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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Structure
CAS No.
13170-43-9
Chemical Name:
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
Synonyms
TRIMETHYLSILYLMETHYL;siL;(Trimethylsilyl)methylmagnesium;(20% in Ethyl Ether, ca. 1Mol/L);Trimethylsilylmethylchloromagnesium;Trimethylsiylmethylmagnesium chloride;(Trimethylsilylmethyl)chloromagnesium;TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;TriMethylsilylMethylMagnesiuM Chloride 
CBNumber:
CB6732457
Molecular Formula:
C4H11ClMgSi
Molecular Weight:
146.97
MOL File:
13170-43-9.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Properties

Melting point 105.8-106.4 °C
Density 1.04
Flash point -40°C
storage temp. Flammables + water-Freezer (-20°C)e area
solubility Sol ethereal solvents; reacts with protic solvents.
form Low Melting Solid
Specific Gravity 0.912
color Clear colorless to yellow to greenish
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN 3587255
CAS DataBase Reference 13170-43-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H225-H302-H314-H336-H313-H318
Precautionary statements  P260h-P303+P361+P353-P405-P501a-P210-P261-P280-P305+P351+P338-P310
Hazard Codes  F+,C,F
Risk Statements  12-14-22-34-66-67-19-11
Safety Statements  16-26-36/37/39-43-45
RIDADR  UN 3399 4.3/PG 1
WGK Germany  1
10
TSCA  No
HazardClass  8
PackingGroup  II
HS Code  29319090
NFPA 704
3
3 2
W

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 256021 (Trimethylsilyl)methylmagnesium chloride solution 1.0?M in diethyl ether 13170-43-9 100ML ₹17969.5 2022-06-14 Buy
Sigma-Aldrich(India) 256021 (Trimethylsilyl)methylmagnesium chloride solution 1.0?M in diethyl ether 13170-43-9 100ML ₹17969.5 2022-06-14 Buy
TCI Chemicals (India) T2609 Trimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L) 13170-43-9 100ML ₹10300 2022-05-26 Buy
TCI Chemicals (India) T1451 Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L) 13170-43-9 100ML ₹7000 2022-05-26 Buy
Product number Packaging Price Buy
256021 100ML ₹17969.5 Buy
256021 100ML ₹17969.5 Buy
T2609 100ML ₹10300 Buy
T1451 100ML ₹7000 Buy

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

Grey liquid

Uses

Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.

Preparation

From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Global( 185)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
VASIN BIO LIFE SCIENCES PVT LTD 9491644688 Hyderabad, India 2096 58 Inquiry
Symax Fine Chemicals 08068442240Ext 881 Hyderabad, India 51 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Hychem Laboratories 91-40-40045318 Hyderabad, India 105 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16220 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21676 55 Inquiry
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE (trimethylsilyl)methylmagnesium chl. sol Trimethylsilylmethylmagnesium chloride (20% in ethyl ether (TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER (TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER [(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether [(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran (Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF (Trimethylsilyl)methylmagnesium chloride solution Trimethylsiylmethylmagnesium chloride Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L) (TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, SpcSeal (trimethylsilyl) methyl magnesium chloride 1.3M tetrahydrofuran (Trimethylsilyl)methylmagnesium chloride, 0.50 M in 2-MeTHF (Trimethylsilyl)methylmagnesium chloride, 0.50 M in THF (Trimethylsilyl)methylmagnesium chloride, 1,3m solution in THF (Trimethylsilyl)methylmagnesium chloride1.3M solution in THFAcroSeal§3 (Trimethylsilylmethyl)chloromagnesium Trimethylsilylmethylchloromagnesium (Trimethylsilyl)methylmagnesium chloride solution 1.0 in diethyl ether (Trimethylsilyl)methylmagnesium chloride, 1.3M solution in THF, AcroSeal TriMethylsilylMethylMagnesiuM Chloride (ca. 18% in Tetrahydrofuran, ca. 1Mol/L) (TriMethylsilyl)MethylMagnesiuM chloride, 1.3M solution in THF, AcroSeal 100ML (TriMethylsilyl)MethylMagnesiuM chloride, 0.5M in 2-MeTHF (20% in Ethyl Ether, ca. 1Mol/L) TriMethylsilylMethylMagnesiuM Chloride  TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in Methyltetrahydrofuran (TriMethylsilyl)MethylMagnesiuM chloride, 1.0M solution in diethyl ether, J&KSeal (TriMethylsilyl)MethylMagnesiuM chloride solution 1.0 M in diethyl ether (TriMethylsilyl)MethylMagnesiuM chloride, 1.0 M solution in diethyl ether, SpcSeal (TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, J&KSeal (Trimethylsilyl)methylmagnesium chloride 1.3MTHF siL TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in methyltetrahydrofuran (46-48 wt %) TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 1.0M in diethyl ether (19 wt %) (Trimethylsilyl)methylmagnesium Chloride, Tetrahydrofuran Solution (abt. 1mol/l) [TMSCH2MgCl(THF)] TIANFU CHEM-- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE TRIMETHYLSILYLMETHYL Magnesium, chloro[(trimethylsilyl)methyl]- (7CI, 8CI, 9CI) Trimethyl silyl methyl magnesium chloride 1. M in THF (Trimethylsilyl)methylmagnesium 13170-43-9 CH33SiCH2MgCl C4H11ClMgSi Alkyl Organometallic Reagents Si-(C)4 Compounds Grignard Reagents & Alkyl Metals Grignard Reagents Classes of Metal Compounds Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Typical Metal Compounds Mg (Magnesium) Compounds Si (Classes of Silicon Compounds) Si-(C)4 Compounds Silicon Compounds (for Synthesis) Synthetic Organic Chemistry