Zirconium oxychloride
- CAS No.
- 7699-43-6
- Chemical Name:
- Zirconium oxychloride
- Synonyms
- ZROCL2;ZIRCONIUM CHLORIDE;ZIRCONYL CHLORIDE;ZIRCONIUM DICHLORIDE OXIDE;nci-c60811;chlorozirconyl;JACS-7699-43-6;dichlorooxo-zirconiu;Dichlorooxozirconium;Zirconium oxychlorid
- CBNumber:
- CB6470074
- Molecular Formula:
- Cl2OZr
- Molecular Weight:
- 178.13
- MOL File:
- 7699-43-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/10 14:01:29
| Melting point | −15 °C |
|---|---|
| Density | 1.344 g/mL at 25 °C |
| solubility | soluble in H2O, ethanol |
| form | Liquid |
| color | Clear colorless |
| Merck | 13,10237 |
| Stability | Stable. Incompatible with strong oxidizing agents, water, moisture, alkali metals. |
| CAS DataBase Reference | 7699-43-6(CAS DataBase Reference) |
| EPA Substance Registry System | Zirconium, dichlorooxo- (7699-43-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|---|---|
| Signal word | Danger |
| Hazard statements | H290-H314-H335 |
| Precautionary statements | P234-P261-P271-P280-P303+P361+P353-P305+P351+P338 |
| Hazard Codes | C,Xn |
| Risk Statements | 23-34-37-20/21/22-36/38 |
| Safety Statements | 26-36-45-36/37/39-36/37 |
| RIDADR | UN 1789 |
| WGK Germany | 1 |
| HazardClass | 8 |
| PackingGroup | III |
Zirconium oxychloride Chemical Properties,Uses,Production
Chemical Properties
Zirconium oxychloride exists as white silky crystals, soluble in water and alcohol. With water, the octahydrate is formed as tetragonal white needles. It is extremely hygroscopic and decomposes to zirconium tetrachloride (ZrCl4) and zirconium oxide (ZrO2) at 250 C. It is also formed as the octahydrate [13520-92-8] as white, tetrahedral crystals that are very soluble in water, ethyl alcohol, ether, and methanol, among others, but only slightly soluble in hydrochloric acid. When heated to decomposition, it emits toxic fumes of hydrogen chloride.
Uses
Textile, cosmetic and grease additive, antiperspirant, water repellents, chemical reagent, zirconium salts, in lakes and toners of acidic and basic dyes, oil-field acidizing aid.
Reactivity Profile
Acidic salts, such as Zirconium oxychloride, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
Health Hazard
Has only a mild pharmacological action. Inhalation of dust may irritate nose and throat. Contact with eyes or skin causes irritation.
Safety Profile
Poison by intraperitoneal route. Moderately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Cl-. Used as an antiperspirant. See also ZIRCONIUM COMPOUNDS and CHLORIDES.
Purification Methods
Crystallise it repeatedly from 8M HCl to give ZrOCl2.8H2O (see below). On drying, ZrOCl2.6H2O, m 150o, is formed. The product is not free from hafnium. [Blumenthal J Chem Ed 39 607 1962.]
Zirconium oxychloride Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Star Earth Minerals Pvt Ltd | +91-9594153555 +91-9594775679 | Maharashtra, India | 45 | 58 | Inquiry |
| Zirconium Chemicals Private Limited | +91-9136333867 +91-9819819364 | Maharashtra, India | 12 | 58 | Inquiry |
| Bhalla Chemical Works Private Limited | +91-1126214550 +91-1140542344 | New Delhi, India | 6 | 58 | Inquiry |
| Star Earth Minerals Private Limited | 08046065133 | Mumbai, India | 35 | 58 | Inquiry |
| Dhairya International | 08048617323 | Vadodara, India | 25 | 58 | Inquiry |
| Zirconium Chemicals Private Limited | 08068442229Ext 980 | Mumbai, India | 9 | 58 | Inquiry |
| Icon Millenium Exports | 09867503195 | Mumbai, India | 1 | 58 | Inquiry |
| Alliance Global | 08048965751 | Delhi, India | 211 | 58 | Inquiry |
| Arnish Laborates Private Limited | 08048957357 | Mumbai, India | 204 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
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