N-HEXYLLITHIUM
![N-HEXYLLITHIUM Structure](CAS/GIF/21369-64-2.gif)
- CAS No.
- 21369-64-2
- Chemical Name:
- N-HEXYLLITHIUM
- Synonyms
- HEXYLLITHIUM;lithium,hexane;1-Hexyllithium;1-Lithiohexane;N-HEXYLLITHIUM;Lithium, hexyl-;hexyllithium solution;N-HEXYLLITHIUM: IN HEXANE;Hexyllithium, 2M in hexane;n-Hexyllithium, soln. in he
- CBNumber:
- CB7480195
- Molecular Formula:
- C6H13Li
- Molecular Weight:
- 92.11
- MOL File:
- 21369-64-2.mol
- Modify Date:
- 2025/1/16 13:03:17
Boiling point | 69 °C |
---|---|
Density | 0.708 g/mL at 25 °C |
vapor pressure | 26.9-39.3hPa at 20-35℃ |
Flash point | 16 °F |
storage temp. | 2-8°C |
color | yellow-brown |
Sensitive | Moisture Sensitive |
BRN | 3600261 |
Stability | Stable, but highly flammable. Reacts violently with water, releasing flammable gas. May spontaneously inflame in air. Moisture and air sensitive. Incompatible with water, alcohols, halocarbons. |
EPA Substance Registry System | Lithium, hexyl- (21369-64-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() ![]() ![]() GHS02,GHS05,GHS07,GHS08,GHS09 |
---|---|
Signal word | Danger |
Hazard statements | H225-H250-H260-H304-H314-H336-H361f-H373-H411-H318-H361 |
Precautionary statements | P210-P222-P223-P231+P232-P370+P378-P422-P201-P273-P280-P307 |
Hazard Codes | F,Xn,N,C |
Risk Statements | 11-14/15-17-35-48/20-51/53-62-65-67 |
Safety Statements | 26-30-36/37/39-43-45-61-62-16-6 |
RIDADR | UN 3394 4.2/PG 1 |
WGK Germany | 2 |
F | 10-23 |
TSCA | Yes |
HazardClass | 4.3 |
PackingGroup | I |
HS Code | 29319090 |
N-HEXYLLITHIUM Chemical Properties,Uses,Production
Description
n-Hexyllithium [21369-64-2], C6H13Li, Mr 92.11, r 0.766 g/cm3 is a pyrophoric colorless and viscous liquid in the neat state. It is commercially available as a 33 % solution in technical-grade hexane. Its reactivity resembles that of n-butyllithium and it can thus principally be used for the same applications. An advantage is that it does not form gaseous byproducts in deprotonation reactions and on hydrolysis, but liquid hexane instead.
Chemical Properties
often supplied as a deep yellow solution (ca 2M) in hexane. n-Hexyllithium is soluble at all concentrations in aliphatic and aromatic hydrocarbons and reacts exothermically with water and protic solvents.
Uses
n-Hexyllithium could be used as alkylating agent for various functional groups; metalating agent of aryl and heteroaryl ring systems; slightly less reactive than n-butyllithium.
Precautions
n-Hexyllithium should be handled as n-Butyllithium; store in a cool, dry place in a tightly sealed container under an inert atmosphere.
N-HEXYLLITHIUM Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
JSK Chemicals | +919879767970 | Gujarat, India | 3753 | 58 | Inquiry |
Ortin Laboratories Limited | +91-9241566560 +91-9241566560 | Hyderabad, India | 31 | 58 | Inquiry |
Organo Metallics | +91-9391016448 +91-9705345345 | Telangana, India | 32 | 58 | Inquiry |
FMC India Private Limited | Karnataka, India | 16 | 58 | Inquiry | |
HYCHEM SAINOR CHEMICALS PVT LTD | +919391007257 | Telangana, India | 205 | 58 | Inquiry |
Anand Agencies | 91-20-24454597 | Maharashtra, India | 2332 | 58 | Inquiry |
Vinsa Pharmaceuticals | 91-9246578585 | Andhra Pradesh, India | 32 | 58 | Inquiry |
FMC India Private Limited | 91-80-40099300 | Karnataka, India | 10 | 58 | Inquiry |
Almas Life Sciences | 09441456585 | Hyderabad, India | 68 | 58 | Inquiry |
S. R. Chemical Specialities | 08048965126 | Hyderabad, India | 90 | 58 | Inquiry |
Supplier | Advantage |
---|---|
JSK Chemicals | 58 |
Ortin Laboratories Limited | 58 |
Organo Metallics | 58 |
FMC India Private Limited | 58 |
HYCHEM SAINOR CHEMICALS PVT LTD | 58 |
Anand Agencies | 58 |
Vinsa Pharmaceuticals | 58 |
FMC India Private Limited | 58 |
Almas Life Sciences | 58 |
S. R. Chemical Specialities | 58 |