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Calcium Propionate

Calcium Propionate Structure
CAS No.
4075-81-4
Chemical Name:
Calcium Propionate
Synonyms
propionic acid calcium;Calcium dipropionate;CALCIUM PROPIONATE FOOD GRADE;bioban-c;CAPROSIL SALZ;MAGGRAN(R) CPR;MAGNESIA 87264;CAPROSIL SALT G;calciumpropanoate;CalClum propionate
CBNumber:
CB6194031
Molecular Formula:
C3H8CaO2
Molecular Weight:
116.17
MOL File:
4075-81-4.mol
MSDS File:
SDS
Modify Date:
2024/7/14 20:44:35

Calcium Propionate Properties

Melting point 300 °C
Density 1.41[at 20℃]
vapor pressure 0-399Pa at 20-23℃
storage temp. Store below +30°C.
solubility water: soluble1g/10 mL, clear, colorless
form Crystals or Crystalline Powder
color White
PH 9.2 (200g/l, H2O, 20℃)(IUCLID)
Odor at 100.00?%. bland mild propionic acid
Water Solubility 1 g/10 mL
Merck 14,1698
BRN 3698682
Stability Stable. Hygroscopic. Incompatible with strong oxidizing agents.
InChIKey BCZXFFBUYPCTSJ-UHFFFAOYSA-L
LogP 0.33 at 25℃
CAS DataBase Reference 4075-81-4(CAS DataBase Reference)
EPA Substance Registry System Calcium propionate (4075-81-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H318-H335
Precautionary statements  P261-P271-P280-P304+P340+P312-P305+P351+P338-P403+P233
Risk Statements  36/37/38
Safety Statements  24/25
WGK Germany  2
RTECS  UE8450000
TSCA  Yes
HS Code  29155000
NFPA 704
1
0 1

Calcium Propionate price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 21230 Calcium propionate ≥97.0% (dry substance, NT) 4075-81-4 250G ₹2619.65 2022-06-14 Buy
Sigma-Aldrich(India) 21230 Calcium propionate ≥97.0% (dry substance, NT) 4075-81-4 1KG ₹6105.3 2022-06-14 Buy
Sigma-Aldrich(India) 18104 Calcium propionate 99.0-100.5% (in dried substance), meets analytical specification of E 282 4075-81-4 1KG ₹5693.95 2022-06-14 Buy
TCI Chemicals (India) P0503 Calcium Propionate 4075-81-4 25G ₹1500 2022-05-26 Buy
TCI Chemicals (India) P0503 Calcium Propionate 4075-81-4 500G ₹2000 2022-05-26 Buy
Product number Packaging Price Buy
21230 250G ₹2619.65 Buy
21230 1KG ₹6105.3 Buy
18104 1KG ₹5693.95 Buy
P0503 25G ₹1500 Buy
P0503 500G ₹2000 Buy

Calcium Propionate Chemical Properties,Uses,Production

Description

Calcium propanoate or calcium propionate has the formula Ca(C2H5COO)2. It is the calcium salt of propanoic acid. It is a preservative commonly used in baked goods around the world, where it extends their shelf life by inhibiting the growth of spoilage microorganisms, namely mold and ropy bacteria.

Chemical Properties

Calcium propionate is a white powder(s) or monoclinic crystal(s), crystallizes as the monohydrate in monoclinic plates and as the trihydrate. The anhydrous salt dissolves up to 41.7 wt % in water and is insoluble in ethanol. The aqueous solutions can cause inflammation. It is used to mold-retardant additive for bread, tobacco, pharmaceuticals, antifungal agent.[HAW93]

Uses

Calcium Propionate is the salt of propionic acid which functions as a preservative. It is the most widely used antimycotic in breadmaking. it is effective against mold, has limited activity against bacteria, and no activity against yeast. it is soluble in water with a solubility of 49 g/100 ml of water at 0°c and insoluble in alcohol. it is less soluble than sodium propionate. its optimum effectiveness is up to ph 5.0 and it has reduced action above ph 6.0. It is often utilized at about 0.2%, flour basis; higher concentrations lead to flavor problems and begin to inhibit yeast fermentation. it is used in bakery products, breads, and pizza crust to protect against mold and “rope.” it is also used in cold-pack cheese food and pie fillings. typical usage level is 0.2–0.3% and 0.1–0.4% based on flour weight.

