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Picramic acid

Picramic acid  Structure
CAS No.
96-91-3
Chemical Name:
Picramic acid
Synonyms
zoba4r;furro4r;Zoba 4R;picramic;Furro 4R;Ursol 4R;C.I.76540;fourrine93;fourrine4r;Fourrine 4R
CBNumber:
CB1361317
Molecular Formula:
C6H5N3O5
Molecular Weight:
199.12
MOL File:
96-91-3.mol
MSDS File:
SDS
Modify Date:
2023/5/15 10:44:00

Picramic acid Properties

Melting point 169°C
Boiling point 336.62°C (rough estimate)
Density 1.6937 (rough estimate)
vapor pressure 0-0Pa at 25℃
refractive index 1.6910 (estimate)
solubility Chloroform (Slightly), Water (Slightly)
form Solid
color Red to Dark Red
Water Solubility <0.1 g/100 mL at 20.5 ºC
Merck 14,7409
Stability Stable. Combustible - burns rapidly: dangerous fire risk. Do not subject to shock, friction or heat. Incompatible with strong oxidizing agents.
LogP 0.93 at 25℃
CAS DataBase Reference 96-91-3(CAS DataBase Reference)
NIST Chemistry Reference Picramic acid(96-91-3)
EPA Substance Registry System Picramic acid (96-91-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H312-H332-H412
Precautionary statements  P264-P270-P301+P312-P330-P501-P280-P302+P352-P312-P322-P363-P501-P261-P271-P304+P340-P312-P273-P501
Hazard Codes  E,Xn,F
Risk Statements  1-20/21/22-52/53-11
Safety Statements  35-61-36/37
RIDADR  3317
RTECS  SJ5800000
HazardClass  4.1
PackingGroup  II

Picramic acid Chemical Properties,Uses,Production

Chemical Properties

dark red crystals

Uses

manufacture of azo dyes; rarely as indicator (yellow with acids, red with alkalies); reagent for albumin.

General Description

Dark red needles or prisms. Red crystals. Water insoluble. Explosive in the dry state but desensitized by wetting. Easily ignited and once ignited burn readily.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Picramic acid should not be subjected to strong shock or heat, and is a dangerous fire risk. Picramic acid reacts with strong oxidizing agents. . Explodes if dried and exposed to heat, flame, friction or shock. Wetting greatly reduces this tendency. Treat as an explosive. Mixing with reducing agents, including hydrides, sulfides, nitrides, and alkali metals may lead to a vigorous reaction that culminates in a detonation. May explode in the presence of a base such as sodium hydroxide or potassium hydroxide, even in the presence of water or organic solvents. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. An amino acid (reacts as an acid with bases and as a base with acids).

Fire Hazard

Picramic acid ignites rapidly and burns relatively fast.

Global( 91)Suppliers
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Krishna Industries +91-7922822554 +91-7922822554 Gujarat, India 235 58 Inquiry
Odyssey Organics Pvt Ltd +91-9766615107 +91-9766615115 Maharashtra, India 1 58 Inquiry
Amogh Chemicals Pvt Ltd +91-9920471328 +91-9833649289 Maharashtra, India 170 58 Inquiry
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Amarjyot Chemical Corporation 91-22-24134374 Maharashtra, India 3 58 Inquiry
Odyssey Organics Private Limited +91 251 2691342 Maharashtra, India 3 58 Inquiry
fourrine93 Furro 4R furro4r Oxidation Base 21 Phenol, 2-amino-4,6-dinitro- picramic Zoba 4R zoba4r Picramic Acid (wetted with ca. 25% Water, containing 25g on a dry weight basis) 2-Amino-4,6-dinitrophenol, wetted with not less than 20% water C.I.76540 Ursol 4R (wetted with ca. 25% Water, containing 25g on a dry weight basis) PicraMic Acid  Picramic Acid (wetted with ca. 25% Water) (unit weight on dry weight basis) LABOTEST-BB LT02098684 2-hydroxy-3,5-dinitroaniline 2-AMINO-4,6-DINITROPHENOL 2,4-dinitro-6-aminophenol 4,6-DINITRO-2-AMINO PHENOL AKOS BB-9292 6-AMINO-2,4-DINITROPHENOL 1-amino-2-hydroxy-3,5-dinitrobenzene 2-amino-4,6-dinitro-pheno Acide picramique acidepicramique acidepicramique(french) C.I. Oxidation Base 21 c.i.oxidationbase21 cioxidationbase21 Fourrine 4R Fourrine 93 fourrine4r PICRAMIC ACID 2-Amino-4,6-dinitrophenol (wet with ~20% of water) Picramic acid USP/EP/BP 96-91-3 C6H5N3O5 HOC6H2NH2NO22 Intermediates of Dyes and Pigments