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4-Methylmorpholine N-oxide

CAS No.: 7529-22-8

Chemical Name:: 4-Methylmorpholine N-oxide

Synonyms: NMO;4-METHYLMORPHOLINE 4-OXIDE;N-Methylmorpholine oxide;Morpholine, 4-methyl-, 4-oxide;4-methyl-morpholin4-oxide;MMNO;NSC 73198;NSC 82153;ine N-oxide;nmo solution

CBNumber:: CB7305470

Molecular Formula:: C5H11NO2

Molecular Weight:: 117.15

MOL File:: 7529-22-8.mol

MSDS File:: SDS

Modify Date:: 2024/6/25 11:05:41

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4-Methylmorpholine N-oxide Properties

Melting point	180-184 °C(lit.)
Boiling point	118-119°C
Density	1,14 g/cm³
vapor pressure	1.41hPa at 20℃
refractive index	n20/D 1.43
Flash point	118-119°C
storage temp.	2-8°C
solubility	DMSO (Soluble), Methanol (Slightly)
pka	4.93±0.20(Predicted)
form	Liquid
color	Clear colorless to yellow
PH	9.00 ( in neat)
Water Solubility	Soluble in water, methanol, ethanol, acetone, ethers and dimethylsulfoxide.
BRN	507437
Stability	Hygroscopic
LogP	-1.2 at 25℃
CAS DataBase Reference	7529-22-8(CAS DataBase Reference)
NIST Chemistry Reference	N-Methylmorpholine-N-oxide(7529-22-8)
EPA Substance Registry System	Morpholine, 4-methyl-, 4-oxide (7529-22-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS03,GHS08

Signal word

Danger

Hazard statements

H228-H272-H361f

Precautionary statements

P202-P210-P220-P240-P241-P308+P313

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36/37

WGK Germany

TSCA

Yes

HS Code

29349990

NFPA 704

	1
2		0

4-Methylmorpholine N-oxide price More Price(14)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	8.14779	4-Methylmorpholine 4-oxide (50% solution in water) for synthesis	7529-22-8	250ML	₹7000	2022-06-14	Buy
Sigma-Aldrich(India)	8.14779	4-Methylmorpholine 4-oxide (50% solution in water) for synthesis	7529-22-8	1L	₹7420	2022-06-14	Buy
Sigma-Aldrich(India)	258822	4-Methylmorpholine N-oxide solution 50?wt. % in H2O	7529-22-8	100G	₹2987.7	2022-06-14	Buy
Sigma-Aldrich(India)	224286	4-Methylmorpholine N-oxide 97%	7529-22-8	5G	₹2078.4	2022-06-14	Buy
Sigma-Aldrich(India)	258822	4-Methylmorpholine N-oxide solution 50?wt. % in H2O	7529-22-8	1KG	₹8421.85	2022-06-14	Buy

Product number	Packaging	Price	Buy
8.14779	250ML	₹7000	Buy
8.14779	1L	₹7420	Buy
258822	100G	₹2987.7	Buy
224286	5G	₹2078.4	Buy
258822	1KG	₹8421.85	Buy

4-Methylmorpholine N-oxide Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to yellow solution

Uses

4-Methylmorpholine N-Oxide is a metabolite of Morpholine (M723725). N-Methylmorpholine N-Oxide is commonly used to dissolve cellulose as well as in the dissolution of of scleroproteins.

General Description

4-Methylmorpholine?N-oxide is an organic compound used as a co-oxidant along with OsO₄ and ruthenates in organic synthesis. In recent studies, it has been used as a catalyst in silylcyanation of aldehydes and ketones. Lyocell, a regenerated cellulose fiber, can be prepared using 4-methylmorpholine?N-oxide in an eco-friendly manner.

Synthesis

A preparation method of N-methylmorpholine-N-oxide comprises the following steps: (1) adding the nano metal oxide into N-methyl morpholine (NMM) and mixing and stirring to uniformly mix the nano metal oxide with the NMM; (2) dropwise adding a hydrogen peroxide solution into a mixed solution of NMM and a catalyst; (3) raising the temperature to accelerate the reaction process; (4) and (4) filtering and distilling the solution prepared in the step (3) under reduced pressure to obtain the required NMMO solution. The method for preparing NMMO provided by the present disclosure has the advantages of a fast reaction rate, low reaction temperature, few byproducts, etc.

Purification Methods

When the oxide is dried for 2-3hours at high vacuum, it dehydrates. Add MeOH to the oxide and distil off the solvent under vacuum until the temperature is ca 95o. Then add Me2CO at reflux and cool to 20o. The crystals are filtered off, washed with Me2CO and dried. The degree of hydration may vary and may be important for the desired reactions. [van Rheenan et al. Tetrahedron Lett 1973 1076, Schneider & Hanze US Pat 2 769 823; see also Sharpless et al. Tetrahedron Lett 2503 1976.]

