pelletierine

pelletierine Structure
CAS No.
4396-01-4
Chemical Name:
pelletierine
Synonyms
pelletierine;isopelletierine;1-piperidin-2-ylacetone;1-(2-Piperidinyl)acetone;2-(2-Oxopropyl)piperidine;1-(2-Piperidyl)-2-propanone;1-piperidin-2-ylpropan-2-one;1-(2-Piperidinyl)-2-propanone;2-Propanone, 1-(2-piperidinyl)-;1-piperidin-2-ylacetone (SALTDATA: FREE)
CBNumber:
CB6937672
Molecular Formula:
C8H15NO
Molecular Weight:
141.21
MOL File:
4396-01-4.mol
Modify Date:
2023/5/4 17:34:38

pelletierine Properties

Melting point 130-132 °C
Boiling point 195 °C
Density 0.918±0.06 g/cm3(Predicted)
storage temp. Hygroscopic, -20°C Freezer, Under inert atmosphere
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Oil
pka pK1:9.45 (15°C)
color Colourless to Light Yellow
Stability Hygroscopic

pelletierine Chemical Properties,Uses,Production

Description

An alkaloid of this name was discovered by Tanret but when this alkaloid was shown to be (±)-pelletierine, the name was adopted for this particular base isolated from Punica granatum. The alkaloid is an oily liquid which yields a number of well crystalline salts and derivative: the hydrochloride, m.p. 143°C; hydrobromide, m.p. 149°C; picrate, m.p. 147 -8°C and the picrolonate, m.p. 185-6°C. The N-acetyl derivative is an oily liquid, b.p. 110-5°C/0.I mm while the N-benzoyl compound is crystalline with m.p. 72-4°C. The alkaloid may be prepared by the demethylation of methylisopelletierine, the action being revers_x0002_ible.

References

Tanret., Compt. rend., 88, 716 (1879) Tanret., ibid, 90, 696 (1880) Hesse., Rev. trav. Chim., 52, 1005 (1919) Hess, Littman., Annalen, 494, 7 (1932) Wibaut, Kloppenburg, Beets., Rev. trav. Chim., 63, 134 (1944) Anet, Hughes, Ritchie., Nature, 164, 50 I (1949) Galinovsky, Branchetti, Vogl.,Monatsh., 84, 1221 (1953) Galinovsky, Hollinger., ibid, 85, 1012 (1954) Wibaut, Hirschel., Rev. trav. Chim., 75,225 (1956)

pelletierine Preparation Products And Raw materials

Raw materials

Preparation Products

pelletierine Suppliers

Global( 9)Suppliers
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GIHI CHEMICALS CO.,LIMITED +8618058761490 China 50000 58 Inquiry
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cjbscvictory 13348960310 13348960310 China 10000 58 Inquiry
pelletierine 2-Acetonylpiperidinepunicineisopelletierine, (.+/-.)-pelletierine isopelletierine 1-(2-Piperidinyl)-2-propanone 1-(2-Piperidyl)-2-propanone 2-(2-Oxopropyl)piperidine 1-piperidin-2-ylpropan-2-one 1-piperidin-2-ylacetone(SALTDATA: 0.15H2O) 1-piperidin-2-ylacetone (SALTDATA: FREE) 1-piperidin-2-ylacetone 2-Propanone, 1-(2-piperidinyl)- 1-(2-Piperidinyl)acetone 1-Piperidin-2-ylacetone DISCONTINUED. Please see B449984. 4396-01-4