1-Naphthol-3,6-disulfonic acid

- CAS No.
- 578-85-8
- Chemical Name:
- 1-Naphthol-3,6-disulfonic acid
- Synonyms
- 1-Naphthol-3,6-disul;1-Naphthol-3,6-disulfonic;1-Naphthol-3,6-disulfonic acid;Sodium1-naphthol-3,6-disulfonate;1-NAPHTHOL-3,6-DISULFONIC ACID 98%;1-Hydroxy-3,6-naphthalenedisulfonic acid;1-Hydroxynaphthalene-3,6-disulfonic acid;4-hydroxynaphthalene-2,7-disulfonic acid;4-Hydroxy-2,7-Naphthalenedisulfonic Acid;4-hydroxynaphthalene-2,7-disulphonic acid
- CBNumber:
- CB0512345
- Molecular Formula:
- C10H8O7S2
- Molecular Weight:
- 304.3
- MOL File:
- 578-85-8.mol
- Modify Date:
- 2024/12/18 13:37:16
Density | 1.816±0.06 g/cm3(Predicted) |
---|---|
pka | -0.14±0.40(Predicted) |
CAS DataBase Reference | 578-85-8(CAS DataBase Reference) |
EPA Substance Registry System | 2,7-Naphthalenedisulfonic acid, 4-hydroxy- (578-85-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS05 |
---|---|
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501 |
1-Naphthol-3,6-disulfonic acid Chemical Properties,Uses,Production
Chemical Properties
Off-white paste. 1-Hydroxynaphthalene-3,6-disulfonic acid [578-85-8]. (4-hydroxynaphthalene-2,7- disulfonic acid), RG acid, Violet acid, C10H8O7S2, Mr 304.3: the free acid ( pKa 8.56) and its alkalimetal salts are readily soluble in water, but the acid sodium salt can be precipitated from concentrated solution with salt. Sulfonation with oleum at 125℃ gives a tetrasulfonic acid, and amination with ammonia and ammonium chloride at 160℃ gives a mixture of 3-amino1-hydroxynaphthalene-6-sulfonic acid and 6- amino-1-hydroxynaphthalene-3-sulfonic acid. Alkali fusion at 170℃ gives mainly 1,6-dihydroxynaphthalene-3-sulfonic acid, and at 250℃ yields 1,3,6-trihydroxynaphthalene. Diazo coupling takes place in the 2-position.
Production Methods
Naphthalene-1,3,6-trisulfonic acid is heated with 50 % sodium hydroxide at 180 C for 15 h in an autoclave. After dilution with water, the product is salted out as the monosodium salt and purified by washing with brine.
1-Naphthol-3,6-disulfonic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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