METHYL TRIPHENYLMETHYL ETHER synthesis
- Product Name:METHYL TRIPHENYLMETHYL ETHER
- CAS Number:596-31-6
- Molecular formula:C20H18O
- Molecular Weight:274.36
76-84-6
419 suppliers
$6.00/25g
74-88-4
340 suppliers
$15.00/10g
596-31-6
80 suppliers
$110.00/100mg
Yield: 71%
Reaction Conditions:
with sodium hydride in tetrahydrofuran;mineral oil at 20; for 15 h;
Steps:
3.1.9. 2-Phenyl-2-methoxypropane (6a)
General procedure: To a solution of 2-phenyl-2-propanol (1c) (1.413 g,10.4 mmol) inTHF (20 mL) was added NaH (60 wt% oil dispersion) (1.422 g,35.6 mmol) and MeI (4.755 g, 33.5 mmol) at room temperature, andthe mixture was stirred for 15 h at that temperature. To the reactionmixture was added H2O (30 mL). After being extracted with EtOAc(30 mL 3), the organic layer was dried with MgSO4. After theconcentration, the residue was subject to column chromatographyon SiO2 (hexane: EtOAc 9: 1) to give 2-phenyl-2-methoxypropane (0.850 g, 5.66 mmol, 54%) as colorless oil.
References:
Matsumoto, Shoji;Naito, Masafumi;Oseki, Takehisa;Akazome, Motohiro;Otani, Yasuhiko [Tetrahedron,2017,vol. 73,# 52,p. 7254 - 7259]
124751-00-4
46 suppliers
inquiry
596-31-6
80 suppliers
$110.00/100mg
114798-26-4
252 suppliers
$6.00/250mg
138402-10-5
118 suppliers
$8.00/100mg
596-31-6
80 suppliers
$110.00/100mg
138402-11-6
714 suppliers
$5.00/250mg
76-84-6
419 suppliers
$6.00/25g
1634-04-4
651 suppliers
$14.00/100g
596-31-6
80 suppliers
$110.00/100mg
67-56-1
739 suppliers
$7.29/5ml-f
781664-81-1
13 suppliers
$466.51/1g
137863-17-3
159 suppliers
$60.00/5g
596-31-6
80 suppliers
$110.00/100mg