1-Butylpyrrolidine
![1-Butylpyrrolidine Structure](CAS/GIF/767-10-2.gif)
- CAS No.
- 767-10-2
- Chemical Name:
- 1-Butylpyrrolidine
- Synonyms
- 1-butyl-pyrrolidin;1-BUTYLPYRROLIDINE;N-BUTYL PYRROLIDINE;Pyrrolidine, 1-butyl-;N-butyl-Tetrahydropyrrole;1-BUTYLPYRROLIDINE FOR SYNTHESIS
- CBNumber:
- CB3238589
- Molecular Formula:
- C8H17N
- Molecular Weight:
- 127.23
- MOL File:
- 767-10-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/24 17:21:45
Boiling point | 155-157 °C/754 mmHg (lit.) |
---|---|
Density | 0.814 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 97 °F |
storage temp. | Refrigerator, Under inert atmosphere |
solubility | Chloroform (Sparingly), Ethyl Acetate (Slightly) |
form | Oil |
pka | 10.62±0.20(Predicted) |
color | Colourless |
LogP | 2.209 (est) |
CAS DataBase Reference | 767-10-2(CAS DataBase Reference) |
NIST Chemistry Reference | 1-Butylpyrrolidine(767-10-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS06 |
---|---|
Signal word | Danger |
Hazard statements | H226-H301+H311 |
Precautionary statements | P210-P233-P240-P280-P301+P310-P303+P361+P353 |
Hazard Codes | T |
Risk Statements | 10-24/25 |
Safety Statements | 16-36/37-45 |
RIDADR | UN 2929 6.1/PG 2 |
WGK Germany | 2 |
RTECS | UX9800000 |
HazardClass | 3.2 |
PackingGroup | III |
1-Butylpyrrolidine Chemical Properties,Uses,Production
Uses
1-Butylpyrrolidine has been used in:
microwave-assisted synthesis of ionic liquid precursor, 1-butyl-1-methylpyrrolidinium methylcarbonate.
[N,N-methylbutylpyrrolidinium] thiosalicylate, ionic liquid.
The reaction of 1-butylpyrrolidine with dimethyl carbonate to yield the ionic liquid precursor, 1-butyl-1-methylpyrrolidinium methylcarbonate, has been investigated under microwave heating conditions and the reaction parameters optimised to achieve 100% yield of the pyrrolidinium salt with no by-products in under 1h.
Uses
1-Butylpyrrolidine can be used in the composition for alcohol recovery solution.
Preparation
The synthesis of 1-butylpyrrolidine and its derivatives (1-butylpyrrolidine with a little of 1-butenylpyrrolidines) was developed via a one-pot method from ammonia and 1,4-butandiol. Here, the product of 1-butylpyrrolidine was emphatically investigated, and the yield was 76% under the optimized conditions. Such a route was realized through successive N-alkylation using aqueous ammonia as the nitrogen source over the CuNiPd/ZSM-5 catalyst, which was prepared by a simple incipient wetness method. In this route, 1,4-butandiol not only participated in the formation of the N-heterocycle, but also acted as an alkylating reagent. This work offers a straightforward, economical route for 1-butylpyrrolidine and its derivatives.
One-pot synthesis of 1-butylpyrrolidine and its derivatives from aqueous ammonia and 1,4-butandiol over CuNiPd/ZSM-5 catalysts
1-Butylpyrrolidine Preparation Products And Raw materials
Raw materials
1of3
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