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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Cyanide / nitrile >Trichloroacetonitrile

Trichloroacetonitrile

Trichloroacetonitrile Structure
  • ₹2500 - ₹26900.13
  • Product name: Trichloroacetonitrile
  • CAS: 545-06-2
  • MF: C2Cl3N
  • MW: 144.39
  • EINECS:208-885-7
  • MDL Number:MFCD00001842
  • Synonyms:trichloromethylcarbonitrile;Trichlroacetonitrile;TRICHLOROACETONITRILE, 1000MG, NEAT;Trichloroacetonitrile,97%;TRICHLORACETONITRILE;Trichlorocyanomethane;Trichloroacetonitrile ,98%;Trichloromethylnitrile
8 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • 50ML
  • 100G
  • 250ML
  • 500G
  • ManufacturerTCI Chemicals (India)
  • Product numberT0372
  • Product descriptionTrichloroacetonitrile min. 98.0 %
  • Packaging25G
  • Price₹2500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0372
  • Product descriptionTrichloroacetonitrile min. 98.0 %
  • Packaging100G
  • Price₹6500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0372
  • Product descriptionTrichloroacetonitrile min. 98.0 %
  • Packaging500G
  • Price₹10700
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT53805
  • Product descriptionTrichloroacetonitrile 98%
  • Packaging5G
  • Price₹5423.33
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.08222
  • Product descriptionTrichloroacetonitrile for synthesis
  • Packaging50ML
  • Price₹5670
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT53805
  • Product descriptionTrichloroacetonitrile 98%
  • Packaging100G
  • Price₹11084.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.08222
  • Product descriptionTrichloroacetonitrile for synthesis
  • Packaging250ML
  • Price₹14440
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT53805
  • Product descriptionTrichloroacetonitrile 98%
  • Packaging500G
  • Price₹26900.13
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T0372 Trichloroacetonitrile min. 98.0 % 25G ₹2500 2022-05-26 Buy
TCI Chemicals (India) T0372 Trichloroacetonitrile min. 98.0 % 100G ₹6500 2022-05-26 Buy
TCI Chemicals (India) T0372 Trichloroacetonitrile min. 98.0 % 500G ₹10700 2022-05-26 Buy
Sigma-Aldrich(India) T53805 Trichloroacetonitrile 98% 5G ₹5423.33 2022-06-14 Buy
Sigma-Aldrich(India) 8.08222 Trichloroacetonitrile for synthesis 50ML ₹5670 2022-06-14 Buy
Sigma-Aldrich(India) T53805 Trichloroacetonitrile 98% 100G ₹11084.8 2022-06-14 Buy
Sigma-Aldrich(India) 8.08222 Trichloroacetonitrile for synthesis 250ML ₹14440 2022-06-14 Buy
Sigma-Aldrich(India) T53805 Trichloroacetonitrile 98% 500G ₹26900.13 2022-06-14 Buy

Properties

Melting point :-42 °C
Boiling point :83-84 °C(lit.)
Density :1.44 g/mL at 25 °C(lit.)
vapor pressure :58 mm Hg ( 20 °C)
refractive index :n20/D 1.441(lit.)
Flash point :None
storage temp. :Store below +30°C.
solubility :<0.1 g/100 mL at 21.5°C
form :Liquid
color :Clear colorless to very slightly yellow
Odor :odor of chloral and hydrogen cyanide
Water Solubility :<0.1 g/100 mL at 21.5 ºC
Sensitive :Lachrymatory
Merck :14,9628
BRN :605572
Dielectric constant :4.6(60℃)
Exposure limits :NIOSH: IDLH 25 mg/m3
Stability :Stable, but water sensitive. Incompatible with acids, water, steam. May hydrolyze in alkali or acid conditions. Flammable.
CAS DataBase Reference :545-06-2(CAS DataBase Reference)
IARC :3 (Vol. 52, 71) 1999
NIST Chemistry Reference :Acetonitrile, trichloro-(545-06-2)
EPA Substance Registry System :Trichloroacetonitrile (545-06-2)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Description

Trichloroacetonitrile is involved as a reagent in Overman rearrangement, which is used to prepare alylic amines from allylic alcohols. It is also used to prepare bistrichloroacetimidates from diols leading to dihyrooxazines through acid catalyzed cyclization. Further, it is utilized in the synthesis of trichloroacetimidates by 1,8-Diazobicyclo[5.4.0]undec-7-ene (DBU) catalyzed addition of allylic alcohols. It finds application in the study of the methoxy methyl (MOM) catalyzed aza-Claisen rearrangement.

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