Cyclobutanone
![Cyclobutanone Structure](CAS/GIF/1191-95-3.gif)
- CAS No.
- 1191-95-3
- Chemical Name:
- Cyclobutanone
- Synonyms
- CBON;obutanone;CYCLOBUTANONE;Oxocyclobutane;1-Oxocyclobutane;Cyclobutanone 98%;Cyclobutanone, 98+%;OS-7558Cyclobutanone;cyclobutanone(SALTDATA: FREE);Cyclobutanone, 98%, stabilized
- CBNumber:
- CB7231982
- Molecular Formula:
- C4H6O
- Molecular Weight:
- 70.09
- MOL File:
- 1191-95-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/29 18:03:56
Melting point | -50.9 °C |
---|---|
Boiling point | 99 °C (lit.) |
Density | 0.938 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 50 °F |
storage temp. | 2-8°C |
solubility | soluble in Dichloromethane |
form | Liquid |
Specific Gravity | 0.938 |
color | Clear colorless to slightly yellow |
Water Solubility | INSOLUBLE |
BRN | 1560289 |
Stability | Volatile |
InChIKey | SHQSVMDWKBRBGB-UHFFFAOYSA-N |
CAS DataBase Reference | 1191-95-3(CAS DataBase Reference) |
EPA Substance Registry System | Cyclobutanone (1191-95-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS02 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225 | |||||||||
Precautionary statements | P210-P233-P240-P241-P242-P243 | |||||||||
Hazard Codes | F,F+ | |||||||||
Risk Statements | 10-11 | |||||||||
Safety Statements | 23-24/25-9-33-29-16-7/9 | |||||||||
RIDADR | UN 1224 3/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29142900 | |||||||||
NFPA 704 |
|
Cyclobutanone price More Price(6)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | C96001 | Cyclobutanone 99% | 1191-95-3 | 5G | ₹20621.63 | 2022-06-14 | Buy |
ALFA India | ALF-A13068-14 | Cyclobutanone, 98%, stab. with ca 0.1% BHT | 1191-95-3 | 25g | ₹64346 | 2022-05-26 | Buy |
ALFA India | ALF-A13068-06 | Cyclobutanone, 98%, stab. with ca 0.1% BHT | 1191-95-3 | 5g | ₹13111 | 2022-05-26 | Buy |
ALFA India | ALF-A13068-03 | Cyclobutanone, 98%, stab. with ca 0.1% BHT | 1191-95-3 | 1g | ₹4418 | 2022-05-26 | Buy |
TCI Chemicals (India) | C1913 | Cyclobutanone (stabilized with Na2CO3) min. 97.0 % | 1191-95-3 | 1G | ₹4200 | 2022-05-26 | Buy |
Cyclobutanone Chemical Properties,Uses,Production
Chemical Properties
Clear colourless to slightly yellow liquid
Uses
Cyclobutanone is used in preparation of cyclobutane derivatives. It is used as a starting material for aminocyclobutanecarboxylic acid through sulfonyloxiranes. It is also used to prepare dihydro-furan-2-one in presence of polystyrene-bound phenylselenic acid as catalyst. Further, it is involved in the photochemical synthesis of nucleoside analogues such as bicyclic nucleosides and isonucleosides.
Preparation
The Russian chemist Nikolai Kischner first prepared cyclobutanone in 1905. He synthesized cyclobutanone in a low yield from cyclobutanecarboxylic acid in several reaction steps.
Another synthesis of cyclobutanone involves lithium-catalyzed rearrangement of oxaspiropentane, which is formed by epoxidation of the easily accessible methylenecyclopropane.
Purification Methods
Treat cyclobutanone with dilute aqueous KMnO4, dry it with molecular sieves and fractionally distil it. Purify it via the semicarbazone, then regenerate the ketone, dry it (CaSO4), and distil it in a stainless steel spinning-band (or Vigreux, p 11) column. Alternatively, purify it by preparative gas chromatography using a Carbowax 20-M column at 80o. (This treatment also removes acetone). The oxime has m 84-85o (from pet ether) and the semicarbazone has m 212-212-5o (220-221o from MeOH or H2O, Buchanan et al. J Am Chem Soc 64 2701 1942). [Salaun Org Synth 57 36 1977, Fitzer & Quabeck Synthesis 299 1987, Beilstein 7 IV 3.]
Cyclobutanone Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
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BTC pharm India | +918790379245 | AndhraPradesh, India | 1269 | 58 | Inquiry |
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Vardhaman P Golechha | 9704422000 | Telangana, India | 294 | 58 | Inquiry |
REAX CHEMICALS | +91-9347443900 +91-9347443900 | Hyderabad, India | 169 | 58 | Inquiry |
JIVICHEM SYNTHESIS PVT LTD | +91-7028392790 +91-7028392790 | Maharashtra, India | 337 | 58 | Inquiry |
KROMOZOME | +91-91-9650900955 +91-09650900955 | Maharashtra, India | 71 | 58 | Inquiry |
Allchem Lifescience Pvt. Ltd | +919867655500 | Gujarat, India | 971 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
Dr. Silviu Pharmachem Pvt., Ltd. | +91-8390608382 +91-8390608382 | Mumbai, India | 248 | 58 | Inquiry |
BTC pharm India | +918790379245 | Telangana, India | 145 | 58 | Inquiry |
Supplier | Advantage |
---|---|
BTC pharm India | 58 |
GLR Innovations | 58 |
Vardhaman P Golechha | 58 |
REAX CHEMICALS | 58 |
JIVICHEM SYNTHESIS PVT LTD | 58 |
KROMOZOME | 58 |
Allchem Lifescience Pvt. Ltd | 58 |
JSK Chemicals | 58 |
Dr. Silviu Pharmachem Pvt., Ltd. | 58 |
BTC pharm India | 58 |
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