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2-Bromo-4'-methoxyacetophenone

2-Bromo-4'-methoxyacetophenone Structure
CAS No.
2632-13-5
Chemical Name:
2-Bromo-4'-methoxyacetophenone
Synonyms
2-BROMO-1-(4-METHOXYPHENYL)ETHAN-1-ONE;2-BROMO-1-(4-METHOXYPHENYL)ETHANONE;PTP Inhibitor II;4-methoxy phenecyl bromide;PTP inhibitor 1;AKOS BBS-00000817;2-Bromo-4-methoxy;TIMTEC-BB SBB007777;2-Bromo-4'-methoxyac;4-METHOXYPHENACYL BR
CBNumber:
CB2715762
Molecular Formula:
C9H9BrO2
Molecular Weight:
229.07
MOL File:
2632-13-5.mol
MSDS File:
SDS
Modify Date:
2024/7/29 15:17:36

2-Bromo-4'-methoxyacetophenone Properties

Melting point 69-71 °C(lit.)
Boiling point 215.8°C (rough estimate)
Density 1.4921 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Crystals or Crystalline Powder
color Off-white to light brown
Water Solubility It is soluble in DMSO, water (partly miscible), most organic solvents, and methanol.
BRN 743112
InChI InChI=1S/C9H9BrO2/c1-12-8-4-2-7(3-5-8)9(11)6-10/h2-5H,6H2,1H3
InChIKey XQJAHBHCLXUGEP-UHFFFAOYSA-N
SMILES C(=O)(C1=CC=C(OC)C=C1)CBr
CAS DataBase Reference 2632-13-5(CAS DataBase Reference)
NIST Chemistry Reference Ethanone, 2-bromo-1-(4-methoxyphenyl)-(2632-13-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H314-H335
Precautionary statements  P260-P271-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
Hazard Codes  C,Xi
Risk Statements  34-36/37-36/37/38
Safety Statements  26-27-28-36/37/39-45-37/39
RIDADR  UN 3261 8/PG 2
WGK Germany  3
8-9-19-21
Hazard Note  Corrosive
HazardClass  8
PackingGroup  III
HS Code  29147090
NFPA 704
1
3 0

2-Bromo-4'-methoxyacetophenone price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 115665 2-Bromo-4′-methoxyacetophenone 97% 2632-13-5 5G ₹6473.35 2022-06-14 Buy
Sigma-Aldrich(India) 115665 2-Bromo-4′-methoxyacetophenone 97% 2632-13-5 25G ₹10370.35 2022-06-14 Buy
Sigma-Aldrich(India) 115665 2-Bromo-4′-methoxyacetophenone 97% 2632-13-5 100G ₹23901.6 2022-06-14 Buy
ALFA India ALF-A13415-22 2-Bromo-4'-methoxyacetophenone, 98% 2632-13-5 100g ₹14299 2022-05-26 Buy
TCI Chemicals (India) M1004 4'-Methoxyphenacyl Bromide min. 98.0 % 2632-13-5 5G ₹3200 2022-05-26 Buy
Product number Packaging Price Buy
115665 5G ₹6473.35 Buy
115665 25G ₹10370.35 Buy
115665 100G ₹23901.6 Buy
ALF-A13415-22 100g ₹14299 Buy
M1004 5G ₹3200 Buy

2-Bromo-4'-methoxyacetophenone Chemical Properties,Uses,Production

Chemical Properties

off-white to light brown crystals or

Uses

2-Bromo-4'-methoxyacetophenone is a α-haloacetophenone derivatives tested for inhibition of protein tyrosine phosphatases SHP-1 and PTP1B.

Preparation

Obtained by reaction of N-bromosuccinimide (NBS) with 4-methoxyacetophenone in the presence of trimethylsilyl trifluoromethanesulfonate (TMS-OTf) in acetonitrile at r.t. for 24 h (87%).

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1-(2-bromo-4-methoxyphenyl)ethanone P-Methoxy-α-bromoacetophenone ω-Bromo-4-methoxyacetophenone, 4-Methoxyphenacyl bromide 2-(4-Methoxyphenyl)-2-oxoethyl bromid 1-(4-Mehtoxyphenyl)-2-bromoethanone 1-(Bromoacetyl)-4-methoxybenzene 4'-Methoxy-α-bromoacetophenone 2-Bromo-4'-methoxyacetophenone,98% 2-Bromo-4′-methoxyacetophenone,ω-Bromo-4-methoxyacetophenone, 4-Methoxyphenacyl bromide 2-Bromo-4'-methoxyac 2-Bromo-4'-methoxyacetophenone, 2-Bromo-1-(4-methoxyphenyl)ethan-1-one, 4-(Bromoacetyl)anisole 4-Methoxyphenacyl Bromide 98% 2-BroMo-1-[4-(Methyloxy)phenyl] ethanone alpha-Bromo-4'-methoxyacetophenone 4-(Bromoacetyl)anisole 2-BroMo-4'-Methoxyacetophenone 97% 4-Methoxyphenacylbromide,98% ALPHA-BROMO-4'-METHOXYACETOPHENONE ALPHA-BROMO-4-METHOXYACETOPHENONE AKOS BBS-00000817 Bromomethyl 4-methoxyphenyl ketone 4-(BROMOACETYL)ANISOLE 4-METHOXYPHENACYL BR 4'-METHOXYPHENACYL BROMIDE 4-METHOXYPHENACYL BROMIDE A-BROMO-P-METHOXYACETOPHENONE 2-BROMO-4-METHOXY ACETOPHENONE TIMTEC-BB SBB007777 OMEGA-BROMO-P-METHOXY ACETOPHENONE OMEGA-BROMO-4-METHOXYACETOPHENONE P-METHOXYPHENACYL BROMIDE PROTEIN TYROSINE PHOSPHATASE INHIBITOR II W-BROMO-4-METHOXY-ACETOPHENONE 2-(4-Methoxyphenyl)-2-oxoethyl bromide 2-Bromo-1-(4-methoxyphenyl)-1-ethanone Ethanone, 2-bromo-1-(4-methoxyphenyl)- 2-Bromo-4-methoxy ω-bromo-4-methoxyacetophenone 2-Bromo-4'-methoxyacetophenone, Pract. 2-Bromo-4'-methoxyacetophenone, 2-Bromo-1-(4-methoxyphenyl)ethan-1-one P-Methoxy-A-Bromoacetophenone 2-BROMO-4''-METHOXYACETOPHENONE (4-METHOXYPHENACYL BROMIDE) 2-bromo-1-(4-methoxyphenyl)-ethanon 2-Bromo-p-methoxyacetophenone 4'-Methoxy-2-bromoacetophenone a-Bromo-4'-methoxyacetophenone Acetophenone, 2-bromo-4'-methoxy- alpha-Bromo-p-methoxyacetophenone Bromomethyl p-anisyl ketone w-Bromo-p-methoxyacetophenone 2-Bromo-4'-Methoxyacetophenone 4'-Methoxyphenacyl Bromide 2-Bromo-1-(4-Methoxyphenyl)ethan-1-one p-Methoxy-alpha-Chloroacetophenone Bromo Methoxy Acetophenone Para Methoxy Phenacyl Bromide 2-Bromo-4'-methoxyacetophenone, 98%, reagent grade 4'-MethoxyphenacylBromide> PTP inhibitor 1 α-Bromo-4-methoxyacetophenone Raloxifene Impurity 12