ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Boric acid >3-Chlorophenylboronic acid
3-Chlorophenylboronic acid
- CAS No.
- 63503-60-6
- Chemical Name:
- 3-Chlorophenylboronic acid
- Synonyms
- 3-CHLOROBENZENEBORONIC ACID;AKOS BRN-0010;RARECHEM AH PB 0179;3-Chlorophenylboroni;3-Chlorophenylboronic;3-CHLOROPHENYLBORNIC ACID;3-Chlorophenylboroic acid;M-CHLOROPHENYLBORONIC ACID;3-CHLOROPHENYLBORONIC ACID;3-Chlorophenylboornic acid
- CBNumber:
- CB3486386
- Molecular Formula:
- C6H6BClO2
- Molecular Weight:
- 156.37
- MOL File:
- 63503-60-6.mol
- Modify Date:
- 2024/5/16 11:16:06
| Melting point | 185-189 °C(lit.) |
|---|---|
| Boiling point | 311.4±44.0 °C(Predicted) |
| Density | 1.32±0.1 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | soluble in Methanol |
| pka | 7.55±0.10(Predicted) |
| form | Crystalline Powder or Needles |
| color | White to light yellow-green |
| Water Solubility | Slightly soluble in water. soluble in ether, tetrahydrofuran,, dimethyl sulfoxide, dimethyl formamide, methanol. |
| BRN | 2936343 |
| InChI | InChI=1S/C6H6BClO2/c8-6-3-1-2-5(4-6)7(9)10/h1-4,9-10H |
| InChIKey | SDEAGACSNFSZCU-UHFFFAOYSA-N |
| SMILES | B(C1=CC=CC(Cl)=C1)(O)O |
| CAS DataBase Reference | 63503-60-6(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332 | |||||||||
| Precautionary statements | P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312 | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 36-37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29163990 | |||||||||
| NFPA 704 |
|
3-Chlorophenylboronic acid price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 417521 | 3-Chlorophenylboronic acid ≥95% | 63503-60-6 | 1G | ₹1179.93 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 417521 | 3-Chlorophenylboronic acid ≥95% | 63503-60-6 | 10G | ₹7187.8 | 2022-06-14 | Buy |
| ALFA India | ALF-B24444-14 | 3-Chlorobenzeneboronic acid, 97% | 63503-60-6 | 25g | ₹8282 | 2022-05-26 | Buy |
| ALFA India | ALF-B24444-06 | 3-Chlorobenzeneboronic acid, 97% | 63503-60-6 | 5g | ₹4058 | 2022-05-26 | Buy |
| TCI Chemicals (India) | C1613 | 3-Chlorophenylboronic Acid (contains varying amounts of Anhydride) | 63503-60-6 | 5G | ₹5400 | 2022-05-26 | Buy |
3-Chlorophenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
white to light yellow-green crystalline powder
Uses
suzuki reaction
Uses
3-Chlorophenylboronic acid is employed as a reactant involved in 1,4-conjugate addition reactions with ethenesulfonamides to form arylethanesulfonamides, Suzuki-Miyaura reactions with dibromotrifluoromethylbenzene, cross-coupling reactions with diazoesters3 or potassium cyanate. It is involved in the synthesis of biarylketones and phthalides and synthesis of inhibitors including PDE4 inhibitors6 among others.
Synthesis
Using m-dichlorobenzene as the starting material, iodine particles and 1,2-dibromoethane as the initiator reacts with magnesium in an organic solvent to prepare 3-chlorophenyl magnesium chloride. Then, the trimethyl borate is reacted with an organic solvent to prepare 3-chlorophenyl borate dimethyl ester. Finally, the product 3-chlorophenylboronic acid is obtained through hydrolysis, extraction, and crystallization.
Solubility in organics
3-Chlorophenylboronic acid can be dissolved in organic solvents such as N, N-dimethylformamide, ethyl acetate, and dichloromethane. In addition, it also has specific solubility in low-polarity and non-polar organic solvents, but 3-chlorophenylboronic acid has poor solubility in water.
3-Chlorophenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
3-CHLOROPHENYLBORONIC ACID, PINACOL ESTER
Cyclohexanone, 3-(3-chlorophenyl)-, (3R)-
6-(3-Chlorophenyl)picolinaldehyde
RARECHEM AL BF 1350
[1,1'-Biphenyl]-3-carboxylic acid, 3'-chloro-, methyl ester
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Global( 500)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Sam Research Labs | +91 9873930190 | Hyderabad, India | 219 | 58 | Inquiry |
| SPD CHEMICALS | +91-7075800742 +91-7075800742 | Hyderabad, India | 214 | 58 | Inquiry |
| REDDY N REDDY PHARMACEUTICALS | +91-9848096759 +91-9848096759 | Hyderabad, India | 1989 | 58 | Inquiry |
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| Prabhat Chemiorganics Limited | +91-2240861600 +91-2240861600 | Maharashtra, India | 86 | 58 | Inquiry |
| Anand Agencies | 91-20-24454597 | Maharashtra, India | 2337 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Sam Research Labs | 58 |
| SPD CHEMICALS | 58 |
| REDDY N REDDY PHARMACEUTICALS | 58 |
| Rivashaa Agrotech Biopharma Pvt. Ltd. | 58 |
| JSK Chemicals | 58 |
| Denisco Chemicals Pvt Ltd | 58 |
| Prabhat Chemiorganics Limited | 58 |
| Anand Agencies | 58 |
| Reax Chemicals | 58 |
63503-60-6(3-Chlorophenylboronic acid)Related Search:
3-Chlorophenylboronic acid, 97%, May contain varying aMounts of anhydride
m-Chlorobenzeneboronic acid
BORONICACID, B-(3-CHLOROPHENYL)-
3-Chlorophenylboronic acid, 97% 5GR
3-Chlorophenylboronic acid, May contain varying amounts of anhydride, 97%
3-Chlorophenylboroni
3-Chlorophenylboronic acid ,98%
3-Chlorophenylboronic acid,97%
3-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
3-CHLOROPHENYLBORONIC ACID 98%
3-CHLOROBENZENEBORONIC ACID / 3-CHLOROPHENYLBORONIC ACID
AKOS BRN-0010
M-CHLOROPHENYLBORONIC ACID
3-Chlorophenylboronic acid, CAS 63503-60-6, C6H6BClO2
3-CHLOROPHENYLBORONIC ACID
3-CHLOROPHENYLBORNIC ACID
RARECHEM AH PB 0179
63503-60-6 3-Chlorophenylboronic acid
3-Chlorophenylboornic acid
3-Chlorophenylboronic
3-Chlorobenzeneboronic acid 98%
B-(3-chlorophenyl)-boronic acid
3-CHLOROBENZENEBORONIC ACID
3-Chlorophenylboroic acid
63503-60-6
C6H6BO2Cl
Organometallic Reagents
Boronic Acids
B (Classes of Boron Compounds)
Boronic Acids and Derivatives
Aryl
BORONIC ACID
Boronic Acid series
BoronicAcids
blocks
Substituted Boronic Acids
Boronic Acids and Derivatives
Boronic Acids
B (Classes of Boron Compounds)
Boronic Acid
Organoborons
Halogenated
Aryl
Boronic acids
Potassium Trifluoroborate
Boronate Ester