Tungsten trioxide
![Tungsten trioxide Structure](CAS/GIF/1314-35-8.gif)
- CAS No.
- 1314-35-8
- Chemical Name:
- Tungsten trioxide
- Synonyms
- WO3;TUNGSTEN OXIDE;Tung;Tungsten blue;CI 77901;Mo 100ppm;Wolframite;tungstenblue;Wolframtrioxid;TUNGSTIC OXIDE
- CBNumber:
- CB1718034
- Molecular Formula:
- O3W
- Molecular Weight:
- 231.84
- MOL File:
- 1314-35-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/12 17:58:41
Melting point | 1470-1475 °C |
---|---|
Boiling point | 1837°C (estimate) |
Density | 7.16 g/mL at 25 °C(lit.) |
storage temp. | Room Temperature |
solubility | insoluble in H2O, organic solvents; slightly soluble in acid solutions; soluble in alkaline solutions |
form | powder |
Specific Gravity | 7.16 |
color | Yellow to greenish-yellow |
Water Solubility | insoluble |
Merck | 14,9817 |
Exposure limits |
ACGIH: TWA 3 mg/m3 NIOSH: TWA 5 mg/m3; STEL 10 mg/m3 |
InChIKey | ZNOKGRXACCSDPY-UHFFFAOYSA-N |
CAS DataBase Reference | 1314-35-8(CAS DataBase Reference) |
NIST Chemistry Reference | Tungsten trioxide(1314-35-8) |
EPA Substance Registry System | Tungsten trioxide (1314-35-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302 | |||||||||
Precautionary statements | P264-P270-P301+P312a-P330-P501a | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 22-36/37/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
WGK Germany | - | |||||||||
RTECS | YO7760000 | |||||||||
F | 21 | |||||||||
TSCA | Yes | |||||||||
HS Code | 28259012 | |||||||||
Toxicity | rat,LD50,oral,1059mg/kg (1059mg/kg),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)BEHAVIORAL: EXCITEMENTBEHAVIORAL: MUSCLE WEAKNESS,Hygiene and Sanitation Vol. 31(7-9), Pg. 197, 1966. | |||||||||
NFPA 704 |
|
Tungsten trioxide price More Price(38)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 95410 | Tungsten(VI) oxide powder, puriss., 99.9% | 1314-35-8 | 100G | ₹10792.53 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 95410 | Tungsten(VI) oxide powder, puriss., 99.9% | 1314-35-8 | 500G | ₹28025.93 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 774537 | Tungsten(VI) oxide nanowires, diam. × L ~50?nm × 10?μm | 1314-35-8 | 500MG | ₹19766.45 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 550086 | Tungsten(VI) oxide nanopowder, <100?nm particle size (TEM) | 1314-35-8 | 5G | ₹6062 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 232785 | Tungsten(VI) oxide powder, ≤25?μm, ≥99% trace metals basis | 1314-35-8 | 100G | ₹5813.03 | 2022-06-14 | Buy |
Tungsten trioxide Chemical Properties,Uses,Production
Chemical Properties
Canary-yellow, heavy powder, darkorange when heated and regains original color on cooling. Insoluble in water, soluble in caustic alkalies, soluble with difficulty in acids. Noncombustible.
Physical properties
Heavy yellow powder; turns dark orange on heating; reverts back to yellow on cooling; density 7.2 g/cm3; melts at 1,472°C; insoluble in water; slightly soluble in acids; soluble in caustic alkalies.
Uses
manufacture of tungstates which are used for x-ray screens and for fireproofing fabrics.
Preparation
Tungsten trioxide is obtained as an intermediate in recovery of tungsten from its minerals (See Tungsten). In commerical processes tungstic acid, H2WO4, obtained from the mineral scheelite, may either be decomposed at high temperatures to form trioxide or dissolved in ammonium hydroxide solution and evaporated to yield ammonium paratungstate (APT) crystals, 5 (NH4)2O?12WO3?11H2O. The APT crystals are then washed, dried, and calcined at elevated temperatures to form tungsten trioxide
Tungsten trioxide, in general, can be made by heating metallic tungsten, its carbides, its lower oxides, or tungstic acid in air.
General Description
Tungsten(VI) oxide (WO3) is a semiconducting material with excellent electrochromic properties. It is a cost efficient material with a high optical modulation. It can be synthesized by a variety of methods which include chemical vapor deposition, electrodeposition, and other sol-gel based coating processes.
Hazard
Toxic material.
Safety Profile
Moderately toxic by ingestion. Can react violently with ClF3, Li, Cl2. See also TUNGSTEN COMPOUNDS.
Structure and conformation
The crystal structure of tungsten trioxide is temperature dependent. It is tetragonal at temperatures above 740℃, orthorhombic from 330 to 740 °C, monoclinic from 17 to 330 °C, triclinic from -50 to 17 °C, and monoclinic again at temperatures below -50 °C.The most common structure of WO3 is monoclinic with space group P21/n.
Tungsten trioxide Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
Evans Fine Chem | +91-9821340302 +91-9821340302 | Maharashtra, India | 286 | 58 | Inquiry |
Sajan Overseas Pvt Ltd | +91-9825074205 +91-9825074205 | Gujarat, India | 38 | 58 | Inquiry |
Dhara Industries | +91-9322395199 +91-9322395199 | Mumbai, India | 190 | 58 | Inquiry |
CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4317 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
Aritech Chemazone Private Limited | +91-9034345475 | Punjab, India | 684 | 58 | Inquiry |
Supplier | Advantage |
---|---|
GLR Innovations | 58 |
Evans Fine Chem | 58 |
Sajan Overseas Pvt Ltd | 58 |
Dhara Industries | 58 |
CHEMSWORTH | 30 |
Otto Chemie Pvt. Ltd. | 58 |
Sisco Research Laboratories Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
Triveni chemicals | 58 |
Aritech Chemazone Private Limited | 58 |
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