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ChemicalBook > Product Catalogue >Analytical Chemistry >Standard >Standard Substance >(S)-1,2,4-Butanetriol

(S)-1,2,4-Butanetriol

(S)-1,2,4-Butanetriol Structure
  • ₹10727.58 - ₹32475
  • Product name: (S)-1,2,4-Butanetriol
  • CAS: 42890-76-6
  • MF: C4H10O3
  • MW: 106.12
  • EINECS:610-080-4
  • MDL Number:MFCD00063213
  • Synonyms:(S)-1,2,4-Butanetriol,95%,99% ee;(2S)-(-)-1,2,4-Trihydroxybutane;ASTM D6584 1,2,4-Butanetriol Solution ;(2S)-BUTANE-1,2,4-TRIOL;1,2,4-BUTANETRIOL, (S);BUTANETRIOL(CAS#: 42890-76-6),INT STD#1&;(S)-()-1,2,4-Butanetriol 98%;(S)-(-)-1,2,4-Butanetriol(ee/glc)
3 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 5ML
  • 5G
  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number296678
  • Product description(S)-(−)-1,2,4-Butanetriol 98%
  • Packaging5G
  • Price₹10727.58
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number44896-U
  • Product descriptionASTM® D6584 1,2,4-Butanetriol Solution 1000?μg/mL in pyridine, analytical standard
  • Packaging5ML
  • Price₹22703.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number296678
  • Product description(S)-(−)-1,2,4-Butanetriol 98%
  • Packaging25G
  • Price₹32475
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 296678 (S)-(−)-1,2,4-Butanetriol 98% 5G ₹10727.58 2022-06-14 Buy
Sigma-Aldrich(India) 44896-U ASTM® D6584 1,2,4-Butanetriol Solution 1000?μg/mL in pyridine, analytical standard 5ML ₹22703.1 2022-06-14 Buy
Sigma-Aldrich(India) 296678 (S)-(−)-1,2,4-Butanetriol 98% 25G ₹32475 2022-06-14 Buy

Properties

alpha :-30 º (c=1, MeOH)
Boiling point :150 °C0.04 mm Hg(lit.)
Density :1.19 g/mL at 25 °C(lit.)
refractive index :n20/D 1.475(lit.)
Flash point :>110°C
storage temp. :Inert atmosphere,Room Temperature
solubility :Chloroform (Slightly), Methanol (Sparingly), Water (Slightly)
form :Oil
pka :14.02±0.20(Predicted)
Specific Gravity :1.190
color :Colourless
optical activity :[α]19/D 28±2, c = 1 in methanol
Water Solubility :soluble
Sensitive :Hygroscopic
BRN :1719408
Stability :Hygroscopic
CAS DataBase Reference :42890-76-6(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
Precautionary statements:
P201 Obtain special instructions before use.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

(S)-(-)-1,2,4-Butanetriol may be used as a starting material in the enantioselective total syntheses of (+)-azimine and (+)-carpaine.It can also be used to prepare the following organic building blocks:(+)-3,4-epoxy-1-butanol(2S,4S)-4-(hydroxymethyl)-2-ferrocenyl-1,3-dioxane(S)-1,2,4-triacetoxybutane via acetylation with acetic anhydride(S)-1,2,4-tris-(3,5-dinitrobenzoy1oxy)butane via esterification with 3,5-dinitrobenzoyl chloride

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