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1-Benzyloxy-2-methoxy-4-propenylbenzene

1-Benzyloxy-2-methoxy-4-propenylbenzene  Structure
CAS No.
120-11-6
Chemical Name:
1-Benzyloxy-2-methoxy-4-propenylbenzene
Synonyms
FEMA 3698;FEMA 3695;BENZYLEUGENOL;benzyl2-methoxy;BENZYL ISOEUGENOL;benzyl2-methoxy-4-;CIS-BENZYL-ISO-EUGENOL;BENZYL ISOEUGENOL FORTE;Iso-eugenol Benzyl Ethe;ISOEUGENYL BENZYL ETHER
CBNumber:
CB8396103
Molecular Formula:
C17H18O2
Molecular Weight:
254.32
MOL File:
120-11-6.mol
Modify Date:
2024/7/21 22:12:10

1-Benzyloxy-2-methoxy-4-propenylbenzene Properties

Melting point 59-63 °C(lit.)
Boiling point 357.54°C (rough estimate)
Density 1.0621 (rough estimate)
vapor pressure 0.002-0.004Pa at 20-25℃
FEMA 3698 | ISOEUGENYL BENZYL ETHER
refractive index 1.5000 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form Solid
color White to Off-White
Odor at 100.00 %. mild spicy balsam carnation
Odor Type spicy
JECFA Number 1268
LogP 4.02 at 23.8℃
Surface tension 69.4mN/m at 1g/L and 23.8℃
CAS DataBase Reference 120-11-6(CAS DataBase Reference)
NIST Chemistry Reference Benzene, 2-methoxy-1-(phenylmethoxy)-4-(1-propenyl)-(120-11-6)
EPA Substance Registry System Benzyl isoeugenol (120-11-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS05,GHS09
Signal word  Danger
Hazard statements  H318-H317-H410-H315-H335
Precautionary statements  P280-P305+P351+P338-P310-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P273-P391-P501-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3
RTECS  CY8225000
Toxicity skn-rbt 500 mg/24H MLD FCTXAV 11,1025,73

1-Benzyloxy-2-methoxy-4-propenylbenzene Chemical Properties,Uses,Production

Description

Isoeugenyl benzyl ether has a faint, floral odor of rose-carnation. May be synthesized by benzylation of isoeugenol; also by alkaline isomerization of benzyleugenol. It is an excellent fixative for floral compositions, blends well with Ylang-Ylang. Benzyl salicylate, Rose alcohols, Butyl phenylacetate, etc.

Chemical Properties

White or off-white crystalline powder. Soluble in alcohol and oils, insoluble in water. M.P: 57° C. Isoeugenyl benzyl ether has faintly rosy-balsamic-carnat ion type odor of exceptional tenacity. It is overall sweet and generally floral when blended with lower boiling components.

Uses

1-Benzyloxy-2-methoxy-4-propenylbenzene blends excellently with the Ionones and Benzyl salicylate in Violet bases, and is widely used as a fixative. This ether is also used in flavor compositions, mainly in Spice flavors, but because of its peculiar "dry" sweetness, also useful in Banana flavors. Concentrations are usually about 15-16 ppm in the finished product.

Preparation

By benzylation of isoeugenol; also by alkaline isomerization of benzyleugenol

Safety Profile

Mildly toxic by ingestion. A skinirritant. When heated todecomposition it emits acrid smoke and irritating fumes.

1-Benzyloxy-2-methoxy-4-propenylbenzene Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 153)Suppliers
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Nagar Haveli Perfumes & Aromatics +917506551149 Mumbai, India 230 58 Inquiry
Organica Aromatics Pvt Ltd +91-8027735252 +91-9845332762 Bangalore, India 33 58 Inquiry
Yasho Industries Ltd +91-2262510100 +91-8291955977 Mumbai, India 70 58 Inquiry
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JINING XINHE CHEMICAL CO., LTD +8615318402391 China 807 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29826 58 Inquiry
1-(Benzyloxy)-2-methoxy-4-[(1E)-1-propenyl]benzene 1-(benzyloxy)-2-methoxy-4-propenyl-benzen 1-.alpha.-Phenyl-4-propenylveratrole 2-methoxy-1-(phenylmethoxy)-4-(1-propenyl)-benzen 2-methoxy-1-(phenylmethoxy)-4-(1-propenyl)-Benzene Benzene, 1-(benzyloxy)-2-methoxy-4-propenyl- Benzene, 2-methoxy-1-(phenylmethoxy)-4-(1-propenyl)- Benzyl alcohol, ether with isoeugenol 1-(BENZYLOXY)-2-METHOXY-4-[(1E)-PROP-1-EN-1-YL]BENE CIS-BENZYL-ISO-EUGENOL TRANS-BENZYL-ISO-EUGENOL BENZYL ISOEUGENOL FORTE 2-Methoxy-4-propenylphenyl benzyl ether 1-BENZYLOXY-2-METHOXY-4-(1-PROPENYL)BENZENE 97% Iso-eugenol Benzyl Ethe 2-Methoxy-4-[(Z)-1-propenyl]phenylbenzyl ether 2-Methoxy-4-(1-propenyl)phenylbenzyl ether 1-(Benzyloxy)-2-Methoxy-4-(prop-1-en-1-yl)benzene (E)-1-(benzyloxy)-2-Methoxy-4-(prop-1-en-1-yl)benzene 1-BENZYLOXY-2-METHOXY-4-(1-PROPENYL)BENZENE 1-(BENZYLOXY)-2-METHOXY-4-PROPENYLBENZENE benzyl2-methoxy benzyl2-methoxy-4- benzyl2-methoxy-4-prop-1-enylphenylether benzylalcohol,etherwithisoeugenol ISOEUGENYL BENZYL ETHER ISOEUGENOL BENZYL ETHER FEMA 3698 FEMA 3695 BENZYLEUGENOL BENZYL ISOEUGENOL BENZYL ISOEUGENOL ETHER BENZYL 2-METHOXY-4-PROPENYLPHENYL ETHER TRANS-ISOEUGENYL BENZYL ETHER 1-(Benzyloxy)-2-methoxy-4-(1-propen-1-yl)benzene 2-methoxy-1-phenylmethoxy-4-[(Z)-prop-1-enyl]benzene Benzene, 2-methoxy-1-(phenylmethoxy)-4-(1-propen-1-yl)- 1-Benzyloxy-2-methoxy-4-propenylbenzene USP/EP/BP Isoeugenyl Benzyl ether 903 120-11-6 0120-11-06 C3H5C6H3OCH3OC7H7 Cd7H19O2