Application

As a food additive, it is listed as E number 282 in the Codex Alimentarius. Calcium propanoate is used as a preservative in a wide variety of products, including but not limited to bread, other baked goods, processed meat, whey, and other dairy products. In agriculture, it is used, amongst other things, to prevent milk fever in cows and as a feed supplement Propanoates prevent microbes from producing the energy they need, like benzoates do. However, unlike benzoates, propanoates do not require an acidic environment.
Calcium propanoate is used in bakery products as a mold inhibitor, typically at 0.1- 0.4 % (though animal feed may contain up to 1 % ) .
When propanoic acid is infused directly into rodents' brains, it produces reversible behavior changes (e.g. hyperactivity, dystonia, social impairment, perseveration ) and brain changes (e.g. innate neuroinflammation, glutathione depletion) that may be used as a model of human autism in rats.
According to the Pesticide Action Network North America, calcium propionate is slightly toxic . This rating is not uncommon for food products; vitamin C is also rated by the same standards as being slightly toxic . Calcium propanoate can be used as a fungicide on fruit.

Preparation

The industrial production of Calcium propionate and sodium propionate is carried out by the neutralization of propionic acid with the corresponding hydroxides and subsequent spraydrying of the concentrated aqueous solutions.

General Description

Calcium propionate is generally used as a food preservative in bread. It has also been reported to reduce milk fever in dairy cows. Calcium propionate is the most effective below pH 5.5. Below this pH, the active component, propionic acid, is undissociated and becomes active. The dough pH needs to be below 5.5 and well controlled to effectively control mold.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes.

Safety

Calcium propionate is affirmed as GRAS for use as an antimicrobial under 21 C.F.R.184.122 1 with no limitation on the level of use other than current good manufacturing practice (gmp). There is no obvious self-limit on the level of use. In commercial practice the amount of calcium propionate used will be limited by cost and the possibility of imparting off-tastes or textures to food when gmp concentrations are exceeded.
Though Calcium Propionate E282 is regarded as safe supplement, there maybe some side effects: damage your stomach lining by exacerbating gastritis and inducing severe ulcers and cause irritability, restlessness, inattention and sleep disturbance.

Purification Methods

Crystallise this antifungal salt from water (2mL/g) by partial evaporation in a desiccator. [Beilstein 2 H 238, 2 II 218, 2 III 516.]

Calcium Propionate Preparation Products And Raw materials

Global( 727)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Rishi Chemical Works Pvt Ltd +91-3322290068 +91-3322290071 Kolkata, India 43 58 Inquiry
Eskay Iodine Pvt Ltd +91-22-6622 7575 Mumbai, India 28 58 Inquiry
PERFECT CHEMICAL +91-9820465461 +91-9820465461 Mumbai, India 391 58 Inquiry
CRYSTAL PHARMA +91-9322218073 +91-9820141331 Mumbai, India 106 58 Inquiry
SAANVI CORP +91-7208939370 +91-7208939370 Maharashtra, India 46 58 Inquiry
HRV Global Life Sciences +91-9820219686 +91-9820219686 Telangana, India 379 58 Inquiry
ShanPar Industries Pvt Ltd +91-2652638973 +91-9909901206 Gujarat, India 115 58 Inquiry
Agilenobel +91-8090295395 +91-8800293647 Haryana, India 50 58 Inquiry
West Bengal Chemical Industries Ltd. +91-3340251500 +91-9088750141 Kolkata, India 51 58 Inquiry
Jiaan Biotech +91-8349999795 +91-9039039794 Madhya Pradesh, India 13 58 Inquiry

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