAP ≥94%
  • Packaging50MG
  • Price₹6007.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692387
  • Product description(R)-H8-BINAP ≥94%
  • Packaging100MG
  • Price₹11084.8
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 692387 (R)-H8-BINAP ≥94% 50MG ₹6007.88 2022-06-14 Buy
Sigma-Aldrich(India) 692387 (R)-H8-BINAP ≥94% 50MG ₹6007.88 2022-06-14 Buy
Sigma-Aldrich(India) 692387 (R)-H8-BINAP ≥94% 100MG ₹11084.8 2022-06-14 Buy

Properties

Melting point :207-208°C
Boiling point :745.6±60.0 °C(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Powder
color :off-white
optical activity :[α]20/D +74°, c = 0.5 in toluene
CAS DataBase Reference :139139-86-9

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Catalytic ligand used for:
  • Enantioselective synthesis of dihydrobenzofurans and dihydronaphthofurans via olefin isomerization/enantioselective intramolecular Alder-ene reaction of enynes catalyzed by Rh
  • Preparation of axially chiral biaryl compounds by gold-catalyzed stereoselective intramolecular hydroarylation
  • Preparation of chiral 3-alkyl-substituted indolines by tandem condensation-asymmetric hydrogenation of indoles with aldehydes, catalyzed by Bronsted acids and palladium BINAP complexes
  • Stereoselective preparation of hydrindanes and decalins containing up to four contiguous stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of ene-allenes with allenes
  • Rhodium-catalyzed asymmetric formal olefination or cycloaddition of 1,3-dicarbonyl compounds with 1,6-diynes or 1,6-enynes
  • Stereoselective preparation of 2,3-substituted indolines via Pd-catalyzed hydrogenation of (α-hydroxyalkyl)indoles

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Related product price

Suppliers and manufacturers

career henan chemical co
(R)-H8-BINAP
₹1.00 /1KG
(R)-H8-BINAP CAS:139139-86-9
XINXIANG RUNYU MATERIAL CO., LTD.
(R)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl；(R)-H8-Binap
₹0.00 /10g
(R)-2,2'-Bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl；(R)-H8-Binap CAS:139139-86-9
Chongqing Chemdad Co., Ltd
Zhengzhou Alfa Chemical Co.,Ltd
changzhou huayang technology co., ltd
Hefei TNJ Chemical Industry Co.,Ltd.
Shaoxin Catsyn Co., Ltd.
Aladdin Scientific
Wuhan Fortuna Chemical Co.,Ltd
Watson Biotechnology Co.,Ltd