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ChemicalBook > Product Catalogue >Flavors and fragrances >Synthetic fragrances >Aromatic acid, ester and derivatives >Tiglic acid

Tiglic acid

Tiglic acid Structure
  • ₹1310 - ₹20800
  • Product name: Tiglic acid
  • CAS: 80-59-1
  • MF: C5H8O2
  • MW: 100.12
  • EINECS:201-295-0
  • MDL Number:MFCD00066864
  • Synonyms:E-2,3-DIMETHYLACRYLIC ACID;FEMA 3599;trans-2,3-Dimethylacrylic acid~(E)-2-Methyl-2-butenoic acid;TRANS-2-METHYL-2-BUTENOIC ACID 99+%;TiglicAcid,>98%;trans-2-Methyl-2-butenoicacid,97%;2-Butenoicacid,2-methyl-,(E)- ;2-methyl-(E)-2-butenoic acid
9 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • SRL

Package

  • 25G
  • 100G
  • 500G
  • 1KG
  • 1SAMPLE-K
  • 25Gms
  • 100Gms
  • ManufacturerTCI Chemicals (India)
  • Product numberT0246
  • Product descriptionTiglic Acid min. 98.0 %
  • Packaging25G
  • Price₹2800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0246
  • Product descriptionTiglic Acid min. 98.0 %
  • Packaging100G
  • Price₹6000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0246
  • Product descriptionTiglic Acid min. 98.0 %
  • Packaging500G
  • Price₹20800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberW359904
  • Product descriptiontrans-2-Methyl-2-butenoic acid ≥99%, FG
  • Packaging1SAMPLE-K
  • Price₹5141.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT35203
  • Product descriptiontrans-2,3-Dimethylacrylic acid 98%
  • Packaging100G
  • Price₹6776.45
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberW359904
  • Product descriptiontrans-2-Methyl-2-butenoic acid ≥99%, FG
  • Packaging100G
  • Price₹9114.65
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberW359904
  • Product descriptiontrans-2-Methyl-2-butenoic acid ≥99%, FG
  • Packaging1KG
  • Price₹20675.75
  • Updated2022-06-14
  • Buy
  • ManufacturerSRL
  • Product number90196
  • Product descriptionTiglic Acid extrapure, 98%
  • Packaging25Gms
  • Price₹1310
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number90196
  • Product descriptionTiglic Acid extrapure, 98%
  • Packaging100Gms
  • Price₹4620
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T0246 Tiglic Acid min. 98.0 % 25G ₹2800 2022-05-26 Buy
TCI Chemicals (India) T0246 Tiglic Acid min. 98.0 % 100G ₹6000 2022-05-26 Buy
TCI Chemicals (India) T0246 Tiglic Acid min. 98.0 % 500G ₹20800 2022-05-26 Buy
Sigma-Aldrich(India) W359904 trans-2-Methyl-2-butenoic acid ≥99%, FG 1SAMPLE-K ₹5141.88 2022-06-14 Buy
Sigma-Aldrich(India) T35203 trans-2,3-Dimethylacrylic acid 98% 100G ₹6776.45 2022-06-14 Buy
Sigma-Aldrich(India) W359904 trans-2-Methyl-2-butenoic acid ≥99%, FG 100G ₹9114.65 2022-06-14 Buy
Sigma-Aldrich(India) W359904 trans-2-Methyl-2-butenoic acid ≥99%, FG 1KG ₹20675.75 2022-06-14 Buy
SRL 90196 Tiglic Acid extrapure, 98% 25Gms ₹1310 2022-05-26 Buy
SRL 90196 Tiglic Acid extrapure, 98% 100Gms ₹4620 2022-05-26 Buy

Properties

Melting point :61-64 °C(lit.)
Boiling point :95-96 °C12 mm Hg(lit.)
Density :0.969 g/mL at 25 °C(lit.)
FEMA :3599 | 2-METHYL-TRANS-2-BUTENOIC ACID
refractive index :nD81 1.4342
Flash point :101°C
storage temp. :2-8°C
solubility :Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form :Crystalline Powder and Chunks
pka :pK (25°) 5.02
Specific Gravity :0.969
color :White to beige
Odor :at 10.00 % in dipropylene glycol. sweet dry spicy woody caramel
Odor Type :spicy
Water Solubility :SOLUBLE IN HOT WATER
JECFA Number :1205
Merck :14,9433
BRN :1236500
InChIKey :UIERETOOQGIECD-ONEGZZNKSA-N
LogP :1.35
CAS DataBase Reference :80-59-1(CAS DataBase Reference)
NIST Chemistry Reference :2-Butenoic acid, 2-methyl-, (E)-(80-59-1)
EPA Substance Registry System :2-Butenoic acid, 2-methyl-, (2E)- (80-59-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tiglic acid (also (E)-2-Methylbut-2-enoic acid) is an organic acid. It occurs in croton oil, Roman chamomile, and geranium. It can be prepared by dehydration of MEK cyanohydrin, followed by the hydrolysis of the nitrile function. It is either in the form of a thick syrup or colorless crystals.  It is with a sweet, warm, spicy odor. It is used to synthesize esters for perfume manufacturing industry and as a raw material to produce acids and esters, which are applied as flavoring agent for food and beverage industry. Tiglic acid is also a useful starting material in the synthesis of pharmaceutical intermediates.

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