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BROMOACETONE

BROMOACETONE Structure
CAS No.
598-31-2
Chemical Name:
BROMOACETONE
Synonyms
CH3COCH2Br;Bromopropanone;B-Stoff;Martonite;BROMOACETONE;1-Bromoacetone;acetonylbromide;bromo-2-propanon;Monobromoacetone;Acetonyl bromide
CBNumber:
CB4301956
Molecular Formula:
C3H5BrO
Molecular Weight:
136.98
MOL File:
598-31-2.mol
MSDS File:
SDS
Modify Date:
2023/9/8 15:24:40

BROMOACETONE Properties

Melting point -36,5°C
Boiling point 137°C
Density 1,63 g/cm3
refractive index nD15 1.4697
Flash point 51℃
Specific Gravity 1.63 (0℃)
CAS DataBase Reference 598-31-2(CAS DataBase Reference)
NIST Chemistry Reference 2-Propanone, 1-bromo-(598-31-2)
EPA Substance Registry System Bromoacetone (598-31-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Warning
Hazard statements  H226
Risk Statements  11-23/24/25-34
Safety Statements  26-36/37/39
RIDADR  1569
HazardClass  6.1(a)
PackingGroup  II
HS Code  29147000

BROMOACETONE Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid when pure, rapidly becomes violet even in absence of air. Soluble in ace- tone, alcohol, benzene, and ether; slightly soluble in water.

Uses

Chemical war gas.

Definition

ChEBI: An alpha-bromoketone that is acetone in which one of the hydrogens is replaced by a bromine atom. A poweful lachrymator, it was formerly used as a chemical weapon.

General Description

A clear colorless liquid turning violet on standing, even in the absence of air, and decomposing to a black resinous mass on long standing. Denser than water and poorly soluble in water. Hence sinks in water. A violent lachrymator--low concentrations are very irritating to the eyes; high concentrations or prolonged exposure at lower concentrations may have adverse health effects. Very toxic by inhalation. Contact with the liquid causes painful burns. Used as a chemical war gas.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

BROMOACETONE decomposes on standing.

Hazard

Toxic by inhalation and skin contact. A lachrymator gas, strong irritant.

Health Hazard

Very powerful lachrymator and upper respiratory tract irritant. Intensely irritating to the eyes, nose, throat, and lungs. Corrosive to the skin.

Fire Hazard

Special Hazards of Combustion Products: Toxic fumes of Bromine

Safety Profile

A poisonous gas. Moderately toxic to humans by inhalation. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.

Purification Methods

Stand bromoacetone over anhydrous CaCO3, filter, distil it under low vacuum, and store it with CaCO3 in the dark at 0o. [Levene Org Synth Coll Vol II 88 1943.] Violently LACHRYMATORY and skin IRRITANT.

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1-bromo-2-propanon B-Stoff Martonite Acetylmethyl bromide acetylmethylbromide alpha-Bromoacetone bromo-2-propanon Bromomethyl methyl ketone bromomethylmethylketone Monobromoacetone Rcra waste number P017 rcrawastenumberp017 stabilizedwithMgO 2-Propanone, 1-bromo- (8CI,9CI) BROMO-2-PROPANONE BROMOACETONE 1-BROMO-2-PROPANONE Acetoffyl bromide Bromoacetone (stabilized with MgO) 1-Bromopropane-2-one --- D/C 09 --- Bromoacetone 100mg [598-31-2] 1-Bromo-2-Propaone 1-Bromoacetone 1-bromo-propan-2-one 2-Propanone, bromo- 2-propanone,1-bromo- Acetonyl bromide acetonylbromide Bromoacetone (stabilized with MgO)> BromoacetoneSolution,1000mg/L,4x1ml 598-31-2 BROMOACETONE Bromoacetone, 95%, stabilized with 0.2%-0.5% MgO CH3COCH2Br Bromopropanone Methotrexate Impurity 62 598-31-2 BrCH2COCH3 Indazoles ACETYLGROUP