2-Methoxynaphthalene
- CAS No.
- 93-04-9
- Chemical Name:
- 2-Methoxynaphthalene
- Synonyms
- NEROLIN YARA YARA;YARA YARA;NEROLINE YARA YARA;METHYL 2-NAPHTHYL ETHER;YARA;Jara jara;2-Methoxynaphthalene (Yara Yara);NSC 4171;Yura yara;IMPURITY-M
- CBNumber:
- CB3483471
- Molecular Formula:
- C11H10O
- Molecular Weight:
- 158.2
- MOL File:
- 93-04-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/12/18 14:08:52
Melting point | 70-73 °C (lit.) |
---|---|
Boiling point | 274 °C (lit.) |
Density | 1.064 g/mL at 25 °C (lit.) |
vapor pressure | 1.097Pa at 25℃ |
refractive index | 1.5440 (estimate) |
FEMA | 4704 | BETA-NAPHTHYL METHYL ETHER |
Flash point | 272-274°C |
storage temp. | Sealed in dry,Room Temperature |
solubility | H2O: soluble (completely) |
form | Crystalline Solid |
pka | 0[at 20 ℃] |
color | White to yellow-brown |
Odor | at 1.00 % in dipropylene glycol. sweet naphthyl floral orange blossom acacia neroli |
Odor Type | naphthyl |
Water Solubility | INSOLUBLE |
Merck | 14,5997 |
JECFA Number | 1257 |
BRN | 1859408 |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
InChIKey | LUZDYPLAQQGJEA-UHFFFAOYSA-N |
LogP | 3.318 at 25℃ |
CAS DataBase Reference | 93-04-9(CAS DataBase Reference) |
NIST Chemistry Reference | Naphthalene, 2-methoxy-(93-04-9) |
EPA Substance Registry System | Naphthalene, 2-methoxy- (93-04-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS09 |
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Signal word | Warning | |||||||||
Hazard statements | H319-H411 | |||||||||
Precautionary statements | P264-P273-P280-P305+P351+P338-P337+P313-P391 | |||||||||
Safety Statements | 22-24/25 | |||||||||
RIDADR | UN 3077 9 / PGIII | |||||||||
WGK Germany | 2 | |||||||||
RTECS | QJ9468750 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29093090 | |||||||||
Toxicity | LD50 oral in rat: > 5gm/kg | |||||||||
NFPA 704 |
|
2-Methoxynaphthalene price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | W470411 | 2-Methoxynaphthalene ≥99%, FG | 93-04-9 | 1SAMPLE-K | ₹4102.68 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | W470411 | 2-Methoxynaphthalene ≥99%, FG | 93-04-9 | 100G | ₹8205.35 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | W470411 | 2-Methoxynaphthalene ≥99%, FG | 93-04-9 | 1KG | ₹20480.9 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | PHR2525 | Naproxen Impurity M Pharmaceutical Secondary Standard; Certified Reference Material | 93-04-9 | 100MG | ₹45529.95 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 148245 | 2-Methoxynaphthalene 99% | 93-04-9 | 100G | ₹1948.5 | 2022-06-14 | Buy |
2-Methoxynaphthalene Chemical Properties,Uses,Production
Description
β-Naphthyl methyl ether has an intensely sweet, floral odor suggestive of orange blossoms. It is free from naphthol by-odor. It has a sweet, strawberry taste. This may be prepared from potassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthol with dimethyl sulfate or by direct esterification with methyl alcohol.
Chemical Properties
white powder
Uses
2-Methoxynaphthalene is an Impurity of the non-steroidal anti-inflammatory Naproxen (N377525).
Preparation
From postassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthlol with dimethyl sulfate or by direct esterification with methyl alcohol
Purification Methods
Fractionally distil the ether under vacuum. Crystallise it from absolute EtOH, aqueous EtOH, *C6H6, pet ether or n-heptane, and dry it under vacuum in an Abderhalden pistol or distil it in vacuo. The picrate has m 118o (from EtOH or CHCl3). [Kikuchi et al. J Phys Chem 91 574 1987, Beilstein 6 III 2969, 6 IV 4257.]
2-Methoxynaphthalene Preparation Products And Raw materials
Raw materials
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Supplier | Advantage |
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GLR Innovations | 58 |
CLEARSYNTH LABS LTD. | 58 |
SynThink RESEARCH CHEMICALS | 58 |
SNECOFRi Pvt Ltd | 58 |
DR MARK LABORATORIES PVT LTD | 58 |
HJ AROCHEM | 58 |
Dodhia Group | 58 |
CNS CHEMICALS | 58 |
AVIGYABIOSCIENCES PRIVATE LIMITED | 58 |
Ramsun Bio Organics | 58 |
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