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(S)-VANOL

(S)-VANOL Structure
  • ₹11084.8
  • Product name: (S)-VANOL
  • CAS: 147702-13-4
  • MF: C32H22O2
  • MW: 438.52
  • EINECS:
  • MDL Number:MFCD08459338
  • Synonyms:(2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL;(2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL;(R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol;(S)-VANOL;(R)-VANOL;(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL);(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL;(2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
Price1 Properties Safety Information Description
1 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • ManufacturerSigma-Aldrich(India)
  • Product number675156
  • Product description(R)-VANOL 97%
  • Packaging250MG
  • Price₹11084.8
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 675156 (R)-VANOL 97% 250MG ₹11084.8 2022-06-14 Buy

Properties

Melting point :200-204 °C
Boiling point :580.1±50.0 °C(Predicted)
alpha :+362° (c 1.0, THF)
Density :1.251±0.06 g/cm3(Predicted)
storage temp. :2-8°C
pka :7.71±0.50(Predicted)
form :Powder
color :white to pale yellow
optical activity :[α]20/D +310°, c = 1 in chloroform
CAS DataBase Reference :147702-13-4

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.

Description

(R)-VANOL is a vaulted biaryl ligand that may be used in the following processes:Transformation of 3-substituted cyclobutanones to enantiopure γ-butyrolactones via asymmetric Baeyer-Villiger Reaction in the presence of an aluminum catalyst.Asymmetric aziridination ofN-(4-(Methylsulfonyl)benzylidene)diphenylmethanamine to form (2S,3S)-ethyl 1-benzhydryl-3-(4-(methylsulfonyl)phenyl) aziridine-2-carboxylate.Conjugate addition of terminal alkynes to 2-arylidene-1,3-diketones with high enantioselectivity in the presence of diethyl zinc.

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Suppliers and manufacturers

Shanghai Acmec Biochemical Technology Co., Ltd.
Aladdin Scientific
Shanghai Likang New Materials Co., Limited ABCR GmbH & CO. KG Shanghai Kaiwei Chemical Technology Co., Ltd. Bide Pharmatech Ltd. Beijing Jin Ming Biotechnology Co., Ltd. Sigma-Aldrich Aikon International Limited Bide Pharmatech Ltd.