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ChemicalBook > Product Catalogue >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon nitrification >Trichloronitromethane

Trichloronitromethane

Trichloronitromethane Structure
  • ₹0
  • Product name: Trichloronitromethane
  • CAS: 76-06-2
  • MF: CCl3NO2
  • MW: 164.38
  • EINECS:200-930-9
  • MDL Number:MFCD00041878
  • Synonyms:NEMAX(R);NITROCHLOROFORM(R);Nitrotrichloromethane;TRICHLORONITROMETHANE;Aquinite;Chloorpikrine;Chloroform, nitro-;CHLOR-O-PIC(R)
Properties Safety Information Description
Manufacturer Product number Product description Packaging Price Updated Buy

Properties

Melting point :-64°; mp -69.2° (corr)
Boiling point :112 °C
Density :1.657
vapor pressure :18.3 at 20 °C (Meister, 1988)
refractive index :1.461
storage temp. :0-6°C
solubility :Miscible with acetone, benzene, carbon disulfide, carbon tetrachloride, ether, and methanol (Worthing and Hance, 1991)
form :Oily Liquid
Water Solubility :2,270 mg/L at 0 °C (Gunther et al., 1968)
1.621 g/L at 25 °C (quoted, Windholz et al., 1983) Merck :13,2175
BRN :1756135
Henry's Law Constant :2.44 (static headspace-GC, Welke et al., 1998)
Dielectric constant :7.3200000000000003
Exposure limits :NIOSH REL: TWA 0.1 ppm, IDLH 2 ppm; OSHA PEL: TWA 0.1 ppm; ACGIH TLV: TWA 0.1 ppm, STEL 0.3 ppm.
Stability :Stable. May decompose violently if heated. Large volumes of this chemical may be shock-sensitive. Reacts violently with sodium methoxide, propargyl bromide and aniline. Incompatible with 3-bromopropyne, strong oxidizers, plastics, rubber, iron, zinc and other light metals.
LogP :2.090
CAS DataBase Reference :76-06-2(CAS DataBase Reference)
NIST Chemistry Reference :Chloropicrin(76-06-2)
EPA Substance Registry System :Chloropicrin (76-06-2)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P284 Wear respiratory protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.

Description

Chloropicrin is a colorless to faint-yellow oily liquid with an intensely irritating and sharp odor with characteristics of tear gas. Some common trade names of products containing chloropicrin include Dolochlor, Aquinite, Nemax, Pic-Chlor, Timberfume, Profume A, Tri-Clor, and Microlysin. It has a molecular weight of 164.38, water solubility of 2000 mg l1 at 25°C, and melting and boiling points of 64 and 112°C, respectively. Chloropicrin is nonflammable and has a vapor density of 5.7 compared to the vapor density of one assigned to air. Heating above 234 F results in explosive decomposition of chloropicrin, leading to the release of toxic gases, including nitrogen oxides, phosgene, nitrosyl chloride, chlorine, and carbon monoxide. Chloropicrin is a widely used fungicide that is primarily used for preplant soil fumigation. Chloropicrin is used to fumigate stored grain and to treat soil against fungi, insects, and nematodes either as a stand-alone treatment or in combination with other fumigants like methyl bromide and sulfuryl fluoride for enhanced potency. Chloropicrin is also used to prevent internal decay of wood poles and timber caused by fungi and insects.

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