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Lead(II) carbonate basic

Lead(II) carbonate basic Structure
CAS No.
1319-46-6
Chemical Name:
Lead(II) carbonate basic
Synonyms
LEAD CARBONATE;basicleadcarbonate;LEAD(II) CARBONATE;LEAD(II) CARBONATE, BASIC;carbonicacid,leadsalt,basic;ceruse;cerussa;White 1;flakelead;C.I.77597
CBNumber:
CB7106691
Molecular Formula:
2CO3.2Pb.H2O2Pb
Molecular Weight:
775.63
MOL File:
1319-46-6.mol
MSDS File:
SDS
Modify Date:
2023/10/17 17:11:55

Lead(II) carbonate basic Properties

Melting point 400 °C (dec.)(lit.)
Density 6,14 g/cm3
solubility insoluble in H2O, ethanol; soluble in acid solutions
form Powder
Specific Gravity 6.14
color White to off-white
Water Solubility Insoluble
Solubility Product Constant (Ksp) pKsp: 13.13
Exposure limits ACGIH: TWA 0.05 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.050 mg/m3
Stability Stable. Incompatible with strong oxidizing agents, strong acids.
CAS DataBase Reference 1319-46-6(CAS DataBase Reference)
EPA Substance Registry System Basic lead carbonate (1319-46-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302+H332-H360FD-H373-H410
Precautionary statements  P202-P260-P273-P301+P312-P304+P340+P312-P308+P313
Hazard Codes  T,N
Risk Statements  61-20/22-33-50/53-62
Safety Statements  53-45-60-61
RIDADR  UN 2291 6.1/PG 3
WGK Germany  3
RTECS  OF9275000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  28369917
NFPA 704
0
2 0

Lead(II) carbonate basic price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 243582 Lead(II) carbonate basic ?325?mesh 1319-46-6 100G ₹3464 2022-06-14 Buy
Sigma-Aldrich(India) 243582 Lead(II) carbonate basic ?325?mesh 1319-46-6 2.5KG ₹22721.68 2022-06-14 Buy
ottokemi L 1348 Lead carbonate, basic 1319-46-6 500gm ₹837 2022-05-26 Buy
Product number Packaging Price Buy
243582 100G ₹3464 Buy
243582 2.5KG ₹22721.68 Buy
L 1348 500gm ₹837 Buy

Lead(II) carbonate basic Chemical Properties,Uses,Production

Chemical Properties

dense white powder

Uses

Lead(II) carbonate basic can be used as pigment in oil paints and water colors; in cements; for making putty and lead carbonate paper; in the processing of parchment.

Production Methods

Basic Lead Carbonate is produced by several methods, in which soluble lead acetate is treated with carbon dioxide. For example, in the Thompson-Stewart process, an aqueous slurry of finely divided lead metal or monoxide, or a mixture of both, is treated with acetic acid in the presence of air and carbon dioxide. High quality, very fine particle-size basic lead carbonate is produced, ranging in carbonate content from 62 to 65% (vs 68.9% PbCO3, theoretical).

Preparation

Many commercial processes have been developed for manufacturing basic lead carbonate. These include: Thomson-Stewart process, Carter process, and Dutch process. The method of preparation involves treating lead with acetic acid vapors in the presence of carbon dioxide at 60°C. In the Thomson-Stewart process, finely divided lead monoxide or lead metal is mixed with water to give aqueous slurry, which is then mixed with acetic acid in the presence of air and carbon dioxide. All these processes are slow, taking weeks to obtain products of desired composition.
Basic lead carbonate also is precipitated by dissolving lead monoxide in lead(II) acetate solution, and treating the solution with carbon dioxide. It also is produced by electrolysis of sodium nitrate or sodium acetate using lead anode and then precipitating out the product by adding sodium carbonate.
.

Definition

Acid-soluble, heavy, white powder or crystalline substance, insoluble in water and alco- hol.

Lead(II) carbonate basic Preparation Products And Raw materials

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