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ChemicalBook > Product Catalogue >Chemical Reagents >Silane reagent >TAS-F

TAS-F

TAS-F Structure
  • ₹4578.98 - ₹23111.38
  • Product name: TAS-F
  • CAS: 59218-87-0
  • MF: C9H24F2N3SSi
  • MW: 272.45
  • EINECS:
  • MDL Number:MFCD00012170
  • Synonyms:TRIS(DIMETHYLAMINO)SULFUR(TRIMETHYLSILYL)DIFLUORIDE 95%;Tris(dimethylamino)(trimethylsilyl)sulfur;Sulfiliminium, S,S-bis(dimethylamino)-N,N-dimethyl-, difluorotrimethylsilicate(1-);TRIS(DIMETHYLAMINO)SULFUR(TRIMETHYLSILYL)DIFLUORIDE, tech-95;Tris(dimethylamino)sulphonium difluoro(trimethyl)silicate, tech;Tris(dimethylamino)sulphur trimethylsilyl difluoride, TAS-F;Tris(diMethylaMino)sulfoniuM difluorotriMethylsilicate technical grade;TRIS(DIMETHYLAMINO)SULFUR (TRIMETHYLSILYL)DIFLUORIDE, PRACT.
Price3 Properties Safety Information Description
3 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number250600
  • Product descriptionTris(dimethylamino)sulfonium difluorotrimethylsilicate technical grade
  • Packaging5G
  • Price₹23111.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number250600
  • Product descriptionTris(dimethylamino)sulfonium difluorotrimethylsilicate technical grade
  • Packaging1G
  • Price₹6083.65
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number250600
  • Product descriptionTris(dimethylamino)sulfonium difluorotrimethylsilicate technical grade
  • Packaging250MG
  • Price₹4578.98
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 250600 Tris(dimethylamino)sulfonium difluorotrimethylsilicate technical grade 5G ₹23111.38 2022-06-14 Buy
Sigma-Aldrich(India) 250600 Tris(dimethylamino)sulfonium difluorotrimethylsilicate technical grade 1G ₹6083.65 2022-06-14 Buy
Sigma-Aldrich(India) 250600 Tris(dimethylamino)sulfonium difluorotrimethylsilicate technical grade 250MG ₹4578.98 2022-06-14 Buy

Properties

storage temp. :2-8°C
solubility :R = Me, sol MeCN, pyridine, benzonitrile; partially sol THF. R = Et, sol THF, MeCN. Both react slowly with MeCN.
form :powder
color :White to off-white
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :3577020

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF2SiMe3) can be used as a mild deprotecting reagent for the cleavage of silicon protecting groups.
It can also be used
  • To synthesize deoxyfluoro sugars by reacting with trifluoromethanesulfonyl derivatives of partially protected sugars.
  • As a reagent for the fluorination of hydroxyl-containing compounds.

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