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TRIMETHYLSILYLMETHYL AZIDE

TRIMETHYLSILYLMETHYL AZIDE Structure
CAS No.
87576-94-1
Chemical Name:
TRIMETHYLSILYLMETHYL AZIDE
Synonyms
DK939;RIMETHYLSILYLMETHYL AZIDE;AZIDOMETHYLTRIMETHYLSILANE;TRIMETHYLSILYLMETHYL AZIDE;Silyl Methyl azide triMethyl
CBNumber:
CB6264697
Molecular Formula:
C4H11N3Si
Molecular Weight:
129.24
MOL File:
87576-94-1.mol
MSDS File:
SDS
Modify Date:
2023/11/13 16:15:56

TRIMETHYLSILYLMETHYL AZIDE Properties

Boiling point 92-95°C
Density 0,87 g/cm3
refractive index 1.4300 to 1.4340
Flash point 6°C
solubility Sol organic solvents; insol water.
form clear liquid
color Colorless to Yellow to Green
Specific Gravity 0.87
Hydrolytic Sensitivity 7: reacts slowly with moisture/water

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378-P403+P235-P501
Risk Statements  11-23/24/25
Safety Statements  16-36/37/39-45
RIDADR  1992
HazardClass  3
PackingGroup  II
HS Code  2931900090
NFPA 704
3
0 0

TRIMETHYLSILYLMETHYL AZIDE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemicals (India) T1184 Trimethylsilylmethyl Azide min. 97.0 % 87576-94-1 1G ₹8300 2022-05-26 Buy
TCI Chemicals (India) T1184 Trimethylsilylmethyl Azide min. 97.0 % 87576-94-1 5G ₹16300 2022-05-26 Buy
Product number Packaging Price Buy
T1184 1G ₹8300 Buy
T1184 5G ₹16300 Buy

TRIMETHYLSILYLMETHYL AZIDE Chemical Properties,Uses,Production

Physical properties

bp 43 °C/43 mmHg; IR νmax 2100 cm?1; 1H NMR (CDCl3) δ = 0.12 (s, 9H), 2.75 (s, 2H); MS m/z 129, 73.

Uses

Trimethylsilylmethyl Azide is used in the amination of organometallic compounds; preparation of heterocyclic compounds; precursor of azomethine ylide, reactant in Silylmethyl-Substituted Heterocumulenes and [3 + 2] Cycloaddition etc.

Preparation

Obtained in high yield by reaction of sodium azide and (chloromethyl)trimethylsilane in DMF or HMPA at 80°C.

TRIMETHYLSILYLMETHYL AZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 93)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Innovative Labs +91-9885794886 +91-9885794886 Telangana, India 219 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Zibo Hangyu Biotechnology Development Co., Ltd +86-0533-2185556 +8617865335152 China 10978 58 Inquiry
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Shenzhen Nexconn Pharmatechs Ltd +86-755-89396905 +86-15013857715 China 10312 58 Inquiry
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Career Henan Chemica Co +86-0371-86658258 +8613203830695 China 30253 58 Inquiry
ANHUI WITOP BIOTECH CO., LTD +8615255079626 China 23556 58 Inquiry
TRIMETHYLSILYLMETHYL AZIDE AZIDOMETHYLTRIMETHYLSILANE Silyl Methyl azide triMethyl RIMETHYLSILYLMETHYL AZIDE DK939 87576-94-1 C4H11N3Si Amination Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-(C)4 Compounds Amination Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Synthetic Organic Chemistry