TITANIUM(III) FLUORIDE
- CAS No.
- 13470-08-1
- Chemical Name:
- TITANIUM(III) FLUORIDE
- Synonyms
- TiF3;TSCS(13470-08-1);TITANIUM FLUORIDE;TITANIUM TRIFLUORIDE;itanium(III)fluoride;TITANIUM(III) FLUORIDE;titaniumfluoride(tif3);Titanium fluoride(F3Ti);Titanium fluoride (TiF3);Titanium(III)fluoride99%
- CBNumber:
- CB6377711
- Molecular Formula:
- F3Ti
- Molecular Weight:
- 104.86
- MOL File:
- 13470-08-1.mol
- Modify Date:
- 2024/7/11 13:03:46
| Melting point | 1200 °C |
|---|---|
| Boiling point | 1400 °C |
| Density | 3.4 g/mL at 25 °C(lit.) |
| solubility | insoluble in H2O, dilute acid solutions, alkaline solutions |
| form | Crystalline Powder |
| Specific Gravity | 3.4 |
| color | Red to brown |
| Water Solubility | Sparingly soluble. It hydrolyses in water. |
| Sensitive | Air & Moisture Sensitive |
| Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3 |
| CAS DataBase Reference | 13470-08-1(CAS DataBase Reference) |
| EPA Substance Registry System | Titanium fluoride (TiF3) (13470-08-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 20/21/22-34-32-14 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3260 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10 | |||||||||
| Hazard Note | Corrosive | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 28261990 | |||||||||
| NFPA 704 |
|
TITANIUM(III) FLUORIDE price More Price(3)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 399817 | Titanium(III) fluoride | 13470-08-1 | 5G | ₹1818.6 | 2022-06-14 | Buy |
| ALFA India | ALF-013079-18 | Titanium(III) fluoride | 13470-08-1 | 50g | ₹23600 | 2022-05-26 | Buy |
| ALFA India | ALF-013079-09 | Titanium(III) fluoride | 13470-08-1 | 10g | ₹5132 | 2022-05-26 | Buy |
TITANIUM(III) FLUORIDE Chemical Properties,Uses,Production
Chemical Properties
Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.
Uses
It is used as a laboratory chemicals & for manufacture of chemicals.
Production Methods
Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%.
TITANIUM(III) FLUORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
| Alfa Chemistry | United States | 24072 | 58 | Inquiry | |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | China | 9003 | 58 | Inquiry |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | China | 49999 | 58 | Inquiry |
| Aladdin Scientific | +1-+1(833)-552-7181 | United States | 57511 | 58 | Inquiry |
| ABCR GmbH & CO. KG | 49 721 95061 0 | Germany | 6846 | 75 | Inquiry |
| Supplier | Advantage |
|---|---|
| CHEMSWORTH | 30 |
| Alfa Aesar | 58 |
| Chongqing Chemdad Co., Ltd | 58 |
| Career Henan Chemica Co | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 58 |
| Alfa Chemistry | 58 |
| Shaanxi Didu New Materials Co. Ltd | 58 |
| GIHI CHEMICALS CO.,LIMITED | 58 |
| Aladdin Scientific | 58 |
| ABCR GmbH & CO. KG | 75 |