1-Naphthol-3,6-disulfonic acid

1-Naphthol-3,6-disulfonic acid Structure
CAS No.
578-85-8
Chemical Name:
1-Naphthol-3,6-disulfonic acid
Synonyms
1-Naphthol-3,6-disul;1-Naphthol-3,6-disulfonic;1-Naphthol-3,6-disulfonic acid;Sodium1-naphthol-3,6-disulfonate;1-NAPHTHOL-3,6-DISULFONIC ACID 98%;1-Hydroxy-3,6-naphthalenedisulfonic acid;1-Hydroxynaphthalene-3,6-disulfonic acid;4-hydroxynaphthalene-2,7-disulfonic acid;4-Hydroxy-2,7-Naphthalenedisulfonic Acid;4-hydroxynaphthalene-2,7-disulphonic acid
CBNumber:
CB0512345
Molecular Formula:
C10H8O7S2
Molecular Weight:
304.3
MOL File:
578-85-8.mol
Modify Date:
2023/11/1 14:37:45

1-Naphthol-3,6-disulfonic acid Properties

Density 1.816±0.06 g/cm3(Predicted)
pka -0.14±0.40(Predicted)
CAS DataBase Reference 578-85-8(CAS DataBase Reference)
EPA Substance Registry System 2,7-Naphthalenedisulfonic acid, 4-hydroxy- (578-85-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501

1-Naphthol-3,6-disulfonic acid Chemical Properties,Uses,Production

Chemical Properties

Off-white paste. 1-Hydroxynaphthalene-3,6-disulfonic acid [578-85-8]. (4-hydroxynaphthalene-2,7- disulfonic acid), RG acid, Violet acid, C10H8O7S2, Mr 304.3: the free acid ( pKa 8.56) and its alkalimetal salts are readily soluble in water, but the acid sodium salt can be precipitated from concentrated solution with salt. Sulfonation with oleum at 125℃ gives a tetrasulfonic acid, and amination with ammonia and ammonium chloride at 160℃ gives a mixture of 3-amino1-hydroxynaphthalene-6-sulfonic acid and 6- amino-1-hydroxynaphthalene-3-sulfonic acid. Alkali fusion at 170℃ gives mainly 1,6-dihydroxynaphthalene-3-sulfonic acid, and at 250℃ yields 1,3,6-trihydroxynaphthalene. Diazo coupling takes place in the 2-position.

Production Methods

Naphthalene-1,3,6-trisulfonic acid is heated with 50 % sodium hydroxide at 180 C for 15 h in an autoclave. After dilution with water, the product is salted out as the monosodium salt and purified by washing with brine.

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1-NAPHTHOL-3,6-DISULFONIC ACID 98% 1-Naphthol-3,6-disulfonic acid 1-Hydroxy-3,6-naphthalenedisulfonic acid 1-Hydroxynaphthalene-3,6-bissulfonic acid 1-Hydroxynaphthalene-3,6-disulfonic acid 1-Naphthol-3,6-disul 4-Hydroxy-2,7-Naphthalenedisulfonic Acid 4-hydroxynaphthalene-2,7-disulfonic acid 1-NAPHTHOL-3,6-DISULFONIC ACID ≡96%(HPLC) 4-hydroxynaphthalene-2,7-disulphonic acid 1-Naphthol-3,6-disulfonic Sodium1-naphthol-3,6-disulfonate 2,7-Naphthalenedisulfonic acid, 4-hydroxy- 578-85-8 C10H5OHSO3H2 Intermediates of Dyes and Pigments Organic acids