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ChemicalBook > Product Catalogue >Organic Chemistry >Amides >Naphthenic amines derivatives >o-Phenylenediamine

o-Phenylenediamine

o-Phenylenediamine Structure
  • ₹351 - ₹44644
  • Product name: o-Phenylenediamine
  • CAS: 95-54-5
  • MF: C6H8N2
  • MW: 108.14
  • EINECS:202-430-6
  • MDL Number:MFCD00007721
  • Synonyms:1,2-Diaminobenzene, o-Phenylenediamine, OPD;1,2-Fenylendiamin;benzene,1,2-diamino- ;diamino-1,2benzene ;EK 1700;ek1700 ;sq15500 ;PHENYLENEDIAMINE(O-)
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • SRL
  • ottokemi

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  • 100TABLETS
  • ManufacturerALFA India
  • Product numberALF-A11946-14
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging25g
  • Price₹1821
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A11946-30
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging250g
  • Price₹2889
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-A11946-0B
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging1000g
  • Price₹6064
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-A11946-0I
  • Product descriptiono-Phenylenediamine, 98%
  • Packaging5000g
  • Price₹44644
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberP0168
  • Product description1,2-Phenylenediamine min. 98.0 %
  • Packaging25G
  • Price₹2000
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberP1805
  • Product description1,2-Phenylenediamine [for Biochemical Research] min. 98.0 %
  • Packaging1G
  • Price₹2600
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberP0168
  • Product description1,2-Phenylenediamine min. 98.0 %
  • Packaging100G
  • Price₹3300
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberP1805
  • Product description1,2-Phenylenediamine [for Biochemical Research] min. 98.0 %
  • Packaging5G
  • Price₹6800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberP0168
  • Product description1,2-Phenylenediamine min. 98.0 %
  • Packaging500G
  • Price₹11400
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberP0968
  • Product description1,2-Phenylenediamine min. 98.0 %
  • Packaging25G
  • Price₹12900
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product numberP23938
  • Product descriptiono-Phenylenediamine flaked, 99.5%
  • Packaging5G
  • Price₹2035.1
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product numberP23938
  • Product descriptiono-Phenylenediamine flaked, 99.5%
  • Packaging50G
  • Price₹2543.88
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.14538
  • Product description1,2-Phenylenediamine for synthesis
  • Packaging5G
  • Price₹2770
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product numberP23938
  • Product descriptiono-Phenylenediamine flaked, 99.5%
  • Packaging100G
  • Price₹3290.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberP23938
  • Product descriptiono-Phenylenediamine flaked, 99.5%
  • Packaging500G
  • Price₹4557.33
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number1.07243
  • Product description1,2-Phenylenediamine GR for analysis
  • Packaging50G
  • Price₹8730.01
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-A11946-14 o-Phenylenediamine, 98% 25g ₹1821 2022-05-26 Buy
ALFA India ALF-A11946-30 o-Phenylenediamine, 98% 250g ₹2889 2022-05-26 Buy
ALFA India ALF-A11946-0B o-Phenylenediamine, 98% 1000g ₹6064 2022-05-26 Buy
ALFA India ALF-A11946-0I o-Phenylenediamine, 98% 5000g ₹44644 2022-05-26 Buy
TCI Chemicals (India) P0168 1,2-Phenylenediamine min. 98.0 % 25G ₹2000 2022-05-26 Buy
TCI Chemicals (India) P1805 1,2-Phenylenediamine [for Biochemical Research] min. 98.0 % 1G ₹2600 2022-05-26 Buy
TCI Chemicals (India) P0168 1,2-Phenylenediamine min. 98.0 % 100G ₹3300 2022-05-26 Buy
TCI Chemicals (India) P1805 1,2-Phenylenediamine [for Biochemical Research] min. 98.0 % 5G ₹6800 2022-05-26 Buy
TCI Chemicals (India) P0168 1,2-Phenylenediamine min. 98.0 % 500G ₹11400 2022-05-26 Buy
TCI Chemicals (India) P0968 1,2-Phenylenediamine min. 98.0 % 25G ₹12900 2022-05-26 Buy
Sigma-Aldrich(India) P23938 o-Phenylenediamine flaked, 99.5% 5G ₹2035.1 2022-06-14 Buy
Sigma-Aldrich(India) P23938 o-Phenylenediamine flaked, 99.5% 50G ₹2543.88 2022-06-14 Buy
Sigma-Aldrich(India) 8.14538 1,2-Phenylenediamine for synthesis 5G ₹2770 2022-06-14 Buy
Sigma-Aldrich(India) P23938 o-Phenylenediamine flaked, 99.5% 100G ₹3290.8 2022-06-14 Buy
Sigma-Aldrich(India) P23938 o-Phenylenediamine flaked, 99.5% 500G ₹4557.33 2022-06-14 Buy
Sigma-Aldrich(India) 1.07243 1,2-Phenylenediamine GR for analysis 50G ₹8730.01 2022-06-14 Buy

Properties

Melting point :100-102 °C
Boiling point :256-258 °C
Density :1,27 g/cm3
vapor density :3.7 (vs air)
vapor pressure :0.01 mm Hg ( 25 °C)
refractive index :1.6339 (estimate)
Flash point :110°C
storage temp. :2-8°C
solubility :H2O: 1 tablet/10 mL, clear, colorless
form :tablet
Colour Index :76010
pka :4.46(at 25℃)
color :white to off-white
PH Range :Green Q uorescence (3.1) to nonQ uorescence (4.4)
PH :7-8 (50g/l, H2O, 20℃)
explosive limit :1.5%(V)
Water Solubility :<0.1 g/100 mL at 20 ºC
Sensitive :Air & Light Sensitive
Merck :14,7284
BRN :606074
Exposure limits :TLV-TWA 0.1 mg/m3; carcinogenicity: A2- Suspected Human Carcinogen (ACGIH 1989).
Stability :Stable. Incompatible with strong oxidizing agents.
Major Application :bottom antireflective coatings, semiconductor devices, hair dyes, detecting antibody, substrate for horseantibody, glucose, streptomycin, penicillin, sulfonamide, neuroglobin, substrate for horseradish peroxidase
LogP :0.12-0.17 at 20-25℃ and pH7-8
CAS DataBase Reference :95-54-5(CAS DataBase Reference)
IARC :2B (Vol. 123) 2020
NIST Chemistry Reference :1,2-Benzenediamine(95-54-5)
EPA Substance Registry System :1,2-Phenylenediamine (95-54-5)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning GHS hazard pictograms P273, P391, P501
Precautionary statements:
P202 Do not handle until all safety precautions have been read and understood.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

o-phenylenediamine is used to prepare tiabendazole, pyrazinamide, morinamide, clemizole and chlormidazole. It is involved in the synthesis of benzimidazole by reacting with carboxylic acids and their derivatives. It is also used to prepare quinoxalinedione and mercaptoimidazoles by condensation with dimethyl oxalate and xanthate esters respectively. It reacts with nitrous acid to get benzotriazole, which finds application as a corrosion inhibitor. It is actively involved in the preparation of pharmaceuticals by reacting substituted o-phenylenediamine with various diketones.

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