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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Structure
  • ₹7000 - ₹17969.5
  • Product name: TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
  • CAS: 13170-43-9
  • MF: C4H11ClMgSi
  • MW: 146.97
  • EINECS:
  • MDL Number:MFCD00009916
  • Synonyms:TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;Trimethylsilylmethylmagnesium chloride (20% in ethyl ether;(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER;(TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER;[(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether;[(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran;(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF
4 prices
Selected condition:

Brand

  • Sigma-Aldrich
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100ML
  • ManufacturerSigma-Aldrich
  • Product number256021
  • Product description(Trimethylsilyl)methylmagnesium chloride solution 1.0?M in diethyl ether
  • Packaging100ML
  • Price₹17969.5
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1451
  • Product descriptionTrimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
  • Packaging100ML
  • Price₹7000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT2609
  • Product descriptionTrimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L)
  • Packaging100ML
  • Price₹10300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number256021
  • Product description(Trimethylsilyl)methylmagnesium chloride solution 1.0?M in diethyl ether
  • Packaging100ML
  • Price₹17969.5
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 256021 (Trimethylsilyl)methylmagnesium chloride solution 1.0?M in diethyl ether 100ML ₹17969.5 2022-06-14 Buy
TCI Chemicals (India) T1451 Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L) 100ML ₹7000 2022-05-26 Buy
TCI Chemicals (India) T2609 Trimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L) 100ML ₹10300 2022-05-26 Buy
Sigma-Aldrich(India) 256021 (Trimethylsilyl)methylmagnesium chloride solution 1.0?M in diethyl ether 100ML ₹17969.5 2022-06-14 Buy

Properties

Melting point :105.8-106.4 °C
Density :1.04
Flash point :-40°C
storage temp. :Flammables + water-Freezer (-20°C)e area
solubility :Sol ethereal solvents; reacts with protic solvents.
form :Low Melting Solid
Specific Gravity :0.912
color :Clear colorless to yellow to greenish
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :3587255
CAS DataBase Reference :13170-43-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H313 May be harmful in contact with skin Acute toxicity,dermal Category 5 P312
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P405 Store locked up.

Description

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals,cross-coupling with aryl triflates and carbamates,and cross-coupling with vinyl selenides.

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