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3-Ethoxyacryloyl chloride

3-Ethoxyacryloyl chloride Structure
CAS No.
6191-99-7
Chemical Name:
3-Ethoxyacryloyl chloride
Synonyms
88.0%;3-EthoxyacryL;Ethoxyacryloylchloride;b-Ethoxyacrylic chloride;3-ETHOXYACRYLOYL CHLORIDE;3-Ethoxyacrylic acid chloride;3-ethoxyprop-2-enoyl chloride;3-Ethoxyacryloyl Chloride >(2E)-3-Ethoxyacryloyl chloride;2-Propenoyl chloride, 3-ethoxy-
CBNumber:
CB5850789
Molecular Formula:
C5H7ClO2
Molecular Weight:
134.56
MOL File:
6191-99-7.mol
MSDS File:
SDS
Modify Date:
2023/6/8 17:06:38

3-Ethoxyacryloyl chloride Properties

Boiling point 75°C/10mmHg(lit.)
Density 1.125±0.06 g/cm3(Predicted)
refractive index 1.4860 to 1.4910
Flash point 25 °C
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
InChI InChI=1S/C5H7ClO2/c1-2-8-4-3-5(6)7/h3-4H,2H2,1H3
InChIKey SFMFACMIOWQIPR-UHFFFAOYSA-N
SMILES C(Cl)(=O)C=COCC

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H226-H302-H314-H317-H334
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C
Risk Statements  10-22-34-42/43
Safety Statements  23-24-26-36/37/39-45
RIDADR  UN2920 8/PG 2
WGK Germany  3
HazardClass  8/3
PackingGroup  II
HS Code  2909500090
NFPA 704
3
2 0

3-Ethoxyacryloyl chloride price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 691119 3-Ethoxy-acryloyl chloride ≥85% (H-NMR) 6191-99-7 250MG ₹36404.48 2022-06-14 Buy
TCI Chemicals (India) E1066 3-Ethoxyacryloyl Chloride min. 88.0 % 6191-99-7 5G ₹9800 2022-05-26 Buy
Product number Packaging Price Buy
691119 250MG ₹36404.48 Buy
E1066 5G ₹9800 Buy

3-Ethoxyacryloyl chloride Chemical Properties,Uses,Production

Chemical Properties

light yellow liquid

Uses

Used as an intermediate in organic synthesis.

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 13, p. 1015, 1976 DOI: 10.1002/jhet.5570130515
Synthesis, p. 1079, 1993

Synthesis

To a solution of ethyl 3,3-diethoxypropionate (20 g) in water (50 mL) was added sodium hydroxide (5 g) at room temperature and the reaction was heated to 110°C and stirred at this temperature for 1 hour. Then the reaction system was naturally cooled to room temperature, diluted with water (2L), extracted with ethyl acetate (1L), the extract was washed with saturated brine (1L), dried over anhydrous sodium sulfate and filtered; the filtrate was directly concentrated to obtain To the crude was added thionyl chloride (30 mL) and the reaction was heated to 70°C and stirring was continued at this temperature for one hour. After the reaction, the reaction solution was directly concentrated under reduced pressure to obtain a brown solid 3-Ethoxyacryloyl chloride (14 g, yield 90%).

3-Ethoxyacryloyl chloride Preparation Products And Raw materials

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3-ETHOXYACRYLOYL CHLORIDE 3-Ethoxyacrylic acid chloride 3-Ethoxypropenoic acid chloride 3-ethoxyprop-2-enoyl chloride Ethoxyacryloylchloride b-Ethoxyacrylic chloride (2E)-3-Ethoxyacryloyl chloride 88.0% 3-Ethoxyacryloyl Chloride > 3-EthoxyacryL 2-Propenoyl chloride, 3-ethoxy- 3-Ethoxyacryloyl chloride ISO 9001:2015 REACH 6191-99-7 Small molecule Acid HalidesOrganic Building Blocks Acyclic Alkenes Carbonyl Compounds Organic Building Blocks