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2-Methoxynaphthalene

2-Methoxynaphthalene Structure
CAS No.
93-04-9
Chemical Name:
2-Methoxynaphthalene
Synonyms
NEROLIN YARA YARA;YARA YARA;NEROLINE YARA YARA;METHYL 2-NAPHTHYL ETHER;YARA;Jara jara;2-Methoxynaphthalene (Yara Yara);NSC 4171;Yura yara;IMPURITY-M
CBNumber:
CB3483471
Molecular Formula:
C11H10O
Molecular Weight:
158.2
MOL File:
93-04-9.mol
MSDS File:
SDS
Modify Date:
2024/8/21 22:41:43

2-Methoxynaphthalene Properties

Melting point 70-73 °C (lit.)
Boiling point 274 °C (lit.)
Density 1.064 g/mL at 25 °C (lit.)
vapor pressure 1.097Pa at 25℃
FEMA 4704 | BETA-NAPHTHYL METHYL ETHER
refractive index 1.5440 (estimate)
Flash point 272-274°C
storage temp. Sealed in dry,Room Temperature
solubility H2O: soluble (completely)
form Crystalline Solid
pka 0[at 20 ℃]
color White to yellow-brown
Odor at 1.00 % in dipropylene glycol. sweet naphthyl floral orange blossom acacia neroli
Odor Type naphthyl
Water Solubility INSOLUBLE
Merck 14,5997
JECFA Number 1257
BRN 1859408
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey LUZDYPLAQQGJEA-UHFFFAOYSA-N
LogP 3.318 at 25℃
CAS DataBase Reference 93-04-9(CAS DataBase Reference)
NIST Chemistry Reference Naphthalene, 2-methoxy-(93-04-9)
EPA Substance Registry System Naphthalene, 2-methoxy- (93-04-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H319-H411
Precautionary statements  P264-P273-P280-P305+P351+P338-P337+P313-P391
Safety Statements  22-24/25
RIDADR  UN 3077 9 / PGIII
WGK Germany  2
RTECS  QJ9468750
TSCA  Yes
HS Code  29093090
Toxicity LD50 oral in rat: > 5gm/kg
NFPA 704
1 0

2-Methoxynaphthalene price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) W470411 2-Methoxynaphthalene ≥99%, FG 93-04-9 1SAMPLE-K ₹4102.68 2022-06-14 Buy
Sigma-Aldrich(India) W470411 2-Methoxynaphthalene ≥99%, FG 93-04-9 100G ₹8205.35 2022-06-14 Buy
Sigma-Aldrich(India) W470411 2-Methoxynaphthalene ≥99%, FG 93-04-9 1KG ₹20480.9 2022-06-14 Buy
Sigma-Aldrich(India) PHR2525 Naproxen Impurity M Pharmaceutical Secondary Standard; Certified Reference Material 93-04-9 100MG ₹45529.95 2022-06-14 Buy
Sigma-Aldrich(India) 148245 2-Methoxynaphthalene 99% 93-04-9 100G ₹1948.5 2022-06-14 Buy
Product number Packaging Price Buy
W470411 1SAMPLE-K ₹4102.68 Buy
W470411 100G ₹8205.35 Buy
W470411 1KG ₹20480.9 Buy
PHR2525 100MG ₹45529.95 Buy
148245 100G ₹1948.5 Buy

2-Methoxynaphthalene Chemical Properties,Uses,Production

Description

β-Naphthyl methyl ether has an intensely sweet, floral odor suggestive of orange blossoms. It is free from naphthol by-odor. It has a sweet, strawberry taste. This may be prepared from potassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthol with dimethyl sulfate or by direct esterification with methyl alcohol.

Chemical Properties

white powder

Uses

2-Methoxynaphthalene is an Impurity of the non-steroidal anti-inflammatory Naproxen (N377525).

Preparation

From postassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthlol with dimethyl sulfate or by direct esterification with methyl alcohol

Purification Methods

Fractionally distil the ether under vacuum. Crystallise it from absolute EtOH, aqueous EtOH, *C6H6, pet ether or n-heptane, and dry it under vacuum in an Abderhalden pistol or distil it in vacuo. The picrate has m 118o (from EtOH or CHCl3). [Kikuchi et al. J Phys Chem 91 574 1987, Beilstein 6 III 2969, 6 IV 4257.]

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b-Methoxynaphthalene Methyl 2-naphtyl ether 2-Methoxynaphthalene, 98% 5GR 6-Methoxy-2-naphthalene NSC 4171 2-Methoxynaphthalene , 98.0%(GC) -Naphthylmethylether Nerolin (old) nerolin(old) Yura yara BETA-METHYL NAPHTHYL ETHER BETA NAPHTHOL METHYL ETHER BETA-NAPHTHYL METHYL ETHER B-NAPHTHOL METHYL ETHER B-NAPHTHYL METHYL ETHER METHYL B-NAPHTHYL ETHER Methyl 2-naphthyl ether beta-Naphthyl methyl ether NAPROXEN IMP M 2-NAPHTHYL METHYL ETHER 2-METHOXYNAPHTHALENE methyl β-naphthyl ether 2-METHOXYNAPHTHALENE 99+% 2-Methoxynaphthalene,98% 2-methoxy-naphthalen 2-Naphthol methyl ether 2-naphtholmethylether beta-Methoxynaphthalene Ethyl beta-naphthyl ether Methyl beta-naphthyl ether methylbeta-naphthylether Naphthalene,2-methoxy- β-Naphthol methyl ether neroline “old” YARA YARA CRYSTALS 2-Methoxynaphthalene, Methyl 2-naphthyl ether 2-MethoxynaphthaL 2-Methoxynaphthalene(Nerolin) 2-Methoxynaphthalene> High Quality 2-methoxynaphthalene 2-Methoxynaphthalene USP/EP/BP Naproxen EP Impurity M (Nerolin) Naproxen Impurity 13(Naproxen EP Impurity M) 2-Methoxynaphthaleneodium salt hydrate 2-Methoxynaphthalene (Yara Yara) METHYL 2-NAPHTHYL ETHER YARA YARA NEROLINE YARA YARA NEROLIN YARA YARA Jara jara YARA Ethyl naphthyl methyl ether β-Naphthol methyl ether Naproxen Impurity M IMPURITY-M 93-04-9 1993-04-09 1993-4-9 34068