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Calcium tungstate

Calcium tungstate Structure
CAS No.
7790-75-2
Chemical Name:
Calcium tungstate
Synonyms
CALC;EFHA3;CBARA1;ara CALC;DKFZp564C246;Allergen=Hom s 4;CALCIUM TUNGSTATE;calcium wolframate;Calciumtungstenoxi;CALCIUM BIPHOSPHATE
CBNumber:
CB6135863
Molecular Formula:
CaO4W
Molecular Weight:
287.92
MOL File:
7790-75-2.mol
Modify Date:
2024/5/31 14:07:17

Calcium tungstate Properties

Melting point 1620°C
Density 6.06 g/mL at 25 °C (lit.)
storage temp. -20°C
solubility Insoluble in H{2}O. Decomposes by hot HCl, HNO{3}
form Powder
Specific Gravity 6.062
color white
Water Solubility insoluble H2O; decomposed by hot HCl, HNO3 [MER06]
Merck 14,1712
Solubility Product Constant (Ksp) pKsp: 8.06
Exposure limits ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 7790-75-2(CAS DataBase Reference)
EPA Substance Registry System Calcium tungsten oxide (CaWO4) (7790-75-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P271
WGK Germany  3
TSCA  Yes
HS Code  28418030
NFPA 704
0
0 0

Calcium tungstate price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 248665 Calcium tungstate powder 7790-75-2 100G ₹14408.08 2022-06-14 Buy
Sigma-Aldrich(India) SAB1304787 ANTI-CBAA1 (N-TERM) antibody produced in rabbit IgG fraction of antiserum, buffered aqueous solution 7790-75-2 400μL ₹47796.6 2022-06-14 Buy
Sigma-Aldrich(India) 248665 Calcium tungstate powder 7790-75-2 500G ₹28448.1 2022-06-14 Buy
ALFA India ALF-035669-30 Calcium tungsten oxide, 99.78% (metals basis) 7790-75-2 250g ₹38358 2022-05-26 Buy
ALFA India ALF-035669-18 Calcium tungsten oxide, 99.78% (metals basis) 7790-75-2 50g ₹7677 2022-05-26 Buy
Product number Packaging Price Buy
248665 100G ₹14408.08 Buy
SAB1304787 400μL ₹47796.6 Buy
248665 500G ₹28448.1 Buy
ALF-035669-30 250g ₹38358 Buy
ALF-035669-18 50g ₹7677 Buy

Calcium tungstate Chemical Properties,Uses,Production

Chemical Properties

-325 mesh, 10μm or less 99.9% pure; occurs in nature as mineral scheelite; white tetr powder(s), a=0.524 nm, c=1.138 nm; can be prepared by heating tungstic acid and CaO or CaCO3; used in tumor treatment and in luminous paint [KIR83] [STR93] [MER06]
Calcium tungstate
Large orange octahedral scheelite, Ca(WO4), crystal to 4.5 cm on muscovite, KAl2(AlSi3O10)(OH)2. Pingwu Co., Mianyang pref., Sichuan prov., China.

Uses

Calcium tungstate can be ued for preparing screens for x-ray observations and photographs; in luminous paints; in scintillation counters.

Application

Calcium tungstate is well known as the phosphor that emits light in λ: 310–700 nm under the excitation light in λ: 220–300 nm. The peak wavelength is positioned at 440 nm, causing it to give off a blue color.

Production Methods

A single crystal is grown from melt by the Czochralski method. Rare earth ions are easy to incorporate into the crystal during growth. Fluorescent films are deposited on a glass substrate through vacuum evaporation using a W filament heated at 2000℃ for about 3 min, followed by thermal annealing in oxygen at 550℃ for 2 h. The film becomes crystalline through this thermal annealing.

General Description

Calcium tungstate (CaWO4) is an optical material, which can be used as a laser host material for a variety of electronic applications. It has a scheelite structure with luminescence, and thermo-luminescence properties.

Structure and conformation

The space lattice of CaWO4 belongs to the tetragonal system, and its Scheelite structure has lattice constants of a=0.524 nm and c=1.138 nm. The space group is I41/a, and there are four formula units per unit cell.

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