ChemicalBook > Product Catalog >Inorganic chemistry >Inorganic salts >Borides, borates and borate >Lithium bis(oxalate)borate
Lithium bis(oxalate)borate
- CAS No.
- 244761-29-3
- Chemical Name:
- Lithium bis(oxalate)borate
- Synonyms
- LIBOB;LITHIUM BIS(OXALATO)BORATE;CHEMLYTE BO MX;CHEMLYTE BO M1;lithium bis(oxalate)borate;Lithium oxalate boronic acid;Lithium bis(ethanedioato)borate;Lithium diethyleneic acid borate;Lithium bis(oxalato)borate LIBOB;LITHIUM BIS (OXALATE) BORATE(LiBOB)
- CBNumber:
- CB6159579
- Molecular Formula:
- C4BLiO8
- Molecular Weight:
- 193.79
- MOL File:
- 244761-29-3.mol
- Modify Date:
- 2024/1/8 10:22:22
| Melting point | >300°C (lit.) |
|---|---|
| vapor pressure | 0.004Pa at 20℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| form | powder or crystals |
| Water Solubility | 1015g/L at 20℃ |
| InChI | InChI=1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1 |
| InChIKey | NVQAYVUCVASGDK-UHFFFAOYSA-N |
| SMILES | O=C1C([O-][B+3]2([O-]C(=O)C(=O)[O-]2)[O-]1)=O.[Li+] |
| LogP | 0 at 20℃ |
| EPA Substance Registry System | Borate(1-), bis[ethanedioato(2-)-.kappa.O1,.kappa.O2]-, lithium, (T-4)- (244761-29-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|---|---|
| Signal word | Danger |
| Hazard statements | H302-H317-H318 |
| Precautionary statements | P261-P264-P280-P301+P312-P302+P352-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| WGK Germany | 3 |
| HS Code | 29319090 |
Lithium bis(oxalate)borate Chemical Properties,Uses,Production
Uses
Lithium bis(oxalate)borate is a new and proprietary conductive salt for the use in high performance batteries like lithium batteries, lithium ion batteries and lithium polymer batteries. The new halide-free product may be used instead of traditional fluorinated compounds like LiPF6, LiBF4, Li-triflate, methanides, imides etc.
General Description
This product has been enhanced for energy efficiency.
Synthesis
Yu et al. employed a solid-state reaction using oxalic acid, lithium hydroxide, and boric acid as starting materials for the first time. This was followed by a thermal treatment in the air and a recrystallization process to obtain LiBOB. In addition, LiBOB decomposes into Li2C2O3, B2O3, CO2, and CO at temperatures higher than 300 °C [1].
References
[1] Ceren Zor. “Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB).” The Journal of Physical Chemistry C 125 21 (2021): 11310–11317.
Lithium bis(oxalate)borate Preparation Products And Raw materials
Raw materials
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Global( 241)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21675 | 55 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | China | 12460 | 58 | Inquiry |
| Hebei Yanxi Chemical Co., Ltd. | +86-17531190177; +8617531190177 | China | 6011 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 16209 | 58 | Inquiry |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | China | 2967 | 58 | Inquiry |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | China | 6387 | 58 | Inquiry |
| Shanghai Longyu Biotechnology Co., Ltd. | +8613917842738 | China | 2534 | 58 | Inquiry |
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