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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organolithium >Lithium diisopropylamide

Lithium diisopropylamide

Lithium diisopropylamide Structure
  • ₹5390.85 - ₹34012.15
  • Product name: Lithium diisopropylamide
  • CAS: 4111-54-0
  • MF: C6H16LiN
  • MW: 109.14
  • EINECS:223-893-0
  • MDL Number:MFCD00064449
  • Synonyms:LITHIUM DIISOPROPYLAMIDE THF COMPLEX;LITHIUM DIISOPROPYLAMIDE;LDA THF COMPLEX;DIISOPROPYLAMINOLITHIUM;Lithium diisopropylamide solution;n-(1-methylethyl)-2-propanaminlithiumsalt ;Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene;LITHIUMDIISOPROPYLAMIDE,2MSOLUTIONINTETRAHYDROFURAN/HEPTANE/ETHYLBENZENE
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Brand

  • Sigma-Aldrich
  • Sigma-Aldrich(India)

Package

  • 75G
  • 100ML
  • 4X25ML
  • 4X100ML
  • 500ML
  • 800ML
  • ManufacturerSigma-Aldrich
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene
  • Packaging4X100ML
  • Price₹25276.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene
  • Packaging800ML
  • Price₹34012.15
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number296961
  • Product descriptionLithium diisopropylamide 10?wt. % suspension in hexanes
  • Packaging75G
  • Price₹5390.85
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number774766
  • Product descriptionLithium diisopropylamide solution 1.0?M in THF/hexanes
  • Packaging100ML
  • Price₹7155.33
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene
  • Packaging100ML
  • Price₹7274.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number774766
  • Product descriptionLithium diisopropylamide solution 1.0?M in THF/hexanes
  • Packaging4X25ML
  • Price₹7956.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene
  • Packaging4X25ML
  • Price₹8963.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number774766
  • Product descriptionLithium diisopropylamide solution 1.0?M in THF/hexanes
  • Packaging500ML
  • Price₹19853.05
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene
  • Packaging4X100ML
  • Price₹25276.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene
  • Packaging800ML
  • Price₹34012.15
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 361798 Lithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene 4X100ML ₹25276.38 2022-06-14 Buy
Sigma-Aldrich 361798 Lithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene 800ML ₹34012.15 2022-06-14 Buy
Sigma-Aldrich(India) 296961 Lithium diisopropylamide 10?wt. % suspension in hexanes 75G ₹5390.85 2022-06-14 Buy
Sigma-Aldrich(India) 774766 Lithium diisopropylamide solution 1.0?M in THF/hexanes 100ML ₹7155.33 2022-06-14 Buy
Sigma-Aldrich(India) 361798 Lithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene 100ML ₹7274.4 2022-06-14 Buy
Sigma-Aldrich(India) 774766 Lithium diisopropylamide solution 1.0?M in THF/hexanes 4X25ML ₹7956.38 2022-06-14 Buy
Sigma-Aldrich(India) 361798 Lithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene 4X25ML ₹8963.1 2022-06-14 Buy
Sigma-Aldrich(India) 774766 Lithium diisopropylamide solution 1.0?M in THF/hexanes 500ML ₹19853.05 2022-06-14 Buy
Sigma-Aldrich(India) 361798 Lithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene 4X100ML ₹25276.38 2022-06-14 Buy
Sigma-Aldrich(India) 361798 Lithium diisopropylamide solution 2.0?M in THF/heptane/ethylbenzene 800ML ₹34012.15 2022-06-14 Buy

Properties

Melting point :decomposes [MER06]
Boiling point :65 °C
Density :0.864 g/mL at 25 °C (lit.)
vapor density :>1 (vs air)
Flash point :91 °F
storage temp. :2-8°C
solubility :soluble in ethyl ether; insoluble in hydrocarbon solvents
form :liquid
color :brown
Water Solubility :decomposes
Sensitive :Air & Moisture Sensitive
Merck :14,3196
BRN :3655042
CAS DataBase Reference :4111-54-0(CAS DataBase Reference)
EPA Substance Registry System :2-Propanamine, N-(1-methylethyl)-, lithium salt (4111-54-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Titanium-ate enolates prepared from ketones by Ti(OiPr)4and LDA underwent efficient radical trifluoromethylation providing trifluoromethyl ketones in good yield.Used in directedortho-lithiation of arylsulfonyloxazolidinones to prepareN-substituted saccharin analogs.

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