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ETHYL 2-(BROMOMETHYL)ACRYLATE

ETHYL 2-(BROMOMETHYL)ACRYLATE Structure
CAS No.
17435-72-2
Chemical Name:
ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonyms
Ethyl Bromomethacrylate;3-bromo-2-methyl-2-propenoic acid ethyl ester;DK588;NSC 215252;2-Carbethoxyallyl Bromide;Ethyl2-(Bromomethyl)acrvlate;ETHYL 2-(BROMOMETHYL)ACRYLATE;Ethyl 2-(bromomethyl)propenoate;Ethyl 2-(bromomethyl)acrylate,97%;Ethyl 2-(bromomethyl)prop-2-enoate
CBNumber:
CB0741901
Molecular Formula:
C6H9BrO2
Molecular Weight:
193.04
MOL File:
17435-72-2.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

ETHYL 2-(BROMOMETHYL)ACRYLATE Properties

Melting point 134-136℃
Boiling point 38 °C/0.8 mmHg (lit.)
Density 1.398 g/mL at 25 °C (lit.)
refractive index n20/D 1.479(lit.)
Flash point 178 °F
storage temp. -20°C
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
form Liquid
color Colorless to pale yellow
BRN 970108
InChIKey MTCMFVTVXAOHNQ-UHFFFAOYSA-N
CAS DataBase Reference 17435-72-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  UN 2810 6.1 / PGII
WGK Germany  3
10-19-23
HS Code  29161900
NFPA 704
2
3 2

ETHYL 2-(BROMOMETHYL)ACRYLATE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 425222 Ethyl 2-(bromomethyl)acrylate 98% 17435-72-2 1G ₹5050 2022-06-14 Buy
Sigma-Aldrich(India) 425222 Ethyl 2-(bromomethyl)acrylate 98% 17435-72-2 5G ₹12620 2022-06-14 Buy
ALFA India ALF-H65384-MD Ethyl 2-(bromomethyl)acrylate, 97% 17435-72-2 250mg ₹1679 2022-05-26 Buy
ALFA India ALF-H65384-06 Ethyl 2-(bromomethyl)acrylate, 97% 17435-72-2 5g ₹29500 2022-05-26 Buy
TCI Chemicals (India) B1820 Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ) min. 97.0 % 17435-72-2 1G ₹5300 2022-05-26 Buy
Product number Packaging Price Buy
425222 1G ₹5050 Buy
425222 5G ₹12620 Buy
ALF-H65384-MD 250mg ₹1679 Buy
ALF-H65384-06 5g ₹29500 Buy
B1820 1G ₹5300 Buy

ETHYL 2-(BROMOMETHYL)ACRYLATE Chemical Properties,Uses,Production

Chemical Properties

Colourless Oil

Uses

ETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.

General Description

Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.

Purification Methods

If it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]

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ETHYL 2-(BROMOMETHYL)ACRYLATE Spectrum

2-Propenoic acid, 2-(bromomethyl)-, ethyl ester 2-(Bromomethyl)-2-propenoic Acid Ethyl Ester 2-Carbethoxyallyl Bromide Ethyl 2-(Bromomethyl)-2-propenoate Ethyl 3-Bromo-2-(methylene)propanoate NSC 215252 Ethyl 2-(bromomethyl)acrylate,97% Ethyl 2-(bromomethyl)acrylate ,98% Ethyl 2-(bromomethyl)prop-2-enoate Ethyl 2-(broMoMethyl)acrylate, 97% 5GR 2-(BROMOMETHYL)ACRYLIC ACID ETHYL ESTER ETHYL 2-(BROMOMETHYL)ACRYLATE Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ) Ethyl 2-(bromomethyl)propenoate Ethyl 3-bromo-2-methylenepropionate Ethyl2-(Bromomethyl)acrvlate Ethyl 2-(bromomethyl)acrylate, 97%, for synthesis Ethyl 2-(Bromomethyl)acrylate (stabilized with HQ)> Ethyl Bromomethacrylate 3-bromo-2-methyl-2-propenoic acid ethyl ester DK588 17435-72-2 CH2CCH2BrCO2CH2CH3 ESTER C6 to C7 Carbonyl Compounds Building Blocks Organic Building Blocks Esters Benzothiophenes ,Thiophenes Aliphatics AcrylateCarbonyl Compounds Acrylic Monomers C6 to C7 Esters Monomers All Aliphatics