LINALYL CINNAMATE
- CAS No.
- 78-37-5
- Chemical Name:
- LINALYL CINNAMATE
- Synonyms
- FEMA 2641;NSC 46163;Linalylcinnamat;LINALYL CINNAMATE;Linallyl Cinnamate;cinnamicacid,linalylester;LINALYL CINNAMATE USP/EP/BP;6-octadien-3-ol,3,7-dimethyl-cinnamate;3,7-DiMethylocta-1,6-dien-3-yl cinnaMate;1,5-dimethyl-1-vinyl-4-hexen-1-ocinnamate
- CBNumber:
- CB2180067
- Molecular Formula:
- C19H24O2
- Molecular Weight:
- 284.39
- MOL File:
- 78-37-5.mol
- Modify Date:
- 2024/6/26 14:49:19
| Boiling point | 396℃ |
|---|---|
| Density | 0.989 |
| refractive index | 1.4709 (estimate) |
| FEMA | 2641 | LINALYL CINNAMATE |
| Flash point | 216℃ |
| storage temp. | 2-8°C |
| color | An almost colourless oily or slightly viscous liquid |
| Odor | at 100.00 %. sweet balsam lily neroli labdanum amber |
| Odor Type | balsamic |
| JECFA Number | 668 |
| LogP | 6.04 |
| CAS DataBase Reference | 78-37-5 |
| EPA Substance Registry System | 2-Propenoic acid, 3-phenyl-, 1-ethenyl-1,5-dimethyl-4-hexenyl ester (78-37-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H319 |
| Precautionary statements | P264-P280-P305+P351+P338-P337+P313P |
| Toxicity | The acute oral LD50 value in rats was reported as 9.96 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964). The acute dermal LD50 value in rabbits exceeded 5 g/kg |
LINALYL CINNAMATE Chemical Properties,Uses,Production
Description
Linalyl cinnamate has a sweet, persistent odor with soft floral notes. It is clearly balsamic. It has a slightly fruity flavor. May be synthesized from linalyl formate plus methylcinnamate and sodium linalool: by "Roche" method from dehydrolinalool and cinnamic acid via the dehydro ester, which is hydrolyzed to the subject compound.
Chemical Properties
Linalyl cinnamate has a sweet, persistent odor with soft floral notes; clearly balsamic. It has a slightly fruity flavor.
Occurrence
Has apparently not been reported to occur in nature
Uses
It is used as a fragrance in soaps, detergents, creams, lotions, and perfumes.
Production Methods
Linayl cinnamate is formed from the reaction of linayl formate with methyl cinnamate and linalool sodium or from the reaction of dehydrolinalool with cinnamic acid.
Preparation
From linalyl formate plus methylcinnamate and sodium linalool; by “Roche” method from dehydrolinalool and cinnamic acid via the dehydro ester, which is hydrolyzed to the subject compound.
Synthesis
Linalyl cinnamate is prepared:
1) from Linalyl formate plus Methylcinnamate
plus Linalool sodium.
2) from Dehydrolinalool and Cinnamic acid
via the Dehydro-ester, which is hydrolyzed
to the subject ester. ("Roche"-method).
LINALYL CINNAMATE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Central Drug House(P) Ltd. | 91-11-49404040 | New Delhi, India | 6160 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29825 | 58 | Inquiry |
| TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 | United States | 19892 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | China | 8673 | 58 | Inquiry |
| PT CHEM GROUP LIMITED | China | 35426 | 58 | Inquiry | |
| Hu Bei Jiutian Bio-medical Technology CO.,Ltd | 027-88013699 17354350817 | China | 7431 | 58 | Inquiry |
| Amadis Chemical Company Limited | 571-89925085 | China | 131980 | 58 | Inquiry |
| Shaanxi DIDU pharmaceutical and Chemical Co., Ltd | 17691182729 18161915376 | China | 10011 | 58 | Inquiry |
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