4-Methylmorpholine N-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

4-METHYL-2-OXO-2 H-CHROMENE-7-CARBALDEHYDE N-Boc-4-oxo-L-Proline methyl ester 4-Methylmorpholine N-oxide monohydrate 4-Bromo-2-nitroaniline N,N'-Dimorpholinomethane

BOC-4-OXO-L-PROLINE TERT-BUTYL ESTER PREGNANEDIONE

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4-Methylmorpholine N-oxide Suppliers

Global( 449)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
GLR Innovations	+91 9891111994	New Delhi, India	4542	58	Inquiry
AMINES AND PLASTICIZERS LTD.	+91-22-24935282 +91-9167680626	Mumbai, India	26	58	Inquiry
Indo Amines Ltd	+91-7045592702 +91-7045592702	Mumbai, India	42	58	Inquiry
VGS SYNTHESIS PRIVATE LIMITED	+91-9866975588 +91-9866975588	Hyderabad, India	1818	58	Inquiry
JSK Chemicals	+919879767970	Gujarat, India	3756	58	Inquiry
ALS INDIA LIFE SCIENCES	+91-8977036379 +91-8977036379	Hyderabad, India	1879	58	Inquiry
Clearsynth Labs	91-22-45045900	Maharashtra, India	3889	58	Inquiry
ASM Organics	91-9866122393	Andhra Pradesh, India	1188	58	Inquiry
Innovative	07942565925	Mumbai, India	617	58	Inquiry
Amines & Plasticizers Limited	08048372484Ext 604	Mumbai, India	18	58	Inquiry

Supplier	Advantage
GLR Innovations	58
AMINES AND PLASTICIZERS LTD.	58
Indo Amines Ltd	58
VGS SYNTHESIS PRIVATE LIMITED	58
JSK Chemicals	58
ALS INDIA LIFE SCIENCES	58
Clearsynth Labs	58
ASM Organics	58
Innovative	58
Amines & Plasticizers Limited	58

4-Methylmorpholine N-oxide Spectrum

4-Methylmorpholine N-oxide(7529-22-8)¹HNMR 4-Methylmorpholine N-oxide(7529-22-8)¹³CNMR 4-Methylmorpholine N-oxide(7529-22-8)IR 4-Methylmorpholine N-oxide(7529-22-8)Raman

7529-22-8(4-Methylmorpholine N-oxide)Related Search:

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4-Methyl-4-oxylatomorpholinium 4-Oxylato-4-methylmorpholine-4-ium N-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L) 4-Methylmorpholine N-oxide,NMO 4-Methylmorpholine N-oxide solution,NMO solution N-Methylmorpholine N-oxide - 50% w/w aqeous solution 4-MethylMorpholin-4-iuM-4-olate (50% in Water, ca. 4.8Mol/L) Morpholine,4-methyl-,4-oxide N-METHYLMORPHOLINE 4-OXIDE 4-METHYLMORPHOLINE N-OXIDE METHYL MORPHOLINE OXIDE 4-MethylMorpholine N-Oxide NSC 73198 NSC 82153 4-METHYLMORPHOLINE N-OXIDE, 50 WT. % SOL UTION IN WATER 4-MethylMorpholine N-oxide, 50 wt.% solution in H2O 4-MethylMorpholine N-oxide solution 50 wt. % in H2O N- MethylMorpholine oxide -N- NMMO solution OTHER DERIVATIVES OF PYRIDINES STERO NMMO 4-Methylmorpholine N-oxide, w/w aq. soln. 4-Methylmorpholine N-oxide solution, 50 wt. % in water 4-METHYLMORPHOLINE-4-OXIDE SOLUTION, ~50 % IN WATER N-MethylMorpholineOxide50%(Nmmo) 4-MethlMorpholine-N-Oxide99% N-Methyl morpholine-N-oxide, 60% w/w soln. in water N-MethylMorpholineOxide(NMMO) N-MethylmorpholineN-oxide,50%w/waq.soln. 4-methylmorpholine n-oxide solution nmo solution N-METHYLMORPHOLINE N-OXIDE: 50% W/W AQUEOUS SOLUTION 4-Methylmorpholine oxide 4-METHYLMORPHOLINE N-OXIDE 97% 4-methyl-4-oxidomorpholin-4-ium N-Methyl morpholine-N-oxide 4-methyl-4-oxidanidyl-morpholin-4-ium 4-METHYLMORPHOLINEN-OXIDE(WATERFREE) N-METHYL MORPHOLINE-N-OXIDE, 50% W/W SOLN. IN WATER 4-Methylmorpholine N-oxide, 50% w/w aq. soln. 4-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L) 4-Methylmorphine-4-oxide Morpholine, 4-methyl-, 4-oxide hydrate N-methyl-n-oxymorpholine 4-MethylmorpholineN-Oxide> N-Methyl-N-Oxomorph 4-Methylmorpholine N-oxide USP/EP/BP N- Methyl Morpholine Oxide -50 % & 60% [NMMO] ine N-oxide 4-methyl-morpholin4-oxide Morpholine, 4-methyl-, 4-oxide N-Methylmorpholine oxide NMO 4-METHYLMORPHOLINE 4-OXIDE MMNO 4-ethylmorpholineN-oxideMETHYLMORPHOLINE4-OXIDE 2,4-Dihydroxybenzoic acid 89-86-1 4-Methylmorpholine N-Oxide, 50wt.% in H2O