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(+)-Taddol

(+)-Taddol Structure
CAS No.
93379-49-8
Chemical Name:
(+)-Taddol
Synonyms
((4S,5S);97.0%(LC);(+)-TADDOL;(S,S)-taddol;SEEBACH REAGENT;bis(diphenylmethanol);(4S,5S)-2,2-Dimethyl-α;(+)-4,5-Bis[hydroxy(diphenyL;meso-2,3-Diphenylsuccinonitrile>(+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TE
CBNumber:
CB6152969
Molecular Formula:
C31H30O4
Molecular Weight:
466.57
MOL File:
93379-49-8.mol
Modify Date:
2023/4/23 13:52:06

(+)-Taddol Properties

Melting point 193-196 °C(lit.)
alpha -62.6 º (c=1 in chloroform)
Boiling point 633.2±50.0 °C(Predicted)
Density 1.200±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
pka 12.28±0.29(Predicted)
color White to Almost white
optical activity [α]19/D +67°, c = 1 in chloroform
BRN 4724097
InChIKey RNSJHECWLNVNFE-LOYHVIPDSA-N
CAS DataBase Reference 93379-49-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H317-H319
Precautionary statements  P280-P305+P351+P338
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29329990

(+)-Taddol price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 264997 (4S,5S)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97% 93379-49-8 1G ₹8032.15 2022-06-14 Buy
TCI Chemicals (India) B2048 (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane 93379-49-8 1G ₹5800 2022-05-26 Buy
TCI Chemicals (India) B2048 (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane 93379-49-8 5G ₹11000 2022-05-26 Buy
Product number Packaging Price Buy
264997 1G ₹8032.15 Buy
B2048 1G ₹5800 Buy
B2048 5G ₹11000 Buy

(+)-Taddol Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Ligand for enantioselective Lewis-acid mediated Diels-Alder, allyltitanation of aldehydes, and Michael-Mukaiyama additions promoted by chiral Ti-complexes.

(+)-Taddol Preparation Products And Raw materials

Raw materials

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Preparation Products

Global( 152)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16920 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21669 55 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29896 58 Inquiry
Xi'an Kono chem co., Ltd., 029-86107037 13289246953 China 2995 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
SIMAGCHEM CORP +86-13806087780 China 17367 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52861 58 Inquiry
(+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE (4S,5S)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYLDIOXOLANE-4,5-DIMETHANOL (4S,5S)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-D-THREITOL (2S,3S)-(+)-1,1,4,4-TETRAPHENYL-2,3-(2-PROPYLIDENEDIOXY)-BUTANE-1,4-DIOL (2S,3S)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL (2S,3S)-(+)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (+)-TADDOL SEEBACH REAGENT 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-.alpha.,.alpha.,.alpha.,.alpha.-tetraphenyl-, (4S,5S)- (4s,5s)-2,2-dimethyl-α,α,α',α'-tetraphenyldioxolane-4,5-dimethanol (+)-Taddol (2S,3S)-(-)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyl-1,3-dioxolane (+)-TRANS-4,5-BIS-(DIPHENYL-HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (+)-TRANS-ALPHA,ALPHA'-(2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL) (+)-trans-A,A-(2,2-dimethyl-1,3-dioxolane -4,5-D Bishydroxydiphenylmethyldimethyldioxolane 1,1,4,4-Tetraphenyl-2,3,0-isopropylidene-D-threitol (4S,5S)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethan (2,2-)Dimethy-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4S,5S)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane- 4,5-dimethanol ((4S,5S) -2,2-Dimethyl-1,3-dioxolane-4,5-diyl) bis(diphenylmethanol) (4S,5S)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane- 4,5-dimethanol,99%e.e. 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol (4S,5S)-2,2-DIMETHYL-A,A,A'',A'',-TETRAPHENYLDIOXOLANE-4,5-DIMETHANOL (+)-trans-α,α'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenlmethanol) (2,2-dimethyl)-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol (4S,5S)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, (+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol, (+)-trans-α,αμ-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4S)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4α,5β-dimethanol (4S,5S)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-dimethanol 2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4α,5β-dimethanol α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4α,5β-bismethanol 2,2-Dimethyl-1,3-dioxolane-4,5-bis(α,α-diphenylmethanol) α,α'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(α-phenylbenzyl alcohol) α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-dimethanol ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (+)-trans-alpha,alpha'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (2S,3S)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (+)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-D-threitol (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane,97% (4S,5S)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol ,98% (4S,5S)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE (4S,5S)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol (-)-2,3-O-isopropylidene-1,1,4,4-tetra-phenyl-D-threitol 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetraphenyl-, (4S,5S)- (+)-4,5-Bis[hydroxy(diphenyL Gal[2346Ac]β(1-3)GlcNPhth[46Bzd]-β-MP> meso-2,3-Diphenylsuccinonitrile> Neu5Acα(2-6)Galβ(1-3)GlcNAc-β-pNP> Methyl2,3,4,6-Tetra-O-pivaloyl-D-mannopyranoside> Neu5GcAc[1Me,4789Ac]α(2-6)Gal[24Bz,3Bn]-β-MP> '-tetraphenyl-1,3-dioxolane-4,5-dimethanol, 98% (99% ee) (4S,5S)-2,2-Dimethyl-α 97.0%(LC) (4S,5S)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol, 98% (99% ee) (S,S)-taddol (+)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TE [(4S,5S)-5-[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-diphenylmethanol