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Dicyandiamide

Dicyandiamide Structure
CAS No.
461-58-5
Chemical Name:
Dicyandiamide
Synonyms
CYANOGUANIDINE;DICYANODIAMIDE;DCD;N-Cyanoguanidine;1-CYANOGUANIDINE;2-Cyanoguanidine;Metformin impurity A;DICY;Dermcidin;Guanidine-1-carbonitrile
CBNumber:
CB1779741
Molecular Formula:
C2H4N4
Molecular Weight:
84.08
MOL File:
461-58-5.mol
MSDS File:
SDS
Modify Date:
2024/6/28 14:37:56

Dicyandiamide Properties

Melting point 208-211 °C (lit.)
Boiling point 144.35°C (rough estimate)
Density 1.40
vapor pressure 0.001Pa at 20℃
refractive index 1.6260 (estimate)
storage temp. 2-8°C
solubility H2O: 0.1 g/mL, clear
pka 0.73±0.70(Predicted)
form Crystalline Powder
color White
Water Solubility 32 g/L (20 ºC)
Merck 14,3092
BRN 605637
Stability Stable. Incompatible with strong acids, strong oxidizing agents, strong bases.
InChIKey QGBSISYHAICWAH-UHFFFAOYSA-N
LogP -1 at 20℃
CAS DataBase Reference 461-58-5(CAS DataBase Reference)
NIST Chemistry Reference Dicyandiamide(461-58-5)
EPA Substance Registry System Dicyanodiamide (461-58-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS09
Hazard statements  H411
Precautionary statements  P273-P391-P501
Hazard Codes  Xn,T
Risk Statements  20/21/22-43-36/38-25
Safety Statements  22-24/25-45-36-3
RIDADR  UN 2811 6.1 / PGIII
WGK Germany  1
RTECS  ME9950000
TSCA  Yes
HS Code  29262000
Toxicity LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
NFPA 704
1
1 0

Dicyandiamide price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) D76609 Dicyandiamide 99% 461-58-5 25G ₹2490 2022-06-14 Buy
Sigma-Aldrich(India) SAB1306514 ANTI-DCD(C-TERMINAL) antibody produced in rabbit purified immunoglobulin, buffered aqueous solution 461-58-5 400μL ₹47796.6 2022-06-14 Buy
Sigma-Aldrich(India) PHR1331 Metformin Related Compound A Pharmaceutical Secondary Standard; Certified Reference Material 461-58-5 500MG ₹8421.85 2022-06-14 Buy
Sigma-Aldrich(India) D76609 Dicyandiamide 99% 461-58-5 1KG ₹3330 2022-06-14 Buy
Sigma-Aldrich(India) D76609 Dicyandiamide 99% 461-58-5 3KG ₹6386.75 2022-06-14 Buy
Product number Packaging Price Buy
D76609 25G ₹2490 Buy
SAB1306514 400μL ₹47796.6 Buy
PHR1331 500MG ₹8421.85 Buy
D76609 1KG ₹3330 Buy
D76609 3KG ₹6386.75 Buy

Dicyandiamide Chemical Properties,Uses,Production

Chemical Properties

white powder

Uses

Dicyandiamide is a guanidine derivative used in the synthesis of barbiturates,it is also used in the plastics industry (manufacture of melamine).

Application

Dicyanodiammonia, abbreviated as dicy or DCD. It is an organic substance with the chemical formula of c2h4n4. It is a dimer of cyanamide and a cyano derivative of guanidine. Chemical formula c2h4n4. White crystalline powder. Soluble in water, alcohol, ethylene glycol and dimethylformamide, almost insoluble in ether and benzene. Stable when dry. It is a guanidine in which one of the amino hydrogens of guanidine itself is substituted by a cyano group. It is used in the manufacture of fertilizers, pharmaceuticals, explosives, oil well drilling muds, and dyestuffs. It has a role as a curing agent, a flame retardant, a fertilizer, an explosive and a nitrification inhibitor. It is a member of guanidines and a nitrile. The application of nitrification inhibitors has been used as a strategy to promote N utilization efficacy and reduce N2O emissions in paddy Dicyandiamide (DCD) as a widely used nitrification inhibitor inhibits the activity of ammonium-oxidizing bacteria which results in longer ammonium retention and reduces the production of NO2?in soils. DCD efficacy was found to be related to DCD concentration, temperature, moisture, pH, and organic matter content. Studies have shown that leaching DCD from agricultural soils into aquatic ecosystems can strongly change the community composition of benthic stream bacteria and algae and influence stream nutrient cycling stoichiometry. Literature on the mechanisms and benefits of nitrification inhibitors is extensive but there are very few studies focused on the influence of DCD application on other microbes in paddy system.

Production Methods

Dicyanodiamide is manufactured by dimerization of cyanamide in aqueous solution. The 25% cyanamide solution produced is adjusted to pH 8–9 and held at approximately 80C for 2 h to give complete conversion. The hot liquor is filtered and transferred to a vacuum crystallizer, where it is cooled. The crystals or dicyanodiamide are separated in continuous centrifuges and passed to rotary driers. In 1990, the total worldwide production of dicyanodiamide was about 30,000 tons.

General Description

Dicyandiamide is commonly used for the curing of epoxy resins. It is a nitrification inhibitor that is said to be capable of reducing nitrate (NO3-) leaching and nitrous oxide (N2O) emissions from grazed pasture soils.

Purification Methods

Recrystallise cyanoguanidine from water or EtOH. [Beilstein 3 IV 160.]

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