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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >Vinylmagnesium bromide

Vinylmagnesium bromide

Vinylmagnesium bromide Structure
  • ₹5300 - ₹32745.63
  • Product name: Vinylmagnesium bromide
  • CAS: 1826-67-1
  • MF: C2H3BrMg
  • MW: 131.26
  • EINECS:217-375-3
  • MDL Number:MFCD00000042
  • Synonyms:bromoethenyl-magnesiu ;Vinylmagnesium bromide, 0.7M solution in THF, AcroSeal;Vinylmagnesium Bromide Solution 1M THF;VinylMagnesiuM broMide ,0% [1.0 M in THF];VinylMagnesiuM broMide, 0.7M solution in THF, AcroSeal 100ML;VinylMagnesiuM BroMide 1.0M Solution in Thf;VinylMagnesiuM broMide, 1M solution in 2-MeTHF, AcroSeal;Bromvinylmagnesium
8 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ottokemi

Package

  • 100G
  • 4X25ML
  • 100ML
  • 200ML
  • 4X100ML
  • 800ML
  • 1.8L
  • ManufacturerSigma-Aldrich(India)
  • Product number225584
  • Product descriptionVinylmagnesium bromide solution 1.0?M in THF
  • Packaging100ML
  • Price₹6386.75
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number225584
  • Product descriptionVinylmagnesium bromide solution 1.0?M in THF
  • Packaging4X25ML
  • Price₹7620.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number257257
  • Product descriptionVinylmagnesium bromide solution 1.0?M in THF
  • Packaging200ML
  • Price₹14613.75
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number225584
  • Product descriptionVinylmagnesium bromide solution 1.0?M in THF
  • Packaging4X100ML
  • Price₹18738.08
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number225584
  • Product descriptionVinylmagnesium bromide solution 1.0?M in THF
  • Packaging800ML
  • Price₹22353.63
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number257257
  • Product descriptionVinylmagnesium bromide solution 1.0?M in THF
  • Packaging1.8L
  • Price₹32745.63
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberV0053
  • Product descriptionVinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)
  • Packaging100G
  • Price₹5300
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number V 1288
  • Product descriptionVinylmagnesium bromide solution 1.0 M in THF
  • Packaging100mL
  • Price₹9702
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 225584 Vinylmagnesium bromide solution 1.0?M in THF 100ML ₹6386.75 2022-06-14 Buy
Sigma-Aldrich(India) 225584 Vinylmagnesium bromide solution 1.0?M in THF 4X25ML ₹7620.8 2022-06-14 Buy
Sigma-Aldrich(India) 257257 Vinylmagnesium bromide solution 1.0?M in THF 200ML ₹14613.75 2022-06-14 Buy
Sigma-Aldrich(India) 225584 Vinylmagnesium bromide solution 1.0?M in THF 4X100ML ₹18738.08 2022-06-14 Buy
Sigma-Aldrich(India) 225584 Vinylmagnesium bromide solution 1.0?M in THF 800ML ₹22353.63 2022-06-14 Buy
Sigma-Aldrich(India) 257257 Vinylmagnesium bromide solution 1.0?M in THF 1.8L ₹32745.63 2022-06-14 Buy
TCI Chemicals (India) V0053 Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L) 100G ₹5300 2022-05-26 Buy
ottokemi V 1288 Vinylmagnesium bromide solution 1.0 M in THF 100mL ₹9702 2022-05-26 Buy

Properties

Density :0.981 g/mL at 25 °C
Flash point :1 °F
storage temp. :Refrigerator
solubility :vigorous reaction
form :Solution
color :Clear light brown to brown
Water Solubility :vigorous reaction
BRN :3535841
CAS DataBase Reference :1826-67-1(CAS DataBase Reference)
EPA Substance Registry System :Magnesium, bromoethenyl- (1826-67-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232 Handle under inert gas. Protect from moisture.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.
It may also be used in the following transformations:
  • (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.
  • (R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.
  • 2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.
  • (4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.
  • Ethyl levulinate to ?-methyl-?-vinylbutyrolactone.


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