L(+)-Tartaric acid
- CAS No.
- 87-69-4
- Chemical Name:
- L(+)-Tartaric acid
- Synonyms
- TARTARIC ACID;L-TARTARIC ACID;TARTRATE;(2R,3R)-2,3-DIHYDROXYSUCCINIC ACID;Tartaric;lev;2,3-Dihydroxysuccinic acid;l-tartaric;2,3-DIHYDROXYBUTANEDIOIC ACID;levo
- CBNumber:
- CB8212874
- Molecular Formula:
- C4H6O6
- Molecular Weight:
- 150.09
- MOL File:
- 87-69-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/19 18:29:52
| Melting point | 170-172 °C(lit.) |
|---|---|
| alpha | 12 º (c=20, H2O) |
| Boiling point | 191.59°C (rough estimate) |
| Density | 1.76 |
| vapor density | 5.18 (vs air) |
| vapor pressure | <5 Pa (20 °C) |
| FEMA | 3044 | TARTARIC ACID (D-, L-, DL-, MESO-) |
| refractive index | 12.5 ° (C=5, H2O) |
| Flash point | 210 °C |
| storage temp. | Store at +5°C to +30°C. |
| solubility | H2O: soluble1M at 20°C, clear, colorless |
| form | Solid |
| pka | 2.98, 4.34(at 25℃) |
| color | White or colorless |
| PH | 3.18(1 mM solution);2.55(10 mM solution);2.01(100 mM solution); |
| Odor | at 100.00 %. odorless |
| Odor Type | odorless |
| optical activity | [α]20/D +13.5±0.5°, c = 10% in H2O |
| Water Solubility | 1390 g/L (20 ºC) |
| JECFA Number | 621 |
| Merck | 14,9070 |
| BRN | 1725147 |
| Dielectric constant | 35.9（-10℃） |
| Stability | Stable. Incompatible with oxidizing agents, bases, reducing agents. Combustible. |
| InChIKey | FEWJPZIEWOKRBE-JCYAYHJZSA-N |
| LogP | -1.43 |
| CAS DataBase Reference | 87-69-4(CAS DataBase Reference) |
| NIST Chemistry Reference | Butanedioic acid, 2,3-dihydroxy- [r-(r*,r*)]-(87-69-4) |
| EPA Substance Registry System | Tartaric acid (87-69-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H318 | |||||||||
| Precautionary statements | P280-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-41 | |||||||||
| Safety Statements | 26-36-37/39-36/37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | WW7875000 | |||||||||
| Autoignition Temperature | 797 °F | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29181200 | |||||||||
| NFPA 704 |
|
L(+)-Tartaric acid price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W304412 | L-(+)-Tartaric acid natural, ≥99.7%, FCC, FG | 87-69-4 | 1SAMPLE-K | ₹5196 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W304412 | L-(+)-Tartaric acid natural, ≥99.7%, FCC, FG | 87-69-4 | 1KG | ₹8378.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W304412 | L-(+)-Tartaric acid natural, ≥99.7%, FCC, FG | 87-69-4 | 5KG | ₹12611.13 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W304412 | L-(+)-Tartaric acid natural, ≥99.7%, FCC, FG | 87-69-4 | 10KG | ₹19820.58 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W304409 | L-(+)-Tartaric acid ≥99.7%, FCC, FG | 87-69-4 | 1SAMPLE | ₹5141.88 | 2022-06-14 | Buy |
L(+)-Tartaric acid Chemical Properties,Uses,Production
Chemical Properties
Tartaric acid occurs as colorless monoclinic crystals, or a white or almost white crystalline powder. It is odorless, with an extremely tart taste. L-(+)-Tartaric Acid is a naturally occurring chemical compound found in berries, grapes and various wines. It provides antioxidant properties and contributes to the sour taste within these products.
Production Methods
Tartaric acid occurs naturally in many fruits as the free acid or in
combination with calcium, magnesium, and potassium.
Commercially, L-(＋)-tartaric acid is manufactured from potassium
tartrate (cream of tartar), a by-product of wine making.
Potassium tartrate is treated with hydrochloric acid, followed by the
addition of a calcium salt to produce insoluble calcium tartrate.
This precipitate is then removed by filtration and reacted with 70%
sulfuric acid to yield tartaric acid and calcium sulfate.
Definition
ChEBI: L-tartaric acid is a tetraric acid that is butanedioic acid substituted by hydroxy groups at positions 2 and 3. It is a conjugate acid of a L-tartrate(1-). It is an enantiomer of a D-tartaric acid.
General Description
Tartaric Acid belongs to the group of carboxylic acids, and is abundantly found in grapes and wine. It is widely used in drugs, food, and beverage industry.
Pharmaceutical Applications
Tartaric acid is used in beverages, confectionery, food products, and
pharmaceutical formulations as an acidulant. It may also be used as
a sequestering agent and as an antioxidant synergist. In pharmaceutical
formulations, it is widely used in combination with
bicarbonates, as the acid component of effervescent granules,
powders, and tablets.
Tartaric acid is also used to form molecular compounds (salts
and cocrystals) with active pharmaceutical ingredients to improve
physicochemical properties such as dissolution rate and solubility.
Safety Profile
Moderately toxic by intravenous route. Mildly toxic by ingestion. Reaction with silver produces the unstable silver tartrate. When heated to decomposition it emits acrid smoke and irritating fumes.
Safety
Tartaric acid is widely used in food products and oral, topical, and
parenteral pharmaceutical formulations. It is generally regarded as
a nontoxic and nonirritant material; however, strong tartaric acid
solutions are mildly irritant and if ingested undiluted may cause
gastroenteritis.
An acceptable daily intake for L-(＋)-tartaric acid has not been set
by the WHO, although an acceptable daily intake of up to 30 mg/kg
body-weight for monosodium L-(＋)-tartrate has been established.
LD50 (mouse, IV): 0.49 g/kg
storage
The bulk material is stable and should be stored in a well-closed container in a cool, dry place.
Incompatibilities
Tartaric acid is incompatible with silver and reacts with metal carbonates and bicarbonates (a property exploited in effervescent preparations).
Regulatory Status
GRAS listed. Accepted for use as a food additive in Europe. Included in the FDA Inactive Ingredients Database (IM and IV injections; oral solutions, syrups and tablets; sublingual tablets; topical films; rectal and vaginal preparations). Included in nonparenteral medicines licensed in the UK. Included in the Canadian List of Acceptable Non-medicinal Ingredients.
L(+)-Tartaric acid Preparation Products And Raw materials
Raw materials
Preparation Products
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| Supplier | Advantage |
|---|---|
| CLEARSYNTH LABS LTD. | 58 |
| ANJI BIOSCIENCES | 58 |
| KAIVAL CHEMICALS Pvt ltd | 58 |
| Vardhaman P Golechha | 58 |
| JIVICHEM SYNTHESIS PVT LTD | 58 |
| Atul Intermediates | 58 |
| Evans Fine Chem | 58 |
| Kronox Lab Sciences Pvt Ltd | 58 |
| Dhara Industries | 58 |
| PAARICHEM RESOURCES LLP | 58 |
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