MENTHONE
- CAS No.
- 89-80-5
- Chemical Name:
- MENTHONE
- Synonyms
- P-MENTHAN-3-ONE;2-Isopropyl-5-methylcyclohexanone;d-Menthone;MENTHON;p-Menthone;trans-Menthone;MENTHONE;FEMA 2667;MENTHON REIN;PARA-MENTHONE
- CBNumber:
- CB6453271
- Molecular Formula:
- C10H18O
- Molecular Weight:
- 154.25
- MOL File:
- 89-80-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/5/25 18:01:15
| Boiling point | 210°C |
|---|---|
| Density | 0.896 |
| vapor pressure | 37Pa at 25℃ |
| FEMA | 2667 | MENTHONE |
| refractive index | 1.450 |
| Flash point | 69 ºC |
| storage temp. | Refrigerator |
| solubility | Chloroform (Sparingly), Methanol (Sparingly) |
| form | Oil |
| color | Colourless |
| Odor | at 10.00 % in dipropylene glycol. minty |
| Odor Type | minty |
| Water Solubility | 688mg/L at 25℃ |
| LogP | 2.295 at 25℃ |
| NIST Chemistry Reference | Cyclohexanone, 5-methyl-2-(1-methylethyl)-, trans-(89-80-5) |
| EPA Substance Registry System | Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (2R,5S)-rel- (89-80-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H412-H302 |
| Precautionary statements | P264-P270-P301+P312-P330-P501-P273-P501 |
| Hazard Codes | Xn |
| Risk Statements | 22-36-43-52/53 |
| Safety Statements | 26-36/37-61 |
| HS Code | 29142990 |
| Toxicity | The acute oral LD50 in rats was reported as 2.18 ml/kg (1.82-2.62 ml/kg) (Levenstein, 1973a). The acute dermal LD50 in rabbits exceeded 5 g/kg (Levenstein, 1973b) |
MENTHONE Chemical Properties,Uses,Production
Description
Menthone has a characteristic odor similar to menthol. May be prepared by oxidation of menthol.
Chemical Properties
Menthone has a characteristic mint-like odor.
Occurrence
Reported found in severalstereoisomersin nature; l-menthone is a constituent of the essential oils of Russian and American peppermint, geranium, Andropogon gragrans, Mentha timija and Mentha arvensis; d-menthone is present in the essential oils of Barosma pulchellum, Nepeta japonica Maxim., and others. d-Isomenthone has been reported isolated from Micromeria abis sinica Benth., Pelargonium tomentosum Jacquin and others; l-isomenthone has been identified in Réunion geranium, Pelargonium capitau and others. Also reported found in lemon peel oil, black currants, celery seed, cinnamon, peppermint, cornmint, pennyroyal and other mentha oils, nutmeg, thymus, cocoa, mushrooms, starfruit, coriander leaf, rice, tarragon, calamus, buckwheat, sweet and bitter fennel, cherimoya, buchu oil, clam and sweet grass oil.
Uses
(±)-Menthone is a Menthol derivative. A volatile flavor compound found in human milk, red and black rice bran and specialty rice types.
Preparation
By oxidation of menthol.
Safety Profile
Moderately toxic by ingestion, intravenous, and subcutaneous routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also KETONES.
Metabolism
H?m?l?inen (1912) claimed that menthone was probably oxidized in the rabbit to ketomenthone, since the glucuronide produced was converted by warm dilute H2SO4 to a substance which was probably △4(8 -p-menthen-3-one (pulegone). Williams (1940), however, showed that it underwent reduction in the rabbit with the production of d-neomenthol. The presence of l-menthol, the other possible reduction product, was not detected and it appeared that the biological reduction was asymmetric (Williams, 1959).
MENTHONE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| D D Shah Essential Oil Co | +91-2222850577 +91-2222850577 | Maharashtra, India | 34 | 58 | Inquiry |
| Sharp Mint Limited | +91-1142290700 +91-1142290700 | New Delhi, India | 9 | 58 | Inquiry |
| Herbochem Industries | +91-8853058555 +91-8853058222 | Uttar Pradesh, India | 10 | 58 | Inquiry |
| B D Aromatics Pvt Ltd | +919837047555 | Uttar Pradesh, India | 11 | 58 | Inquiry |
| Musks & Fragrance | +91-22-2624 9902 / 2624 4121 /2 670 3348 | New Delhi, India | 124 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21675 | 55 | Inquiry |
| Chengdu GLP biotechnology Co Ltd | 028-87075086 13350802083 | CHINA | 1824 | 58 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
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