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Bromocyclohexane

Bromocyclohexane Structure
CAS No.
108-85-0
Chemical Name:
Bromocyclohexane
Synonyms
CYCLOHEXYL BROMIDE;Cyclohexylbromid;Bromocylohexane;BROMOCYCLOHEXANE;bromo-cyclohexan;BroMocyclohexance;Cyclohexane,bromo-;1-Bromocyclohexane;Cyelohexyl bromide;Bromocyclohexane>
CBNumber:
CB0234782
Molecular Formula:
C6H11Br
Molecular Weight:
163.06
MOL File:
108-85-0.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02

Bromocyclohexane Properties

Melting point -57°C
Boiling point 166-167 °C (lit.)
Density 1.324 g/mL at 25 °C (lit.)
vapor density 5.62 (vs air)
refractive index n20/D 1.495(lit.)
Flash point 145 °F
storage temp. Sealed in dry,Room Temperature
solubility Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
form Liquid
color Clear colorless to light yellow
Specific Gravity approximate 1.33 (20℃)
Odor Unpleasant Odor
Water Solubility insoluble
Sensitive Air & Light Sensitive
Merck 14,2730
BRN 1098373
Dielectric constant 7.9(25℃)
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChIKey AQNQQHJNRPDOQV-UHFFFAOYSA-N
CAS DataBase Reference 108-85-0(CAS DataBase Reference)
NIST Chemistry Reference Cyclohexane, bromo-(108-85-0)
EPA Substance Registry System Cyclohexane, bromo- (108-85-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335-H227
Precautionary statements  P210-P280-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a
Hazard Codes  Xn
Risk Statements  36/37/38-20-18-52
Safety Statements  23-24/25-37/39-26
WGK Germany  3
RTECS  GU7171700
8
TSCA  Yes
HS Code  29035990
NFPA 704
2
1 0

Bromocyclohexane price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 135194 Bromocyclohexane 98% 108-85-0 5G ₹1403.15 2022-06-14 Buy
Sigma-Aldrich(India) 135194 Bromocyclohexane 98% 108-85-0 100G ₹1993.95 2022-06-14 Buy
Sigma-Aldrich(India) 135194 Bromocyclohexane 98% 108-85-0 500G ₹6635.95 2022-06-14 Buy
Sigma-Aldrich(India) 135194 Bromocyclohexane 98% 108-85-0 1KG ₹10666.05 2022-06-14 Buy
TCI Chemicals (India) B0581 Bromocyclohexane min. 98.0 % 108-85-0 25G ₹1500 2022-05-26 Buy
Product number Packaging Price Buy
135194 5G ₹1403.15 Buy
135194 100G ₹1993.95 Buy
135194 500G ₹6635.95 Buy
135194 1KG ₹10666.05 Buy
B0581 25G ₹1500 Buy

Bromocyclohexane Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.

Preparation

Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.

General Description

Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

Purification Methods

Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]

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