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Nickelous acetate

Nickelous acetate Structure
CAS No.
373-02-4
Chemical Name:
Nickelous acetate
Synonyms
Nickel diacetate;Nickel(II) acetate;ai3-26110;ous acetate;Nickelous acetate;nickel(2+)acetate;Nickel(Ⅱ) Acetate;nickelous diacetate;Bisacetoxynickel(II);nickel(2+) diacetate
CBNumber:
CB2502391
Molecular Formula:
C4H6NiO4
Molecular Weight:
176.78
MOL File:
373-02-4.mol
Modify Date:
2024/5/10 17:26:08

Nickelous acetate Properties

Melting point 1555°C
Boiling point 16.6°C
Density 1.798 g/cm3
form solid
Water Solubility 177g/L at 20℃
EPA Substance Registry System Nickel(II) acetate (373-02-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Toxicity guinea pig,LDLo,subcutaneous,20mg/kg (20mg/kg),PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)LUNGS, THORAX, OR RESPIRATION: DYSPNEALUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,Journal of Hygiene. Vol. 8, Pg. 565, 1908.

Nickelous acetate Chemical Properties,Uses,Production

Description

Nickel (II) acetate (Ni (CH3 COO)2 ) is an inorganic compound of nickel and acetic acid. This inorganic compound is usually found as the tetrahydrate. It is used for electroplating.
It can be made by reacting nickel or nickel (II) carbonate with acetic acid.
Ni + 2 CH3 COOH → C4 H6 NiO4 + H2
NiCO3 + 2 CH3 COOH → C4 H6 NiO4 + CO2 + H2 O
The green tetrahydrate has been determined by X-ray crystallography to be octahedral about the central nickel atom, coordinated by four water molecules and two acetate fragments.It may be dehydrated in vacuo, by reaction with acetic anhydride,or by heat.

Chemical Properties

Green, monoclinic crystals; effloresces somewhat in air.Soluble in water and alcohol.

Physical properties

The tetrahydrate is a green crystalline solid; sweet taste; odor of acetic acid; density 1.744 g/cm3; loses water on heating to form a yellow-green powder of anhydrous nickel acetate; decomposes above 250°C; soluble in water, 17g/100mL at 20°C; sparingly soluble in alcohol.

Uses

Textiles (mordant), catalyst.

General Description

Dull green odorless solid. Sinks and mixes slowly with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

Nickelous acetate is a green, crystalline material, mildly toxic and carcinogenic. Combustible when exposed to heat or flame. When heated to decomposition Nickelous acetate emits acrid smoke and irritating fumes [Lewis, 3rd ed., 1993, p. 909].

Hazard

Toxic by ingestion, a carcinogen (OSHA).

Health Hazard

Inhalation causes irritation of nose and throat. Ingestion causes vomiting. Contact with eyes causes irritation. May cause dermatitis in contact with skin.

Safety Profile

Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by ingestion, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits irritating fumes. See also NICKEL COMPOUNDS.

Safety

Nickel salts are carcinogenic and irritate the skin.

Nickelous acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Nickelous acetate Bisacetic acid nickel(II) salt Bisacetoxynickel(II) Diacetic acid nickel(II) salt nickel(2+) diacetate nickel(2+) diethanoate nickelous diacetate Nickel(II) acetate hydrate, 99+%, 99+% NICKEL(II) ACETATE-4-HYDRATE PURE Aceticacid,nickel(2+)salt aceticacid,nickel(2++)salt ai3-26110 nickel(2+)acetate nickel(ii)acetate(1:2) NICKEL(II) ACETATE R. G. NICKELACETATE,ANHYDROUS NICKELOUS(II)ACETATE Nickel Acetate, 4-Hydrate Acetic acid, nickel(2+) salt (2:1) ous acetate Nickel - acetic acid Nickelous acetate ISO 9001:2015 REACH Nickel acetate tetrahydrate extrapure 500GM Nickel(II) acetate Nickel diacetate Nickel(Ⅱ) Acetate 373-02-4 CH3COO2Ni4H2O Organic-metal salt