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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organolithium >SEC-BUTYLLITHIUM

SEC-BUTYLLITHIUM

SEC-BUTYLLITHIUM Structure
  • ₹0
  • Product name: SEC-BUTYLLITHIUM
  • CAS: 598-30-1
  • MF: C4H9Li
  • MW: 64.06
  • EINECS:209-927-7
  • MDL Number:MFCD00009323
  • Synonyms:sec-Butyllithium, 1.0 M solution in Hexane, HySeal;SEC-BUTYLLITHIUM;LITHIUM-2-BUTANIDE;LITHIUM SEC-BUTYL;s-butyllithium(1.3M)in cyclonexane;Sec-butyllithium 1.4M in cyclohexane;sec-Butyllithium, 1.3M sol. in cyclohexane/hexane (92/8), AcroSeal;sec-ButyllithiuM, 12% (ca 1.4M) in cyclohexane/hexane, packed in resealable septuM seal bottle
Manufacturer Product number Product description Packaging Price Updated Buy

Properties

Density :0.769 g/mL at 25 °C
Flash point :1 °F
storage temp. :2-8°C
form :Liquid
color :Clear colorless
Sensitive :Air & Moisture Sensitive
BRN :3587206
Exposure limits :ACGIH: TWA 100 ppm
OSHA: TWA 300 ppm(1050 mg/m3)
NIOSH: IDLH 1300 ppm; TWA 300 ppm(1050 mg/m3) InChIKey :VATDYQWILMGLEW-UHFFFAOYSA-N
CAS DataBase Reference :598-30-1(CAS DataBase Reference)
EPA Substance Registry System :Lithium, (1-methylpropyl)- (598-30-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H252 Self-heating in large quantities; may catch fire Self-heating substances and mixtures Category 2 Warning P235+P410, P280, P407, P413, P420
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P422 Store contents under …

Description

sec-Butyllithium is used almost exclusively as a polymerization catalyst. It is more expensive than n-butyllithium and is used mainly because of its greater reactivity and faster polymerization initiation.

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